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Non-destructive measurement of in-operando lithium concentration in batteries via x-ray Compton scattering

K. Suzuki、B. Barbiellini、Y. Orikasa 等 12 位作者2016-01-14arXiv

Non-destructive determination of lithium distribution in a working battery is key for addressing both efficiency and safety issues. Although various techniques have been developed to map the lithium distribution in electrodes, these methods are mostly applicable to test cells. Here we propose the use of high-energy x-…

Materials ScienceChemical Physics

"Hard" crystalline lattice in the Weyl semimetal NbAs

Yongkang Luo、N. J. Ghimire、E. D. Bauer 等 5 位作者2016-01-14arXiv

We report the effect of hydrostatic pressure on the magnetotransport properties of the Weyl semimetal NbAs. Subtle changes can be seen in the $ρ_{xx}(T)$ profiles with pressure up to 2.31 GPa. The Fermi surfaces undergo an anisotropic evolution under pressure: the extremal areas slightly increase in the $\mathbf{k_x}$…

Materials ScienceStrongly Correlated ElectronsSuperconductivity

Exchange interactions and Curie temperatures of the tetrametal nitrides Cr 4 N, Mn 4 N, Fe 4 N, Co 4 N, and Ni 4 N

Markus Meinert2016-01-14Journal of Physics Condensed Matter

The exchange interactions of Cr4N, Mn4N, Fe4N, Co4N, and Ni4N compounds with perovskite structure were calculated to obtain the Curie temperatures for these compounds from Monte Carlo calculations. Contrary to naíve expectation, the exchange interactions vary markedly among these five compounds. In Fe4N, the intra-sub…

Metal and Thin Film MechanicsBoron and Carbon Nanomaterials ResearchThermal Expansion and Ionic Conductivity

Choice of tip, signal stability and practical aspects of Piezoresponse-Force-Microscopy

L. F. Henrichs、J. Bennett、A. J. Bell2016-01-14arXiv

Piezoresponse force-microscopy (PFM) has become the standard tool to investigate ferroelectrics on the micro- and nanoscale. However, reliability of PFM signals is often problematic and their quantification is challenging and thus not widely applied. Here, we present a study of the reproducibility of PFM signals and o…

Materials Sciencephysics.ins-det

Thermally triggered phononic gaps in liquids at THz scale

Dima Bolmatov、Mikhail Zhernenkov、Dmitry Zav'yalov 等 6 位作者2016-01-14arXiv

In this paper we present inelastic X-ray scattering experiments in a diamond anvil cell and molecular dynamic simulations to investigate the behavior of phononic excitations in liquid Ar. The spectra calculated using molecular dynamics were found to be in a good agreement with the experimental data. Furthermore, we ob…

Mesoscale and Nanoscale PhysicsMaterials Science

Development and Characterization of Edible Films Based on Fruit and Vegetable Residues

Roberta Melquiades Silva de Andrade、Mariana Simões Larraz Ferreira、Édira Castello Branco de Andrade Gonçalves2016-01-14Journal of Food Science

Edible films were developed from the solid residue of the processing of whole fruits and vegetables. The solid residue, processed into flour (FVR flour) was chemically and structurally characterized by microstructure, elemental composition, structural links, and moisture sorption isotherm. Films were prepared by casti…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingMicroencapsulation and Drying Processes

Two-dimensional control of light with light on metasurfaces

Maria Papaioannou、Eric Plum、J. Valente 等 5 位作者2016-01-14Light Science & Applications

The ability to control the wavefront of light is fundamental to focusing and redistribution of light, enabling many applications from imaging to spectroscopy. Wave interaction on highly nonlinear photorefractive materials is essentially the only established technology allowing the dynamic control of the wavefront of a…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsRandom lasers and scattering media

Electrochemical Capacitors with High Output Voltages that Mimic Electric Eels

Hao Sun、Xuemei Fu、Songlin Xie 等 5 位作者2016-01-14Advanced Materials

A new family of energy-storage devices is created by mimicking the electric eel to obtain a high output voltage. These novel energy-storage devices are flexible, stretchable, and weavable fibers, which satisfies the needs of next-generation portable and wearable electronics. The devices are fabricated via a continuous…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Substitutionally doped phosphorene: electronic properties and gas sensing

Nawat Suvansinpan、Fayyaz Hussain、Gang Zhang 等 6 位作者2016-01-14Nanotechnology

Phosphorene, a new elemental two-dimensional material, has attracted increasing attention owing to its intriguing electronic properties. In particular, pristine phospohorene, due to its ultrahigh surface-volume ratio and high chemical activity, has been shown to be promising for gas sensing (Abbas et al 2015 ACS Nano…

Advanced Photocatalysis Techniques2D Materials and ApplicationsMXene and MAX Phase Materials

Polyoxometalate‐Driven Self‐Assembly of Short Peptides into Multivalent Nanofibers with Enhanced Antibacterial Activity

Jingfang Li、Zhijun Chen、Mengcheng Zhou 等 10 位作者2016-01-14Angewandte Chemie International Edition

Multivalent peptide nanofibers have attracted intense attention as promising platforms, but the fabrication of those nanofibers is mainly dependent on the spontaneous assembly of β-sheet peptides. Herein we report an alternative approach to the creation of nanofibers: the polyoxometalate-driven self-assembly of short…

Polyoxometalates: Synthesis and ApplicationsSupramolecular Self-Assembly in MaterialsAdvanced Nanomaterials in Catalysis

Charge Recombination Control for High Efficiency Quantum Dot Sensitized Solar Cells

Ke Zhao、Zhenxiao Pan、Xinhua Zhong2016-01-14The Journal of Physical Chemistry Letters

Benefiting from the unique excellent optoelectronic properties of quantum dot light absorbers, quantum dot sensitized solar cell (QDSCs) are a promising candidate for the low-cost third-generation solar cells. Over the past few years, the power conversion efficiency (PCE) of QDSCs presents a rapid evolution from less…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Mapping of Low-Frequency Raman Modes in CVD-Grown Transition Metal Dichalcogenides: Layer Number, Stacking Orientation and Resonant Effects

Maria O’Brien、Niall McEvoy、Damien Hanlon 等 6 位作者2016-01-14Scientific Reports

Layered inorganic materials, such as the transition metal dichalcogenides (TMDs), have attracted much attention due to their exceptional electronic and optical properties. Reliable synthesis and characterization of these materials must be developed if these properties are to be exploited. Herein, we present low-freque…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Twisted MoSe 2 Bilayers with Variable Local Stacking and Interlayer Coupling Revealed by Low-Frequency Raman Spectroscopy

Alexander A. Puretzky、Liangbo Liang、Xufan Li 等 7 位作者2016-01-14ACS Nano

Unique twisted bilayers of MoSe2 with multiple stacking orientations and interlayer couplings in the narrow range of twist angles, 60 ± 3°, are revealed by low-frequency Raman spectroscopy and theoretical analysis. The slight deviation from 60° allows the concomitant presence of patches featuring all three high-symmet…

Perovskite Materials and Applications2D Materials and ApplicationsChalcogenide Semiconductor Thin Films

Dried and Redispersible Cellulose Nanocrystal Pickering Emulsions

Zhen Hu、Heera S. Marway、Hesham Kasem 等 5 位作者2016-01-14ACS Macro Letters

The effect of tannic acid (TA) and water-soluble cellulose derivatives on the properties of Pickering emulsions stabilized by cellulose nanocrystals (CNCs) was investigated. The potential to both fully dry CNC-stabilized emulsions and to redisperse the dried emulsions in water is demonstrated. When CNCs are mixed with…

Proteins in Food SystemsAdvanced Cellulose Research StudiesPickering emulsions and particle stabilization

Ultrathin carbon foams for effective electromagnetic interference shielding

Yang Li、Bin Shen、Xueliang Pei 等 9 位作者2016-01-14Carbon

Ultrathin carbon foams with the thickness about 24 μm were fabricated by the pyrolysis of polyimide/graphene composite foams. The addition of graphene was verified to stabilize the porous structure of the foams and accelerate their graphitization process simultaneously. Consequently, the well-defined carbon foams exhi…

Electromagnetic wave absorption materialsFlame retardant materials and propertiesAdvanced Antenna and Metasurface Technologies

Biodegradable Nanocomposite Films Based on Sodium Alginate and Cellulose Nanofibrils

B. Deepa、Eldho Abraham、Laly A. Pothan 等 6 位作者2016-01-14Materials

Biodegradable nanocomposite films were prepared by incorporation of cellulose nanofibrils (CNF) into alginate biopolymer using the solution casting method. The effects of CNF content (2.5, 5, 7.5, 10 and 15 wt %) on mechanical, biodegradability and swelling behavior of the nanocomposite films were determined. The resu…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Higher-gradient continua: The legacy of Piola, Mindlin, Sedov and Toupin and some future research perspectives

Francesco dell’Isola、Alessandro Della Corte、Ivan Giorgio2016-01-14Mathematics and Mechanics of Solids

Since the first studies dedicated to the mechanics of deformable bodies (by Euler, D’Alembert, Lagrange) the principle of virtual work (or virtual velocities) has been used to provide firm guidance to the formulation of novel theories. Gabrio Piola dedicated his scientific life to formulating a continuum theory in ord…

Composite Material MechanicsThermoelastic and Magnetoelastic PhenomenaNonlocal and gradient elasticity in micro/nano structures

Highly Transparent Wafer-Scale Synthesis of Crystalline WS2 Nanoparticle Thin Film for Photodetector and Humidity-Sensing Applications

Amit Pawbake、Ravindra Waykar、Dattatray J. Late 等 4 位作者2016-01-14ACS Applied Materials & Interfaces

In the present investigation, we report a one-step synthesis method of wafer-scale highly crystalline tungsten disulfide (WS2) nanoparticle thin film by using a modified hot wire chemical vapor deposition (HW-CVD) technique. The average size of WS2 nanoparticle is found to be 25-40 nm over an entire 4 in. wafer of qua…

2D Materials and ApplicationsGas Sensing Nanomaterials and SensorsMXene and MAX Phase Materials

Filtration Shell Mediated Power Density Independent Orthogonal Excitations–Emissions Upconversion Luminescence

Xiaomin Li、Zhenzhen Guo、Tiancong Zhao 等 7 位作者2016-01-14Angewandte Chemie International Edition

Lanthanide doped core-multishell structured NaGdF4:Yb,Er@NaYF4:Yb@NaGdF4:Yb,Nd@NaYF4@NaGdF4:Yb,Tm@NaYF4 nanoparticles with power-density independent orthogonal excitations-emissions upconversion luminescence (UCL) were fabricated for the first time. The optical properties of these core-multishell structured nanopartic…

Luminescence Properties of Advanced MaterialsSolid State Laser TechnologiesLuminescence and Fluorescent Materials

Light‐Directed Dynamic Chirality Inversion in Functional Self‐Organized Helical Superstructures

Hari Krishna Bisoyi、Quan Li2016-01-14OpenAlex

Helical superstructures are widely observed in nature, in synthetic polymers, and in supramolecular assemblies. Controlling the chirality (the handedness) of dynamic helical superstructures of molecular and macromolecular systems by external stimuli is a challenging task, but is of great fundamental significance with…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry