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Achieving very bright mechanoluminescence from purely organic luminophores with aggregation-induced emission by crystal design

Bingjia Xu、Wenlang Li、Jiajun He 等 14 位作者2016-01-01Chemical Science

Although bright organic mechanoluminescence (ML) has been observed for a few luminophores with aggregation-induced emission (AIE), details of the positive effect of AIE on ML performance remain unclear and a feasible design principle for AIE-ML compounds has not yet been presented. Herein, an effective strategy for th…

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Unraveling the aggregation effect on amorphous phase AIE luminogens: a computational study

Xiaoyan Zheng、Qian Peng、Lizhe Zhu 等 6 位作者2016-01-01Nanoscale

To achieve the efficient and precise regulation of aggregation-induced emission (AIE), unraveling the aggregation effects on amorphous AIE luminogens is of vital importance. Using a theoretical protocol combining molecular dynamics simulations and quantum mechanics/molecular mechanics calculations, we explored the rel…

Organic Light-Emitting Diodes ResearchPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Fabrication of durable anticorrosion superhydrophobic surfaces on aluminum substrates via a facile one-step electrodeposition approach

Binbin Zhang、Xia Zhao、Yantao Li 等 4 位作者2016-01-01RSC Advances

A facile one-step electrodeposition method was used to fabricate a hierarchical papillae-covered SHPS on an Al substrate with enhanced corrosion resistance (corrosion inhibition efficiency ~99.96%) and lotus-like self-cleaning effect.

Corrosion Behavior and InhibitionSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Graphene-based fabrics and their applications: a review

J. Molina2016-01-01RSC Advances

This review covers the up-to-date synthesis and applications of graphene-based fabrics obtained by chemical coating or by chemical vapor deposition.

Graphene research and applicationsSupercapacitor Materials and FabricationGraphene and Nanomaterials Applications

Ultra-high thermally conductive and rapid heat responsive poly(benzobisoxazole) nanocomposites with self-aligned graphene

Weifeng Zhao、Jie Kong、Hu Liu 等 6 位作者2016-01-01Nanoscale

Self-alignment of thermally reduced graphene sheets (TRG) that enable highly efficient heat transfer paths in their poly(p-phenylene benzobisoxazole) (PBO)-based nanocomposite films along the in-plane direction was achieved for the first time without any assistance of an external magnetic or an electric field. In the…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Development of efficient electrocatalysts via molecular hybridization of NiMn layered double hydroxide nanosheets and graphene

Wei Ma、Renzhi Ma、Jinghua Wu 等 7 位作者2016-01-01Nanoscale

Ni(2+)Mn(3+) layered double hydroxide (LDH) nanoplatelets have been hydrothermally synthesized in a homogeneous precipitation of mixed Ni(2+)/Mn(2+) salts at a molar ratio of 2 : 1 via the hydrolysis of hexamethylenetetramine (HMT) and in situ oxidation with H2O2. After anion-exchange, NiMn LDH was exfoliated into uni…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Synthesis of fluorescent nitrogen-doped carbon dots from dried shrimps for cell imaging and boldine drug delivery system

Stephanie L. D’souza、Balaji Deshmukh、Jigna R. Bhamore 等 6 位作者2016-01-01RSC Advances

Fluorescent N-doped carbon dots were synthesized using dried shrimps as precursors and rationally fabricated as a traceable drug delivery system for the targeted delivery of boldine to human breast cancer cells (MCF-7 cells).

Luminescence and Fluorescent MaterialsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Carbon nanotube fibers and films: synthesis, applications and perspectives of the direct-spinning method

Dawid Janas、Krzysztof Kozioł2016-01-01Nanoscale

The direct-spinning method of creation of CNT macroassemblies has received a lot of attention because of its simplicity to produce high-performance material without apparent limits to its size. CNT fibers or films have shown unparalleled properties and opened new areas of research and commercial development. The proce…

Carbon Nanotubes in CompositesGraphene research and applicationsFiber-reinforced polymer composites

Proposing the prospects of Ti 3 CN transition metal carbides (MXenes) as anodes of Li-ion batteries: a DFT study

Xingzhu Chen、Zhouzhou Kong、Neng Li 等 5 位作者2016-01-01Physical Chemistry Chemical Physics

, Li-F formed a six-membered ring with increasing Li concentration, thereby making the system more stable. This work contributes to offering perspectives for carbonitride systems (MXenes) as LIB anodes.

Advancements in Battery Materials2D Materials and ApplicationsMXene and MAX Phase Materials

Mechanical properties of monolayer penta-graphene and phagraphene: a first-principles study

Hao Sun、Sankha Mukherjee、Chandra Veer Singh2016-01-01Physical Chemistry Chemical Physics

Two new graphene allotropes, penta-graphene and phagraphene, have been proposed recently with unique electronic properties, <italic>e.g.</italic> quasi-direct band gap, direction-dependent Dirac cones and tunable Fermi velocities.

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

Multifunctional redox-tuned viologen-based covalent organic polymers

Gobinda Das、Thirumurugan Prakasam、Selbi Nuryyeva 等 11 位作者2016-01-01Journal of Materials Chemistry A

The immobilization of molecular switches within materials can give rise to new bulk properties that are useful for a variety of applications.

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Role of oxygen vacancies in crystalline WO 3

Wennie Wang、Anderson Janotti、Chris G. Van de Walle2016-01-01Journal of Materials Chemistry C

We demonstrate that oxygen vacancies act as shallow donors in WO <sub>3</sub> , suggesting carriers in the conduction band (CB) mediate electrochromism.

Gas Sensing Nanomaterials and SensorsAdvanced Memory and Neural ComputingTransition Metal Oxide Nanomaterials

Tin/vanadium redox electrolyte for battery-like energy storage capacity combined with supercapacitor-like power handling

Juhan Lee、Benjamin Krüner、Aura Tolosa 等 8 位作者2016-01-01Energy & Environmental Science

We introduce a high performance hybrid electrochemical energy storage system based on an aqueous electrolyte containing tin sulfate (SnSO <sub>4</sub> ) and vanadyl sulfate (VOSO <sub>4</sub> ) with nanoporous activated carbon.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

A photoluminescent covalent triazine framework: CO 2 adsorption, light-driven hydrogen evolution and sensing of nitroaromatics

Asamanjay Bhunia、Dolores Esquivel、Subarna Dey 等 8 位作者2016-01-01Journal of Materials Chemistry A

Porous PCTF-8 has a fluorescence quantum yield of 31% which is quenched by trinitrophenol, and Pt@PCTF-8 yields H <sub>2</sub> with visible light.

Advanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

pH-Sensitive nanogates based on poly( l -histidine) for controlled drug release from mesoporous silica nanoparticles

Panayiotis Bilalis、Leto‐Aikaterini Tziveleka、Spyridon Varlas 等 4 位作者2016-01-01Polymer Chemistry

Mesoporous silica nanoparticles (MSNs) bearing poly( <sc>l</sc> -histidine)-grafted nanogates were prepared by surface-initiated ROP. The obtained polypeptide-functionalized MSNs were used as smart pH-responsive nanocarriers for controlled drug release applications.

Nanoparticle-Based Drug DeliveryMesoporous Materials and CatalysisDendrimers and Hyperbranched Polymers

Chitosan: A promising marine polysaccharide for biomedical research

AhmadSukari Halim、MercyHalleluyah Periayah、Arman Zaharil Mat Saad2016-01-01Pharmacognosy Reviews/Bioinformatics Trends/Pharmacognosy review

Biomaterials created 50 years ago are still receiving considerable attention for their potential to support development in the biomedical field. Diverse naturally obtained polysaccharides supply a broad range of resources applicable in the biomedical field. Lately, chitosan, a marine polysaccharide derived from chitin…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsStudies on Chitinases and Chitosanases

Nacre-inspired integrated strong and tough reduced graphene oxide–poly(acrylic acid) nanocomposites

Sijie Wan、Han Hu、Jingsong Peng 等 7 位作者2016-01-01Nanoscale

Inspired by the relationship between interface interactions and the high performance mechanical properties of nacre, a strong and tough nacre-inspired nanocomposite was demonstrated based on graphene oxide (GO) and polyacrylic acid (PAA) prepared via a vacuum-assisted filtration self-assembly process. The abundant hyd…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionPickering emulsions and particle stabilization

Pd–In intermetallic alloy nanoparticles: highly selective ethane dehydrogenation catalysts

Zhenwei Wu、Evan C. Wegener、Han-Ting Tseng 等 9 位作者2016-01-01Catalysis Science & Technology

2 nm PdIn intermetallic alloy (cubic, CsCl type) nanoparticle catalyst was near 100% selective to ethane dehydrogenation at 600 °C (at 15% conversion) with a dehydrogenation TOR almost 10 times higher than that of monometallic Pd.

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions