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A simple mechanism for emergent chirality in achiral hard particle assembly

Scott P. Carmichael、M. Scott Shell2013-10-25The Journal of Chemical Physics

For centuries, chirality has been appreciated as a key component in understanding how matter orders. While intuitively chiral particles can self-assemble into chiral superstructures, it is often less obvious how achiral particles can do the same. Here we show that there is a potentially general, packing-based mechanis…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Optimizing Established Processes like Sugar Extraction from Sugar Beets – Design of Experiments versus Physicochemical Modeling

Simon Both、J. Eggersglüß、Andreas Lehnberger 等 6 位作者2013-10-25Chemical Engineering & Technology

Abstract Extraction of sugar from sugar beets is a process optimized over decades based on experience gathered during production. This process improvement is achieved without any systematic approach for optimization which raised the question whether such a mature process can be further optimized effectively, applying…

Microbial Metabolic Engineering and BioproductionCrystallization and Solubility StudiesFood Chemistry and Fat Analysis

Optimization of bioplastic (poly--hydroxybutyrate) production by a promising Azomonas macrocytogenes bacterial isolate P173

Salah Elsayed Noha、M Aboshanab Khaled、M Aboulwafa Mohammad 等 4 位作者2013-10-25African Journal of Microbiology Research

An extensive screening program was previously done to isolate a promising bacterial isolate Azomonas macrocytogenes isolate P173 capable of polyhydroxybutyrate (PHB) production. It produced 24% PHB per dry weight after 48 h. In this study, several experiments were designed to optimize the composition of the…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCarbon dioxide utilization in catalysis

Structural transition of zinc oxide cluster cations: Smallest tube like structure at (ZnO)6+

Kiichirou Koyasu、Kunihiko Komatsu、Fuminori Misaizu2013-10-25The Journal of Chemical Physics

Zinc oxide cluster cations have been analyzed by ion mobility spectrometry using a home-made drift cell combined with a time-of-flight reflectron mass spectrometer. Structural changes from cyclic to tube like structures were observed around n = 8, corresponding to predictions by theoretical calculations. The structure…

ZnO doping and propertiesMass Spectrometry Techniques and ApplicationsIon-surface interactions and analysis

Simultaneous optimization of the mechanical properties of postconsumer natural fiber/plastic composites: Phase compatibilization and quality/cost ratio

Jean Luc Toupe、Albert Trokourey、Denis Rodrigue2013-10-25Polymer Composites

In this work, a simultaneous optimization by phase compatibilization of four mechanical proprieties (flexural and tensile moduli, impact strength, and tensile stress at yield) of natural fiber/plastic composites was performed with respect to raw materials cost. In particular, a recycled resin of postconsumer origin (b…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesMechanical Engineering and Vibrations Research

Interaction mechanisms of screw dislocations with and twin boundaries in Mg

Motohiro Yuasa、Kohei Masunaga、Mamoru Mabuchi 等 4 位作者2013-10-25The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Molecular dynamics simulations were carried out to investigate the interactions between screw partials and the and twin boundaries in Mg. In the twin, the interaction was attractive and the partials were absorbed readily in the boundary. In the twin, however, they passed through the twin boundary because of a repulsiv…

Microstructure and mechanical propertiesMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Synthesis of silver nanoparticles using Cardiospermum halicacabum L. leaf extract and their characterization

Mahipal S. Shekhawat、M. Manokari、N. Kannan 等 5 位作者2013-10-25The Journal of Phytopharmacology

Present study reports the biogenesis of silver nanoparticles from the leaves of Cardiospermum halicacabum L. and their characterization. C. halicacabum has been used in traditional medicines but so far it has not been tested for synthesis of silver nanoparticles (AgNPs). The aqueous silver ions exposed to the herbal e…

Nanoparticles: synthesis and applicationsNanotechnology research and applications

Development of microbial resistant Carbopol nanocomposite hydrogels via a green process

Kokkarachedu Varaprasad、Goddeti Siva Mohan Reddy、J. Jayaramudu 等 6 位作者2013-10-25Biomaterials Science

The present scientific research resulted in the development of novel microbial resistant inorganic nanocomposite hydrogels, which can be used as antibacterial agents. They are promising candidates for advanced antimicrobial applications in the field of biomedical science. Novel inorganic nanocomposite hydrogels were d…

Nanoparticles: synthesis and applicationsHydrogels: synthesis, properties, applicationsGraphene and Nanomaterials Applications

Surface resistivity and mechanical properties of rotationally molded polyethylene/graphite composites

Washington Mhike、Walter W. Focke2013-10-25Journal of Vinyl and Additive Technology

Antistatic polymers are required to dissipate static charges safely from component surfaces. Our overall objective has been to develop cost‐effective flame‐retarded and antistatic polyethylene compounds suitable for rotomolding. This communication considers the surface resistivity and mechanical properties of rotation…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

A Series of Weak Ferromagnets Based on a Chromium–Acetylide–TTF Type Complex: Correlation of the Structures and Magnetic Properties and Origin of the Weak Ferromagnetism

Junichi Nishijo、Masaya Enomoto2013-10-25Inorganic Chemistry

The crystal structures and magnetic properties of a series of new weak ferromagnets containing a chromium-acetylide-tetrathiafulvalene (TTF) type complex, [CrCyclam(C≡C-5-methyl-4'5'-ethylenedithio-TTF)2](2+) ([1](2+)), were investigated. The six new isostructural weak ferromagnets [1][BF4]2(PhF)2(MeCN), [1][ClO4]2(Ph…

Magnetism in coordination complexesCrystal Structures and PropertiesOrganic and Molecular Conductors Research

The Influence of Carbon Nanotube Aspect Ratio on Thermal Conductivity Enhancement in Nanotube–Polymer Composites

Rahul S. Kapadia、Brian M. Louie、Prabhakar R. Bandaru2013-10-25ASME Journal of Heat and Mass Transfer

We report and model a linear increase in the thermal conductivity (κ) of polymer composites incorporated with relatively low length/diameter aspect ratio multiwalled carbon nanotubes (CNTs). There was no evidence of percolation-like behavior in the κ, at/close to the theoretically predicted threshold, which was attrib…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Multi‐Length Scale Porous Polymers

Ryu Takekoh、Thomas P. Russell2013-10-25Advanced Functional Materials

Thin films with porosities spanning from the nanoscopic to the macroscopic are obtained by combining breath figures (BFs), micrometer‐sized surface cavities arising from the condensation of water on the surface of a film as solvent evaporates rapidly, with the nanoscopic morphology inherent to block copolymers. Using…

Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-AssemblyNanopore and Nanochannel Transport Studies

Coupling of HPLC with Electrospray Ionization Mass Spectrometry for Studying the Aging of Ultrasmall Multifunctional Gadolinium-Based Silica Nanoparticles

Charles Truillet、François Lux、Olivier Tillement 等 5 位作者2013-10-25Analytical Chemistry

Sub-5 nm multimodal nanoparticles have great potential for theranostic applications due to their easy renal elimination combined with complementary imaging properties and therapeutic facilities. Their potential clinical use requires the full characterization of not only the nanoparticle but also all its possible degra…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Copper(II) removal from aqueous solutions by adsorption on non-treated and chemically modified cactus fibres

Melpomeni Prodromou、Ioannis Pashalidis2013-10-25Water Science & Technology

The adsorption efficiency of a biomass by-product (cactus fibres) regarding the removal of copper(II) from aqueous solutions has been investigated before and after its chemical treatment. The chemical treatment of the biomass by-product included phosphorylation and MnO2-coating. The separation/removal efficiency has b…

Adsorption and biosorption for pollutant removalPickering emulsions and particle stabilizationBotanical Research and Applications

The influence of feed rate and shear forces on the devulcanization process of ground tire rubber (GTR) conducted in a co-rotating twin screw extruder

Krzysztof Formela、M. Cysewska、Józef T. Haponiuk 等 4 位作者2013-10-25Polimery

The search for new ways to recycling of rubber waste has been the aim of many studies conducted by research centers and companies worldwide. The results of our investigations on the process of continuous thermomechanical devulcanization of ground tire rubber using a twin screw extruder are presented. We used a co-rota…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesAdvanced Theoretical and Applied Studies in Material Sciences and Geometry

Flame retardant and thermal decomposition properties of flexible polyurethane foams filled with several halogen‐free flame retardants

Chengqun Wang、Hai‐Ning Lv、Jie Sun 等 4 位作者2013-10-25Polymer Engineering and Science

Expandable graphite (EG), dimethyl methylphosphonate (DMMP), melamine (MEL), zinc borate (ZB), or magnesium hydroxide (MH) was separately added to polyurethane to form flame retardant flexible polyurethane foam (FPUF) in one‐step. The cell morphologies of the FPUF composites before and after burning were observed by s…

Fire dynamics and safety researchFlame retardant materials and propertiesEnvironmental and Industrial Safety

Novel Ti–Zr–Hf–Fe Nanostructured Alloy for Biomedical Applications

Anna Hynowska、Andreu Blanquer、Eva Pellicer 等 11 位作者2013-10-25Materials

The synthesis and characterization of Ti40Zr20Hf20Fe20 (atom %) alloy, in the form of rods (f = 2 mm), prepared by arc-melting, and subsequent Cu mold suction casting, is presented. The microstructure, mechanical and corrosion properties, as well as in vitro biocompatibility of this alloy, are investigated. This mater…

Metal and Thin Film MechanicsTitanium Alloys Microstructure and PropertiesAdvanced materials and composites

Photoconductivities in monocrystalline layered V2O5 nanowires grown by physical vapor deposition

Ruei‐San Chen、Wenchun Wang、Ching‐Hsiang Chan 等 6 位作者2013-10-25Nanoscale Research Letters

Photoconductivities of monocrystalline vanadium pentoxide (V2O5) nanowires (NWs) with layered orthorhombic structure grown by physical vapor deposition (PVD) have been investigated from the points of view of device and material. Optimal responsivity and gain for single-NW photodetector are at 7,900 A W-1 and 30,000, r…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Isotopic13C/12C effect on the resonant Raman spectrum of twisted bilayer graphene

E. del Corro、Martin Kalbáč、Cristiano Fantini 等 5 位作者2013-10-25Physical Review B

In this work we report a Raman study of bilayer graphene in which one layer is of natural isotope composition and the other layer is enriched by the ${}^{13}$C isotope. We use different laser lines in the visible range in order to provide the resonant Raman profiles and to analyze the dispersion with energy of all the…

Carbon Nanotubes in CompositesGraphene research and applicationsGraphene and Nanomaterials Applications

Enhancement of Quantum Dot Förster Resonance Energy Transfer within Paper Matrices and Application to Proteolytic Assays

Hyungki Kim、Eleonora Petryayeva、W. Russ Algar2013-10-25IEEE Journal of Selected Topics in Quantum Electronics

Brightly luminescent semiconductor quantum dots (QDs) continue to play an increasing role in biophotonic research and applications such as bioassays. Here, we present methods for the immobilization of QDs on the cellulose fibers of paper substrates for Förster resonance energy transfer (FRET)-based assays of proteolyt…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesBiosensors and Analytical Detection