Materials Literature
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Developing carriers comprised of biomaterials and capable of withstanding significant mechanical pressures, structural deformations and at the same time delivering biomolecules is of high interest for drug delivery. Using colloidal probe AFM combined with quantitative fluorescence microscopy, we investigated mechanica…
Silicate glasses are used as containment matrices for deep geological disposal of nuclear waste arising from spent fuel reprocessing. Understanding the dissolution mechanisms of glasses in contact with iron, an element present in large amounts in the immediate environment (overpack, claystone, etc.) would be a major b…
An assemblage of a Tb(III) ion and two mononuclear [Zn(II)(L)] complexes as antenna chromophores (H(2)L: Schiff base ligand) afforded a luminescent single-molecule magnet. The f-f emission spectrum had partially resolved fine structure which provides detailed information on the magnetic anisotropy of the (7)F(6) groun…
The formation of high-density zinc oxide (ZnO) nanorods on porous silicon (PS) substrates at growth temperatures of 600–1000 °C by a simple thermal evaporation of zinc (Zn) powder in the presence of oxygen (O2) gas was systematically investigated. The high-density growth of ZnO nanorods with (0002) orientation over a…
Metalation of ethanethiol by [{(Me 3 Si) 2 N} 3 Ln(μ-Cl)Li(thf) 3 ] (Ln = Gd, Tb, Dy) in thf produces the thiolate-bridged tetralanthanide compounds [Li(thf) 4 ][Ln 4 {N(SiMe 3 ) 2 } 4 (μ-SEt) 8 (μ 4 -SEt)], where Ln = Gd is [Li(thf) 4 ][ 1 ], Ln = Tb is [Li(thf) 4 ][ 2 ], and Ln = Dy is [Li(thf) 4 ][ 3 ]. Crystallogr…
First-principles calculations have been performed to study Au-decorated silicene (Au/silicene) as a high-activity catalyst for CO oxidation. The high binding strength of the Au/silicene system and the high diffusion-energy barrier of Au adsorbates, as well as the assisted Coulomb repulsion effect, jointly prevent the…
Aluminum (Al) films with thickness of 100 nm were grown on unheated glass, silicon and mica substrates by electron beam evaporation. The deposition rates were adjusted in the range between 0.1 nm/s and 2 nm/s, the pressure in the vacuum chamber during deposition was lower than 1·10–3 Pa. The structure and surface mor…
Au@Pt nanorods were prepared by growing platinum nanodots on gold nanorods. Using electron spin resonance (ESR), we determined that the mechanisms for oxidation of ascorbic acid (AA) by Au@Pt nanorods and ascorbic acid oxidase (AAO) were kinetically similar and yielded similar products. In addition we observed that Au…
Direct electrochemical templating is carried out using a thin layer of a self-assembled diamond phase (QIID) of phytantriol to create a platinum film with a novel nanostructure. Small-angle X-ray scattering shows that the nanostructured platinum films are asymmetrically templated and exhibit “single diamond” morpholog…
The use of plasmonic nanoparticle complexes for biomedical applications such as imaging, gene therapy, and cancer treatment is a rapidly emerging field expected to significantly improve conventional medical practices. In contrast, the use of these types of nanoparticles to noninvasively trigger biochemical pathways ha…
We show that subterahertz transmission of the superconducting metamaterial, an interlinked two-dimensional network of subwavelength resonators connected by a continuous superconducting wire loop, can be dynamically modulated by passing electrical current through it. We have identified the main mechanisms of modulation…
PURPOSE: This study aimed to quantitatively investigate two main magnetization transfer effects at low B1: the nuclear Overhauser enhancement (NOE) and amide proton transfer in the human brain at 7 T. METHODS: The magnetization transfer effects in the human brain were characterized using a four-pool proton model, whic…
The synthesis and utilization of mesoporous Cu ‐ MCM ‐41 catalysts for hydrogenation of dimethyl oxalate to ethylene glycol is described in this article. Physicochemical properties of these Cu ‐ MCM ‐41 catalysts have been investigated by N 2 ‐physisorption, X ‐ray diffraction, inductively coupled plasma, N 2 O titrat…
Block copolymer self-assembled thin films formed at the surface of chemically modified graphene films are successfully transferred and utilized for the nanoscale patterning of various flexible and nonplanar geometries.
The size of nanocrystals provides a limitation on dislocation activity and associated stress-induced deformation. Dislocation-mediated plastic deformation is expected to become inactive below a critical particle size, which has been proposed to be between 10 and 30 nanometers according to computer simulations and tran…
Lately, there has been a growing interest in anticancer therapy with a combination of different drugs that work by different mechanisms of action, which decreases the possibility that resistant cancer cells will develop. Herein we report on the development of a drug delivery system for photosensitive delivery of a kno…
We present the first investigation on the effect of highly charged ion bombardment on a manganese arsenide thin film. The MnAs films, 150 nm thick, are irradiated with 90 keV Ne$^{9+}$ ions with a dose varying from $1.6\times10^{12}$ to $1.6\times10^{15}$ ions/cm$^2$. The structural and magnetic properties of the film…
We present a combined x-ray and neutron reflectivity study characterizing the interface between polystyrene (PS) and silanized surfaces. Motivated by the large difference in slip velocity of PS on top of dodecyl-trichlorosilane (DTS) and octadecyl-trichlorosilane (OTS) found in previous studies, these two systems were…
We report the first experimental observation of the spin Seebeck effect in magnetite thin films. The signal observed at temperatures above the Verwey transition is a contribution from both the anomalous Nernst (ANE) and spin Seebeck effects (SSE). The contribution from the ANE of the Fe3O4 layer to the SSE is found to…
All-spin logic devices are promising candidates to augment and complement beyond-CMOS integrated circuit computing due to non-volatility, ultra-low operating voltages, higher logical efficiency, and high density integration. However, the path to reach lower energy-delay product performance compared to CMOS transistors…