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Synthesis and characterization of [1,4-bis(α,β-galactopyranos-6-yl)phthalocyaninato]zinc(II)

Göran Crucius、Michael Hanack、Thomas Ziegler2013-05-10Journal of Porphyrins and Phthalocyanines

Herein we present the synthesis and full characterization of the water-soluble [1,4-bis(α,β-galactopyranos-6-yl)phthalocyaninato]zinc(II) (8). For a cross-condensation with phthalonitrile in presence of zinc bromide, bisglycosylated phthalonitrile (5) has been synthesized by nucleophilic displacement of triflyl groups…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Structure and functional studies of the ribonuclease binase Glu43Ala/Phe81Ala mutant

Vladimir A. Mitkevich、Alexey Schulga、A.A. Trofimov 等 8 位作者2013-05-10Acta Crystallographica Section D Biological Crystallography

Ribonuclease from Bacillus intermedius (binase) is a small basic protein with antitumour activity. The three-dimensional structure of the binase mutant form Glu43Ala/Phe81Ala was determined at 1.98 Å resolution and its functional properties, such as the kinetic parameters characterizing the hydrolysis of polyinosinic…

Protein Structure and DynamicsBacterial Genetics and BiotechnologyEnzyme Structure and Function

Enhancements to Modeling Dry Fabrics for Impact Analysis

A. Deivanayagam、Aditya Vaidya、Subramaniam Rajan2013-05-10Journal of Aerospace Engineering

The focus of this paper is on improving the modeling of dry fabric-based systems widely used in propulsion engine containment systems. Simulations of fabrics under impact using finite elements (FEs) provide valuable insight into the mechanics of fabric behavior and its energy absorption characteristics. In this model,…

Mechanical Behavior of CompositesHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Stress biaxiality in high-burnup PWR fuel cladding under reactivity-initiated accident conditions

Yutaka Udagawa、Tomoyuki Sugiyama、Motoe Suzuki 等 4 位作者2013-05-10Journal of Nuclear Science and Technology

In order to promote a better understanding of failure mechanisms of high-burnup pressurized water reactor (PWR) fuels under reactivity-initiated accident (RIA) conditions, stress biaxiality in cladding has been estimated for the pellet-cladding (PC) mechanical interaction (PCMI) phase. The estimation was based on an a…

High Temperature Alloys and CreepNuclear Materials and PropertiesHigh-Velocity Impact and Material Behavior

Effect of Mg(OH) 2 nanoparticles on thermal, mechanical and morphological properties of millable polyurethane elastomer

Navinchandra G. Shimpi、Harishchandra A. Sonawane、Ananda D Mali 等 4 位作者2013-05-10Journal of Reinforced Plastics and Composites

Millable polyurethane (MPU) rubber nanocomposites were prepared on a two-roll mill and molded on a compression molding machine. The amount of loading of Mg(OH) 2 nanoparticles ( nMg(OH) 2 ) was from 0.5 to 2.5 wt% followed by the addition of dicumyl peroxide (as a curing agent). The compounded matter was subjected to…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingMagnesium Oxide Properties and Applications

Observations of the genusDiploneisfrom Lake Ohrid, Macedonia

Elena Jovanovska、Teofil Nakov、Zlatko Levkov2013-05-10Diatom Research

Lake Ohrid is an important biodiversity hotspot, including diatom diversity and endemism. Numerous, putatively endemic diatom species have been described from the lake, alongside reports of relict taxa otherwise known only as fossils from European Neogene deposits. Diploneis Ehrenberg ex Cleve is considered to be one…

Diatoms and Algae ResearchAquatic Invertebrate Ecology and BehaviorMarine and environmental studies

A Thermoresponsive Hydrogel Formed from a Star–Star Supramolecular Architecture

Zhong‐Xing Zhang、Kerh Li Liu、Jun Li2013-05-10Angewandte Chemie

Stern mit Hirn: Eine neuartige supramolekulare Architektur wurde aus einem sternförmigen achtarmigen Polyethylenglycol mit Adamantyl-Endgruppen und einem sternförmigen Poly(N-isopropylacrylamid) mit β-Cyclodextrin-Kern durch Einschlusskomplexierung erhalten. Die Stern-Stern-Supramoleküle bilden wiederum temperaturabhä…

Hydrogels: synthesis, properties, applicationsMesoporous Materials and CatalysisSupramolecular Self-Assembly in Materials

Kinetics and thermodynamics of the ferroelectric transitions in PbMg1/3Nb2/3O3 and PbMg1/3Nb2/3O3-12% PbTiO3 crystals

Eugene V. Colla、N. Jurik、Yehan Liu 等 7 位作者2013-05-10Journal of Applied Physics

The two-step freezing and melting of the field-induced ferroelectric order in PbMg1/3Nb2/3O3 (PMN) and (PbMg1/3Nb2/3O3)0.88(PbTiO3)0.12 (PMN-PT) is investigated. In PMN-PT, direct microscopic images show that both steps occur in the same spatial regions. The higher temperature freezing corresponds to the higher temper…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Cherenkov radiation in a metamaterial comprised of coated wires

Andrey V. Tyukhtin、Viktor V. Vorobev2013-05-10Journal of the Optical Society of America B

The electromagnetic field of a point charge moving in a “wire metamaterial” parallel to the wires is investigated. The metamaterial under consideration is a periodic structure of perfect conductors with a dielectric or magnetic coating. The spacing of the structure is assumed to be much less than the typ…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Effect of chemico‐mineralogical composition on color of natural and calcined kaolins

Nedjima Bouzidi、Siham Aissou、Nicolas Concha‐Lozano 等 7 位作者2013-05-10Color Research & Application

Abstract A total of six washed French and Algerian kaolins were studied. Kaolinite, halloysite, muscovite, feldspars, anatase, rutile, gibbsite, goethite, and todorokite were present. The thermal behavior of the samples was studied and the transformation heats were determined and quantified by differential thermal ana…

Clay minerals and soil interactionsIron oxide chemistry and applicationsMineralogy and Gemology Studies

High-sensitivity SrTiO3 photodetectors with paralleled multiple interdigital electrode cells

Le Wang、Kuijuan Jin、Jie Xing 等 7 位作者2013-05-10Applied Optics

We report high-sensitivity SrTiO(3) photoconductive detectors with multiple photoelectric cells connected in parallel. The photocurrent of the detectors increases significantly with an increase of the cell number. The photocurrent responsivity of the detector with three cells can reach 237 mA/W at 10 V bias under illu…

Gas Sensing Nanomaterials and SensorsGa2O3 and related materialsElectronic and Structural Properties of Oxides

Ultraviolet/visible photodiode of nanostructure Sn–doped ZnO/Si heterojunction

N. Kheirandish、Abdollah Mortezaali2013-05-10Journal of Applied Physics

Sn doped ZnO nanostructures deposited on Si substrate with (100) orientation by spray pyrolysis method at temperature 450 °C. Sn/Zn atomic ratio varies from 0% to 5%. The scanning electron microscope measurements showed that size of particles reduce with increasing the doping concentration. The X-ray diffraction analy…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Highly scalable nanoparticle–polymer composite fiber via wet spinning

Roland Stone、Stephen James Hipp、Joel Barden 等 5 位作者2013-05-10Journal of Applied Polymer Science

ABSTRACT Magnetic nanoparticles have continued to gather the interest of researchers due to the unique physical properties of materials found at this size scale. Herein, the production of composite magnetic fibers composed of iron oxide nanoparticles suspended in alginate is described. These materials were produced vi…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics

Nanostructured Biomaterials and Their Applications

Kirsten Parratt、Nan Yao2013-05-10Nanomaterials

Some of the most important advances in the life sciences have come from transitioning to thinking of materials and their properties on the nanoscale rather than the macro or even microscale. Improvements in imaging technology have allowed us to see nanofeatures that directly impact chemical and mechanical properties o…

Bone Tissue Engineering MaterialsPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Two important mechanisms damaging KH2PO4 crystal processed by ultraprecision fly cutting and their relationships with cutting parameters

Mingquan Li、Mingjun Chen、Jian Cheng 等 5 位作者2013-05-10Applied Optics

Mid-frequency waviness and subsurface crack are two fundamental factors that damage KH(2)PO(4) (KDP) crystal processed by ultraprecise fly cutting. In this paper, the motif theory and the Fourier model method are used to analyze the influence of the two factors on the laser-induced damage threshold (LIDT) of KDP. Rese…

Nonlinear Optical Materials ResearchCrystallization and Solubility StudiesThermal and Kinetic Analysis

Effect of strain on the evolution of magnetic multi-vortices in ferromagnetic nano-platelets

Jie Wang、Jianwei Zhang、Takahiro Shimada 等 4 位作者2013-05-10Journal of Physics Condensed Matter

The effect of external strain on the evolution of magnetic multi-vortices in nanoscale ferromagnetic platelets is investigated by a phase field model that explicitly includes the coupling between the magnetization and deformation. Phase field simulations show that a compressive strain makes the magnetic vortex-antivor…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsCharacterization and Applications of Magnetic Nanoparticles

The afterglow characteristics and trap level distribution of chromatic rare-earth luminous fiber

Xuefeng Guo、Mingqiao Ge2013-05-10Textile Research Journal

The samples of luminous fiber with different colors have been prepared by adding the fiber-forming polymer PET chips as base materials and SrAl 2 O 4 : Eu 2+ , Dy 3+ luminescent materials. The phase composition, afterglow decay and thermoluminescent characteristics of the fiber were measured by X-ray diffraction (XRD)…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesLuminescence and Fluorescent Materials

Effects of PVP and CTAB surfactants on the morphology of cerium oxide nanoparticles synthesized via co-precipitation method

Ata Chitsaz、Marzieh Jalilpour、Mohammad Fathalilou2013-05-10International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract This paper reports the synthesis and characterization of CeO 2 nanoparticles via a simple and cost-effective co-precipitation method using cerium (III) nitrate hexahydrate, ammonium carbonate, cetyltrimethylammonium bromide (CTAB) and polyvinyl pyrrolidone (PVP) as the starting chemicals. The precursor was ca…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsCopper-based nanomaterials and applications

A versatile, one-pot synthesis of gold nanostars with long, well-defined thorns using a lyotropic liquid crystal template

S. Umadevi、H. C. Lee、V. Ganesh 等 5 位作者2013-05-10Liquid Crystals

We describe a simple, one-pot, silver-assisted synthesis of branched gold nanoparticles (GNPs) (nanostars) using Ag NO3 and the mild reducing agent, ascorbic acid, in the presence of a lyotropic liquid crystal (LLC) template formed by Triton X-100 in water either in the hexagonal phase or the micellar phase above the…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesPickering emulsions and particle stabilization

Dielectric and mechanical properties of diglycidyl ether of bisphenol a modified by a new fluoro‐terminated hyperbranched poly(phenylene oxide)

Lijuan Luo、Yan Meng、Teng Qiu 等 7 位作者2013-05-10Polymer Composites

Diglycidyl ether of bisphenol A (DGEBA)/fluoro‐terminated hyperbranched poly(phenylene oxide) (FHPPO) composites with improved mechanical and dielectric performances were prepared by blending a FHPPO with DGEBA. The low‐polarity building blocks, abundant fluorinated terminal groups, and the inherent free volume brough…

Fiber-reinforced polymer compositesSynthesis and properties of polymersSilicone and Siloxane Chemistry