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Synthetic Engineering of Morphology and Electronic Band Gap in Lateral Heterostructures of Monolayer Transition Metal Dichalcogenides

Hossein Taghinejad、Mohammad Taghinejad、Ali A. Eftekhar 等 15 位作者2020-05-04ACS Nano

Abstract Heterostructures of two-dimensional transition metal dichalcogenides (TMDs) can offer a plethora of opportunities in condensed matter physics, materials science, and device engineering. However, despite state-of-the-art demonstrations, most current methods lack enough degrees of freedom for the synthesis of h…

Advanced Photocatalysis Techniques2D Materials and ApplicationsMXene and MAX Phase Materials

Near-Infrared-Active Copper Bismuth Oxide Electrodes for Targeted Dissociation of Alzheimer’s β-Amyloid Aggregates

Yerin Heo、Kayoung Kim、Jin‐Hyun Kim 等 5 位作者2020-05-04ACS Applied Materials & Interfaces

The abnormal accumulation of β-amyloid (Aβ) aggregates in the brain is a major pathological hallmark of Alzheimer’s disease. We report a near-infrared (NIR)-active CuBi 2 O 4 -based photocathodic platform that can target intact Aβ aggregates and dissociate them into nontoxic species. Because of its relatively narrow b…

Molecular Sensors and Ion DetectionPhotoreceptor and optogenetics researchAdvanced Nanomaterials in Catalysis

Halloysite‐reinforced thermoplastic polyurethane nanocomposites: Physico‐mechanical, rheological, and thermal investigations

Mohammadali Pourmohammadi‐Mahunaki、Vahid Haddadi‐Asl、Hossein Roghani‐Mamaqani 等 5 位作者2020-05-04Polymer Composites

Abstract Different thermoplastic polyurethane (TPU) nanocomposites with various amounts of halloysite nanotube (HNT) were prepared. The morphological, rheological, thermal, mechanical, and electrical properties of the nanocomposites were also investigated. Fourier‐transform infrared spectroscopy shows that increasing…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingClay minerals and soil interactions

External Stimuli Responsive Bis(anthryl)borylaniline AIEgens for Viscosity and Temperature Sensing: The Game of Molecular Flexibility

Umesh Pratap Pandey、Pakkirisamy Thilagar2020-05-04Advanced Optical Materials

Abstract External stimuli‐responsive luminogens have attracted a lot of attention in the recent years owing to their potential applications in various fields such as sensing, bio‐probes, and optical devices. In this work, the design and synthesis of a new class of external stimuli‐responsive anthracene based fluoresce…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistry

A computational modeling framework for reaction and failure of environmental barrier coatings under silicate deposits

William D. Summers、David L. Poerschke、Matthew R. Begley 等 5 位作者2020-05-04Journal of the American Ceramic Society

Abstract Environmental barrier coatings (EBCs) for use with SiC‐based composites in gas turbine engines may fail following reaction with molten silicate deposits. The processes involved may include dissolution of the EBC material into the deposit, reactions that produce new phases, and cracking or spallation upon cool…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceHigh-Temperature Coating Behaviors

Quantum and classical ratchet motions of vortices in a two-dimensional trigonal superconductor

Yuki M. Itahashi、Yu Saito、Toshiya Ideue 等 5 位作者2020-05-04Physical Review Research

This paper reports the nonreciprocal transport in a noncentrosymmetric 2D superconductor, gated MoS2, under out-of-plane magnetic field. The magnitude of the nonreciprocal signal, arising from the vortex rectification by the asymmetric pinning potentials in the trigonal lattice, substantially depends on whether the vo…

Physics of Superconductivity and MagnetismOrganic and Molecular Conductors ResearchQuantum many-body systems

Preparation and characterization of graphene oxide aerogel/gelatin as a hybrid scaffold for application in nerve tissue engineering

Khdijeh Zeinali、Mohammad Taghi Khorasani、Alimorad Rashidi 等 4 位作者2020-05-04International Journal of Polymeric Materials

There is currently no appropriate therapy for the treatment of injuries that affect the central nervous system. Therefore, scientists have attempted to explore novel methods to improve the neural tissue regeneration, while preventing inhibitory fibro glial scars. In these methods, hollow graphene oxide aerogel was ini…

Supercapacitor Materials and FabricationElectrospun Nanofibers in Biomedical ApplicationsGraphene and Nanomaterials Applications

Spin Angular Momentum Controlled Multifunctional All‐Dielectric Metasurface Doublet

Lieguo Yu、Yubin Fan、Yujie Wang 等 7 位作者2020-05-04Laser & Photonics Review

Abstract Lenses are the most important components of portable and integrable optical systems. Due to the inherent limitation of system sizes, external accessories are required for realizing additional functions such as close‐up or telegraph imaging, making the entire system complicated and cumbersome. Herein, based on…

Metamaterials and Metasurfaces ApplicationsOrbital Angular Momentum in OpticsAdvanced Antenna and Metasurface Technologies

Fermi Level Engineering of Passivation and Electron Transport Materials for p‐Type CuBi2O4 Employing a High‐Throughput Methodology

Zemin Zhang、Sarah A. Lindley、Dan Guevarra 等 10 位作者2020-05-04Advanced Functional Materials

Abstract Metal oxide semiconductors are promising for solar photochemistry if the issues of excessive charge carrier recombination and material degradation can be resolved, which are both influenced by surface quality and interface chemistry. Coating the semiconductor with an overlayer to passivate surface states is a…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

In Situ Chromophore Doping: A New Mechanism for the Long-Wavelength Emission of Carbon Dots

Sara Karami、Mojtaba Shamsipur、Avat Taherpour 等 5 位作者2020-05-04The Journal of Physical Chemistry C

Abstract Doping of carbon dots (CDs) with heteroatoms (e.g., N, S, P, and B) is known as an efficient method to modulate the electronic and optical properties of these fluorescent carbonaceous nanomaterials. Here, we have demonstrated the possibility of in situ azo doping in CDs through hydrothermal treatment of gluco…

Quantum Dots Synthesis And PropertiesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Efficient Ab Initio Modeling of Dielectric Screening in 2D van der Waals Materials: Including Phonons, Substrates, and Doping

Morten N. Gjerding、L. S. R. Cavalcante、Andrey Chaves 等 4 位作者2020-05-04The Journal of Physical Chemistry C

The quantum electrostatic heterostructure (QEH) model allows for efficient computation of the dielectric screening properties of layered van der Waals (vdW)-bonded heterostructures in terms of the dielectric functions of the individual two-dimensional (2D) layers. Here, we extend the QEH model by including (1) contrib…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Low‐T CO Oxidation over Cu−CHA Catalysts in Presence of NH3: Probing the Mobility of CuII Ions and the Role of Multinuclear CuII Species

Roberta Villamaina、Umberto Iacobone、Isabella Nova 等 7 位作者2020-05-04ChemCatChem

Abstract We use dry CO oxidation to probe CuII dimers in Cu−CHA catalysts in the presence of ammonia. Samples with different Cu/Al and Si/Al ratios were exposed to CO in He at 200 °C after either one of two catalyst pre‐treatments: (i) pre‐oxidization in 8 % O2/He at 550 °C for 1 hour; (ii) pre‐oxidation in 8 % O2/He…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsOxidative Organic Chemistry Reactions

Electron Energy Loss Spectroscopy of Bright and Dark Modes in Hyperbolic Metamaterial Nanostructures

Tommi Isoniemi、Nicolò Maccaferri、Quentin M. Ramasse 等 5 位作者2020-05-04Advanced Optical Materials

Abstract Layered metal/dielectric hyperbolic metamaterials (HMMs) support a wide landscape of plasmon polariton excitations. In addition to surface plasmon polaritons, coupled Bloch‐like gap‐plasmon polaritons with high modal confinement inside the multilayer are supported. Photons can excite only a subset of these po…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon Research

Single- and double-walled boron nitride nanotubes: Controlled synthesis and application for water purification

Hyunjin Cho、Jun Hee Kim、Jae Hun Hwang 等 8 位作者2020-05-04Scientific Reports

Abstract Research interest in boron nitride nanotubes (BNNTs) has increased after the recent success of large-scale BNNT syntheses using high-temperature-pressure laser ablation or high-temperature plasma methods. Nonetheless, there are limits to the application and commercialization of these materials because of the…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Ultrafast Exciton Dynamics in Scalable Monolayer MoS2 Synthesized by Metal Sulfurization

Hsu‐Sheng Tsai、Yung-Hung Huang、Po-Cheng Tsai 等 7 位作者2020-05-04ACS Omega

Abstract Excitons in monolayer transition metal dichalcogenides (TMDs) have exceptionally large binding energies and dominate the optical properties of materials. Exploring the relaxation behavior of excitons is crucial for understanding the fundamental physics as well as the performance of TMD-based optoelectronic de…

Graphene research and applicationsPerovskite Materials and Applications2D Materials and Applications

Mechanical and free vibration properties of skin and core designed basalt woven intertwined with flax layered polymeric laminates

K Ramraji、K. Rajkumar、Sabarinathan Palaniyappan2020-05-04Proceedings of the Institution of Mechanical Engineers Part C Journal of Mechanical Engineering Science

Design of fiber-reinforced polymer damping laminates has been attracting great interest in industrial sectors for lightweight structural damping applications. The present work investigates the impact of skin, core, neutral, and alternate intertwined basalt/flax fabric on the mechanical and vibrational properties of th…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesMechanical Engineering and Vibrations Research

Modulation of the Self‐Assembly of π‐Amphiphiles in Water from Enthalpy‐ to Entropy‐Driven by Enwrapping Substituents

P. Syamala、Frank Würthner2020-05-04Chemistry - A European Journal

Depending on the connectivity of solubilizing oligoethylene glycol (OEG) side chains to the π-cores of amphiphilic naphthalene and perylene bisimide dyes, self-assembly in water occurs either upon heating or cooling. Herein, we show that this effect originates from differences in the enwrapping capability of the π-cor…

Lipid Membrane Structure and BehaviorSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Recent advances on synthesis and biomaterials applications of hyperbranched polymers

Timothy Cuneo、Haifeng Gao2020-05-04Wiley Interdisciplinary Reviews Nanomedicine and Nanobiotechnology

Hyperbranched polymers represent an intriguing class of shape-persistent soft nanomaterials that could be easily produced in one-pot reaction to obtain highly branched arborescent structures. Although traditional synthesis of hyperbranched polymers suffers from the poorly defined structures and broad molecular weight…

Advanced biosensing and bioanalysis techniquesRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Obtaining Efficiently Tunable Red Emission in Ca3-δLnδWO6:Mn4+ (Ln = La, Gd, Y, Lu, δ = 0.1) Phosphors Derived from Nearly Nonluminescent Ca3WO6:Mn4+ via Ionic Substitution Engineering for Solid-State Lighting

Kai Li、Rik Van Deun2020-05-04ACS Sustainable Chemistry & Engineering

In this work, a facile ionic substitution strategy was initiated to realize the intense red luminescence in Ca 3-δ Ln δ WO 6:Mn 4+ (δ = 0.1, CLnWO:Mn 4+, Ln = La, Gd, Y, Lu,) phosphors evolved from luminescence-ignorable Ca 3 WO 6:Mn 4+ (CWO:Mn 4+ ) material, for the first time. It is fascinating that the emission pro…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesLuminescence and Fluorescent Materials

Bi-tunable terahertz absorber based on strontium titanate and Dirac semimetal

Han Xiong、Yuehong Peng、Fan Yang 等 5 位作者2020-05-04Optics Express

We proposed a polarization-insensitive absorber based on strontium titanate (STO) and bulk Dirac semimetal (BDS) in the terahertz (THz) region. The center frequency of the absorption peak can be independently regulated by temperature or Fermi energy level of STO or BDS, respectively. The numerical simulation result re…

Metamaterials and Metasurfaces ApplicationsTopological Materials and PhenomenaAdvanced Antenna and Metasurface Technologies