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Vertically Stacked 2H‐1T Dual‐Phase MoS 2 Microstructures during Lithium Intercalation: A First Principles Study

Shayani Parida、Avanish Mishra、Jie Chen 等 7 位作者2020-07-19Journal of the American Ceramic Society

Abstract Layered transition‐metal dichalcogenides (TMDs) have shown promise to replace carbon‐based compounds as suitable anode materials for Lithium‐ion batteries (LIBs) owing to facile intercalation and de‐intercalation of lithium (Li) during charging and discharging, respectively. While the intercalation mechanism…

Advancements in Battery Materials2D Materials and ApplicationsMXene and MAX Phase Materials

Optimizing an Osteosarcoma-Fibroblast Coculture Model to Study Antitumoral Activity of Magnesium-Based Biomaterials

Philipp Globig、Regine Willumeit‐Römer、Fernanda Martini 等 5 位作者2020-07-19International Journal of Molecular Sciences

Osteosarcoma is among the most common cancers in young patients and is responsible for one-tenth of all cancer-related deaths in children. Surgery often leads to bone defects in excised tissue, while residual cancer cells may remain. Degradable magnesium alloys get increasing attention as orthopedic implants, and some…

Bone Tissue Engineering MaterialsMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Efficient Blue Luminescent Graphene Quantum Dots and their Photocatalytic Ability Under Visible Light

作者信息未提供2020-07-19Biointerface Research in Applied Chemistry

Graphene Quantum Dots (GQDs) are considered to be a new class of materials with distinctive photoluminescence and low toxic level properties. Herein, we have reported the preparation of GQDs at different pH (pH 5, 8, 10, and 14) from pyrocatechol. UV-Visible absorption and normalized fluorescence spectra were applied…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications

Diamond-Like Carbon Films with Low Internal Stress by a Simple Bilayer Approach

K. Baba、R. Hatada、S. Flege 等 4 位作者2020-07-19Coatings

Amorphous carbon films with a high hardness usually suffer from high internal stress. To deposit films with a hard top surface but reduced internal stress, a simple bilayer approach was used. Films were prepared by plasma source ion implantation, using only hydrocarbon precursors. The single layer with the highest har…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchLubricants and Their Additives

Two Dimensional Oxygen-deficient Bismuth oxy-iodide Nanosheets with Enhanced Supercapacitor Performances

Huichao Wang、Zhengde Wang、Huadong Tian 等 8 位作者2020-07-19International Journal of Electrochemical Science

Introducing oxygen vacancy into oxides has become an effective strategy for enhancing the electrochemical performance. Herein, a series of identical two-dimensional BiOI nanosheets with various concentration of oxygen vacancies are rationally fabricated through a facile ion-exchange and annealing process under Ar atmo…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationCopper-based nanomaterials and applications

First-Principles Study on III-Nitride Polymorphs: AlN/GaN/InN in the Pmn21 Phase

Zheren Zhang、Changchun Chai、Wei Zhang 等 6 位作者2020-07-19Materials

The structural, mechanical, and electronic properties, as well as stability, elastic anisotropy and effective mass of AlN/GaN/InN in the Pmn21 phase were determined using density functional theory (DFT). The phonon dispersion spectra and elastic constants certify the dynamic and mechanical stability at ambient pressur…

GaN-based semiconductor devices and materialsMetal and Thin Film MechanicsBoron and Carbon Nanomaterials Research

Rational Design of a Novel Catalyst Cu‐SAPO‐42 for NH 3 ‐SCR Reaction

Nana Yan、Chao Ma、Yi Cao 等 8 位作者2020-07-19Small

Abstract Cu‐exchanged LTA‐type aluminosilicate catalyst has been considered as an efficient catalyst for the selective catalytic reduction of NO x with ammonia (NH 3 ‐SCR). However, expensive organic structure‐directing agents (OSDAs) and the corrosive fluoride medium are inevitably used to synthesize LTA‐type molecul…

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceZeolite Catalysis and Synthesis

Effect of Macromolecular Crowders on the Self‐Assembly Process of Silk Fibroin

Priyanka Dubey、Sinchan Seit、Pramit K. Chowdhury 等 4 位作者2020-07-19Macromolecular Chemistry and Physics

Abstract Macromolecular crowding is known to have a significant impact on the aggregation and folding of proteins. In this study, the role of different macromolecular crowders such as polyethylene glycol (PEG 200 and PEG 6000) and dextran (dextran 6000 and 70000) on the self‐assembly of silk fibroin protein is explore…

Polymer Surface Interaction StudiesSilk-based biomaterials and applicationsBiochemical and Structural Characterization

Effect of rare earth Y2O3 on the corrosion and friction properties of Al2O3 ceramic coatings prepared via microarc oxidation

Yu Guo、Zhu Xue、Gang Li 等 5 位作者2020-07-19International Journal of Electrochemical Science

Rare earth Y 2 O 3 /Al 2 O 3 ceramic coatings were prepared on 6063 aluminum alloy via micro-arc oxidation. The corrosion and friction properties of the substrates were enhanced. Scanning electron microscopy results showed that the number of “crater” holes increased and decreased, and the diameter of micropores first…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Influence of Sodium Lignosulfonate on the Corrosion-Inhibition Behavior of Q235 Steel in Simulated Concrete Pore Solutions

Jiansan Li、Weilin Liu、Wanchen Xie2020-07-19International Journal of Electrochemical Science

The corrosion mechanism and behavior of Q235 steel treated with sodium lignosulfonate and a mixture of sodium lignosulfonate and sodium silicate inhibitors in simulated concrete pore (SCP) solutions containing 0.08-mol/L NaCl were evaluated using polarization methods, electrochemical impedance spectroscopy, scanning e…

Corrosion Behavior and InhibitionPolymer composites and self-healingLignin and Wood Chemistry

Nitrogen and Oxygen Co-doped Hierarchical Porous Carbon Derived from Pine Mushroom Biomass for High-Performance Supercapacitor

Zhentao Bian、Guangzhen Zhao、Long Chao 等 9 位作者2020-07-19International Journal of Electrochemical Science

Due to the unique physicochemical properties, heteroatom doping of porous carbon has attracted wide attention. However, the complicated synthesis process and high cost limit its mass production. In this work, nitrogen and oxygen co-doped porous carbon materials (N-O-PCMs) derived from pine mushroom (PM) were prepared…

Supercapacitor Materials and FabricationBiodiesel Production and ApplicationsElectrospun Nanofibers in Biomedical Applications

Application of the adverse outcome pathway framework for investigating skin sensitization potential of nanomaterials using new approach methods

Soraia F. Bezerra、Bruna dos Santos Rodrigues、Artur Christian Garcia da Silva 等 9 位作者2020-07-19Contact Dermatitis

BACKGROUND: Currently, considerable efforts to standardize methods for accurate assessment of properties and safety aspects of nanomaterials are being made. However, immunomodulation effects upon skin exposure to nanomaterial have not been explored. OBJECTIVES: To investigate the immunotoxicity of single-wall carbon n…

Nanoparticles: synthesis and applicationsAdvancements in Transdermal Drug DeliveryContact Dermatitis and Allergies

Polyurethane and Polyurethane Nanocomposites: Recent Contributions to Medicine

作者信息未提供2020-07-19Biointerface Research in Applied Chemistry

Polyurethane (PU) is a synthetic polymer obtained by polycondensation process of isocyanates and polyols, and for some cross-linked products with a third component as an extender. It is one of the most versatile macromolecular compounds, and it contains soft and hard segments. Beside (PU)'s physicomechanical and chemi…

Polymer composites and self-healing

Fabrication of Nanosized Layered-MnO2/Activated Carbon Composites Electrodes for High-performance Supercapacitor

Ya Liu、Songlin Zuo、Baoshou Shen 等 5 位作者2020-07-19International Journal of Electrochemical Science

Layered-MnO2/activated carbon composites were prepared by simply mixing activated carbons and Mn (NO3)2 solution, followed by heat treatment at 300 °C in order to develop high-performance and cost-effective active materials for supercapacitor electrodes. The effects of the loading mass of MnO2, the surface chemistry a…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationElectrochemical sensors and biosensors

Effect of Sodium Tungstate on the Corrosion Behavior of Fe-Base Alloy in H2SO4 Solution

Ghalia A. Gaber、Hayam A. Aly、Lamiaa Z. Mohamed2020-07-19International Journal of Electrochemical Science

The corrosion behavior of Fe-base alloy in H 2 SO 4 acid at different concentrations was evaluated. The effect of sodium tungstate inhibitor on Fe-base alloy in 10 % H 2 SO 4 solutions was evaluated by using weight loss and potentiodynamic polarization methods along with scanning electron microscope and energy dispers…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

A Polarization-Insensitive and Wide-Angle Terahertz Absorber with Ring-Porous Patterned Graphene Metasurface

Hongyang Shen、Fengxiang Liu、Chunyang Liu 等 10 位作者2020-07-19Nanomaterials

dielectric layer, is proposed and studied by numerical simulation. The simulated results show that the absorptivity of the absorber reaches 90% in the range of 0.91-1.86 THz, and the normalized bandwidth of the absorptivity is 68.6% under normal incidence. In the simulation, the effects of the geometric parameters of…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchThermal Radiation and Cooling Technologies

Edible packaging from hydroxypropyl thermoplastic cassava starch, agar and maltodextrin blends produced by cast extrusion

Phanwipa Wongphan、Nathdanai Harnkarnsujarit2020-07-19International Journal of Food Science & Technology

Summary Edible packaging from hydroxypropyl cassava starch with different degrees of substitution (DS), agar and maltodextrin films was produced by conventional cast extrusion. Microstructures showed hydrophobic agar aggregates (100–200 µm) dispersed in film matrices, giving nonsmooth surfaces that enhanced wettabilit…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Kinetic and Thermodynamic Studies on Synthesis of Mg-Doped LiMn2O4 Nanoparticles

Aleksei Llusco、Mario Grágeda、Svetlana Ushak2020-07-19Nanomaterials

In this work, a first study on kinetics and thermodynamics of thermal decomposition for synthesis of doped LiMn2O4 nanoparticles is presented. The effect of Mg doping concentration on thermal decomposition of synthesis precursors, prepared by ultrasound-assisted Pechini-type sol–gel process, and its significance on nu…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal and Kinetic Analysis

Template Engineering of CuBi2O4 Single‐Crystal Thin Film Photocathodes

Jongmin Lee、Hongji Yoon、Kyoung Soon Choi 等 12 位作者2020-07-19Small

Abstract To develop strategies for efficient photo‐electrochemical water‐splitting, it is important to understand the fundamental properties of oxide photoelectrodes by synthesizing and investigating their single‐crystal thin films. However, it is challenging to synthesize high‐quality single‐crystal thin films from c…

Gas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Film Blowing of Linear and Long-Chain Branched Poly(ethylene terephthalate)

Michael Härth、Andrea Dörnhöfer2020-07-19Polymers

Film blowing of Poly(ethylene terephthalate) (PET) is challenging due its inherently low melt viscosity and poor melt strength. In this study, it is shown how the rheological properties of a commercial PET can be altered by reactive extrusion using either pyromellitic dianhydride (PMDA) or a multifunctional epoxy (Jon…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Foaming and Composites