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Unimolecularly thick monosheets of vinyl polymers fabricated in metal–organic frameworks

Nobuhiko Hosono、Shuto Mochizuki、Yuki Hayashi 等 4 位作者2020-07-17Nature Communications

Polymers with two-dimensional (2D) network topologies are currently gaining significant attention due to their unique properties that originate from their regulated conformations. However, in contrast to conventional 1D- and 3D-networked macromolecules, the synthesis of such 2D networks provides challenges for polymer…

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Effect of Lattice Strain on the Formation of Ruddlesden–Popper Faults in Heteroepitaxial LaNiO3 for Oxygen Evolution Electrocatalysis

Jumi Bak、Hyung Bin Bae、Chadol Oh 等 5 位作者2020-07-17The Journal of Physical Chemistry Letters

A great deal of research has recently been focused on Ruddlesden–Popper (RP) two-dimensional planar faults consisting of intervened [AO] monolayers in an ABO 3 perovskite framework due to the structurally peculiar shear configuration. In this work, we scrutinize the effect of elastic strain on the generation behavior…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Stretchable piezoelectric elastic composites for sensors and energy generators

Jose Enrico Q. Quinsaat、Tym de Wild、Frank Nüesch 等 11 位作者2020-07-17Composites Part B Engineering

The search for a piezoelectric elastomer that generates an electrical signal when pressed and stretched has increased significantly in the last decade as they hold great promise in harvesting energy from human motion and monitoring human activities. Here, the excellent elasticity of polydimethylsiloxane-based elastome…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsDielectric materials and actuators

Proanthocyanidin–Aluminum Complexes Improve Aluminum Resistance and Detoxification of Camellia sinensis

Zhouping Fu、Xiaolan Jiang、Weiwei Li 等 11 位作者2020-07-17Journal of Agricultural and Food Chemistry

Aluminum (Al) influences crop yield in acidic soil. The tea plant ( Camellia sinensis ) has high Al tolerance with abundant monomeric catechins in its leaves, especially epigallocatechin gallate (EGCG), and polymeric proanthocyanidins in its roots (rPA). The role of these polyphenols in the Al resistance of tea plants…

Clay minerals and soil interactionsAluminum toxicity and tolerance in plants and animalsSilicon Effects in Agriculture

Electrical Probes of the Non-Abelian Spin Liquid in Kitaev Materials

David Aasen、Roger S. K. Mong、Benjamin M. Hunt 等 5 位作者2020-07-17Physical Review X

Tailored circuits joined to a quantum spin liquid provide a way to electrically probe the spin liquid's fractionalized excitations, a key step toward harnessing such systems for fault-tolerant quantum computing.

Topological Materials and PhenomenaAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Magneto-Rheological Elastomer Composites. A Review

Sneha Samal、Marcela Škodová、L. Abate 等 4 位作者2020-07-17Applied Sciences

Magneto-rheological elastomer (MRE) composites belong to the category of smart materials whose mechanical properties can be governed by an external magnetic field. This behavior makes MRE composites largely used in the areas of vibration dampers and absorbers in mechanical systems. MRE composites are conventionally co…

Polymer Nanocomposites and PropertiesVibration Control and Rheological FluidsDielectric materials and actuators

Tailored piezoelectric performance of self‐polarized PVDF‐ZnO composites by optimization of aspect ratio of ZnO nanorods

Shewli Pratihar、Samar Kumar Medda、Shrabanee Sen 等 4 位作者2020-07-17Polymer Composites

Abstract Aspect ratio of filler plays a crucial role to study the electrical properties of polymer based composite system. Here, we investigated the effect of filler aspect ratio on the electrical properties of zinc oxide (ZnO) incorporated poly(vinylidene fluoride) (PVDF) matrix. ZnO nanorods having different aspect…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsDielectric materials and actuators

Bio-inspired Surface Texture Modification as a Viable Feature of Future Aquatic Antifouling Strategies: A Review

Chloe Richards、Asma Slaimi、Noel E. O’Connor 等 6 位作者2020-07-17International Journal of Molecular Sciences

The imitation of natural systems to produce effective antifouling materials is often referred to as "biomimetics". The world of biomimetics is a multidisciplinary one, needing careful understanding of "biological structures", processes and principles of various organisms found in nature and based on this, designing na…

Polymer Surface Interaction StudiesMarine Biology and Environmental ChemistryMarine Ecology and Invasive Species

Combinatory Treatment with miR-7-5p and Drug-Loaded Cubosomes Effectively Impairs Cancer Cells

Ewa Gajda、Marlena Godlewska、Zenon Mariak 等 5 位作者2020-07-17International Journal of Molecular Sciences

BACKGROUND: Multidrug resistance (MDR) is an emerging problem in the treatment of cancer. Therefore, there is a necessity for novel strategies that would sensitize tumor cells to the administered chemotherapeutics. One of the innovative approaches in fighting drug-resistant tumors is the treatment of cancer with micro…

MicroRNA in disease regulationNanoparticle-Based Drug DeliveryRNA Interference and Gene Delivery

Detecting Basal Myeloperoxidase Activity in Living Systems with a Near-Infrared Emissive “Turn-On” Probe

Lingyan Liu、Peng Wei、Wei Yuan 等 7 位作者2020-07-17Analytical Chemistry

Detecting myeloperoxidase (MPO) activity in living organisms is important because MPO contributes to the pathogenesis of many diseases such as rheumatoid arthritis and other inflammatory diseases, artherosclerosis, neurodegenerative disease, and some cancers. However, rapid and effective methods for the detection of b…

Nanoplatforms for cancer theranosticsNeutrophil, Myeloperoxidase and Oxidative MechanismsAdvanced Nanomaterials in Catalysis

Microstructured Sulfur-Doped Carbon-Coated Fe7S8 Composite for High-Performance Lithium and Sodium Storage

Feng Jiang、Limin Zhang、Wenqing Zhao 等 10 位作者2020-07-17ACS Sustainable Chemistry & Engineering

From the perspective of resource reserves, environmental effects, and production costs, direct utilization of natural ores as electrode materials for rechargeable batteries after mineral processing is of more practical significance than chemosynthetic materials. While the corresponding investigation is relatively insu…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Cryo-EM structures of calcium homeostasis modulator channels in diverse oligomeric assemblies

K. Demura、Tsukasa Kusakizako、Wataru Shihoya 等 10 位作者2020-07-17Science Advances

CLHM-1 at resolutions of 2.66, 3.4, and 3.6 Å, respectively. The CALHM1 octamer structure reveals that the N-terminal helix forms the constriction site at the channel pore in the open state and modulates the ATP conductance. The CALHM2 undecamer and CLHM-1 nonamer structures show the different oligomeric stoichiometri…

Carbon Nanotubes in CompositesLipid Membrane Structure and BehaviorIon channel regulation and function

Comparative analysis between normal and submerged friction stir processed friction stir welded dissimilar aluminium alloy joints

Sipokazi Mabuwa、Velaphi Msomi2020-07-17Journal of Materials Research and Technology

The friction stir welded dissimilar aluminium alloy joints were friction stir processed under air (normal) and underwater (submerged) with room temperature conditions. The joints produced through these two distinct conditions were studied comparatively. The microstructural analysis revealed that due to the water rapid…

Aluminum Alloys Composites PropertiesAdvanced Welding Techniques AnalysisMXene and MAX Phase Materials

Polyacrylonitrile Nanofiber Membranes Modified with Ni-Based Conductive Metal Organic Frameworks for Air Filtration and Respiration Monitoring

Hansol Lee、Wuseok Kim2020-07-17ACS Applied Nano Materials

We developed a nanofiber membrane that blocks particulate matters (PMs) and monitors respiration. The membrane was composed of polyacrylonitrile (PAN) nanofibers and was prepared by electrospinning. An electrically conductive metal organic framework (MOF) was synthesized directly on the nanofiber by a two-step hydroth…

Metal-Organic Frameworks: Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsCovalent Organic Framework Applications

Electron Beam Aberration Correction Using Optical Near Fields

Andrea Konečná、F. Javier Garcı́a de Abajo2020-07-17Physical Review Letters

The interaction between free electrons and optical near fields is attracting increasing attention as a way to manipulate the electron wave function in space, time, and energy. Relying on currently attainable experimental capabilities, we design optical near-field plates to imprint a lateral phase on the electron wave…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesNear-Field Optical Microscopy

Néel-type antiferromagnetic order and magnetic field–temperature phase diagram in the spin- 12 rare-earth honeycomb compound YbCl3

Jie Xing、Erxi Feng、Yaohua Liu 等 11 位作者2020-07-17Physical review. B./Physical review. B

Most of the searches for Kitaev materials deal with $4d/5d$ magnets with spin-orbit-coupled $J=1/2$ local moments such as iridates and $\ensuremath{\alpha}\text{\ensuremath{-}}{\mathrm{RuCl}}_{3}$. Here we propose the monoclinic ${\mathrm{YbCl}}_{3}$ with a ${\mathrm{Yb}}^{3+}$ honeycomb lattice for the exploration of…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Morphological and Swelling Potential Evaluation of Moringa oleifera Gum/Poly(vinyl alcohol) Hydrogels as a Superabsorbent

Suhail Ahmad、K. Manzoor、Roli Purwar 等 4 位作者2020-07-17ACS Omega

Abstract Synergistic use of superabsorbent hydrogels has vital contribution to the daily life. This work gives an account of a facile approach to synthesize superabsorbent hydrogels based on Moringa oleifera gum and polyvinyl alcohol cross-linked with borax. Fourier transform infrared, X-ray diffraction, and scanning…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer-Based Agricultural Enhancements

Assessing the modification efficiency of waste glass powder in hydraulic construction materials

Xiaojian Gao、Qingliang Yu、X.S. Li 等 4 位作者2020-07-17Construction and Building Materials

In this paper, the effects of waste glass powder on reaction kinetics, gel characteristics, as well as workability and mechanical property of two typical binding systems: Portland cement system and alkali activation system, are investigated. The commercial silica fume was used as a comparative supplementary cementitio…

Concrete and Cement Materials ResearchInnovative concrete reinforcement materialsMagnesium Oxide Properties and Applications

Effective Molecular Descriptors for Chemical Accuracy at DFT Cost: Fragmentation, Error-Cancellation, and Machine Learning

Eric M. Collins、Krishnan Raghavachari2020-07-17Journal of Chemical Theory and Computation

Recent advances in theoretical thermochemistry have allowed the study of small organic and bio-organic molecules with high accuracy. However, applications to larger molecules are still impeded by the steep scaling problem of highly accurate quantum mechanical (QM) methods, forcing the use of approximate, more cost-eff…

Computational Drug Discovery MethodsMetabolomics and Mass Spectrometry StudiesMachine Learning in Materials Science

Highly nonlinear trion-polaritons in a monolayer semiconductor

R. P. A. Emmanuele、M. Sich、Oleksandr Kyriienko 等 12 位作者2020-07-17White Rose Research Online (University of Leeds, The University of Sheffield, University of York)

Abstract Highly nonlinear optical materials with strong effective photon-photon interactions are required for ultrafast and quantum optical signal processing circuitry. Here we report strong Kerr-like nonlinearities by employing efficient optical transitions of charged excitons (trions) observed in semiconducting tran…

2D Materials and ApplicationsPlasmonic and Surface Plasmon ResearchStrong Light-Matter Interactions