Materials Literature
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After a spinal cord injury, axonal regeneration over long distances is challenging due to the lack of physical guidance cues and bioactive signals. In this study, a multichannel bioactive silk fibroin nanofiber conduit was fabricated to improve spinal cord injury repair by enhancing axonal regeneration. The conduit wa…
of ∼60 kΩ·μm. The weaker performance of 1L devices is due to their sensitivity to processing and ambient. Our results suggest that 2L (or few layers) is preferable to 1L for improved electronic properties in applications that do not require a direct band gap, which is a key finding for future two-dimensional electroni…
A novel mathematical formulation is presented for the applications of the stress-driven nonlocal theory of elasticity to engineering nano-scale problems requiring longitudinal discretization. Specifically, a differential formulation accompanied with novel constitutive continuity conditions is provided for determining…
Tip-enhanced Raman scattering (TERS) in ångström-scale plasmonic cavities has drawn increasing attention. However, Raman scattering at vanishing cavity distances remains unexplored. Here, we show the evolution of TERS in transition from the tunneling regime to atomic point contact (APC). A stable APC is reversibly for…
Polyzwitterions have emerged as a new class of antifouling materials alternating poly(ethylene glycol). The exemplary biopassivation and lubrication behaviors are often attributed to the particular chemical structure of zwitterions, which involve a large dipole moment of the charged groups and a neutral net charge, wh…
The structure, morphology, and mechanical properties of two compression-molded grades of ultrahigh-molecular-weight polyethylene (UHMWPE) and, for comparison, one conventional linear polyethylene (HDPE) were studied. Compression molding resulted in some preferred orientation of lamellae in the compression direction in…
A new biobased bismaleimide architecture from methyl oleate, consisting of an aliphatic branched structure, denoted methyl oleate bismaleimide (MO BMI), was synthesized and fully characterized. MO BMI was used as a cross-linking agent to obtain networks by using linear biobased furan bearing PUs via the Diels–Alder re…
Topological defects such as vortices in ferroelectric materials are attracting tremendous interest because of their splendid possibilities for unique physical phenomena and potential applications in nanoelectronic devices. However, reports of the vortex structure have been scarce in organic ferroelectrics, which are h…
High Resolution Image Download MS PowerPoint Slide Cellulose nanofibers (CNFs) with nanoscale dimension, high aspect ratio, and easily modified surface chemistry show great potential as novel rheological and filtration modifiers in bentonite water-based drilling fluids (BT-WDFs). However, CNFs would suffer from poor r…
The design of heterogeneous catalysts for highly efficient catalysis for cyanosilylation reactions and Knoevenagel condensations is greatly significant, due to the important application of their products in industry. Herein, five hybrid compounds constructed from two types of polyoxovanadates, [MV 12 O 38 ] 12– (M = N…
A Ba-based glass-ceramic sealant is designed and tested for solid oxide electrolysis cell (SOEC) applications. A suitable SiO2/BaO ratio is chosen in order to obtain BaSi2O5 crystalline phase and subsequently favorable thermo-mechanical properties of the glass-ceramic sealant. The glass is analyzed in terms of thermal…
Abstract The origin of plasticity in bulk metallic glasses (BMGs) is highly elusive due to their complicated amorphous atomic structures. Nonetheless, there is a general consensus that the homogeneous regime of deformation on the deformation map of BMGs is constrained by high temperature and low strain rate. Here we r…
The use of fly ash as a cement replacement material brings economy and sustainability in the concrete construction. Despite economic and environmental benefits, fly ash incorporation in concrete reduces its early age performance. Therefore, the main objective of this research is to increase the incorporation level of…
Abstract Designing deep‐ultraviolet (DUV) nonlinear‐optical (NLO) crystals is one of the major current research interests, but it faces a great challenge. In order to overcome the problem of crystal growth and the toxicity of BeO raw materials in KBe2BO3F2 (KBBF), the only applicable DUV NLO crystal so far, we substit…
Silver nanoparticles (AgNPs) are one of the most investigated metal-based nanomaterials. Their biocidal activity boosted their application in both diagnostic and therapeutic medical systems. It is therefore crucial to provide sound evidences for human-related safety of AgNPs. This study aimed to enhance scientific kno…
High coverage structures for CO on Pt(111) and Pt(100) surfaces are studied by density functional theory modeling and compared to high-pressure scanning tunneling microscopy experiments. Semilocal exchange correlation functionals are known to provide an incorrect adsorption site and overestimated adsorption energy for…
Lead sulfide (PbS) quantum dots (QDs) have shown promising performance as a sensitizer in infrared-to-visible photon upconversion systems. To investigate the key design rules, we compare three PbS-sensitized upconversion systems using three mediator molecules with the same tetracene triplet acceptor at different dista…
Abstract Bioplastics such as poly(lactic acid) (PLA), which are derived from renewable sources, promoted as biodegradable and implemented for numerous functions, offer a promising alternative to the enduring synthetic plastics abundant in society. However, the degradation of PLA is slow under natural environmental con…
Electromagnetic wave absorbing materials at high-temperature are urgently needed for stealth aircrafts or aero-engines worked in harsh environments. In this contribution, cobalt-containing siliconboron carbonitride (MOF/SiBCN) nanomaterials were prepared by pyrolyzing metal–organic framework, i.e. cobalt 2-methylimida…
Abstract Thanks to their unique optical properties Ge–Sb–S–Se–Te amorphous chalcogenide materials and compounds offer tremendous opportunities of applications, in particular in near and mid-infrared range. This spectral range is for instance of high interest for photonics or optical sensors. Using co-sputtering techni…