Materials Literature
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The surface stability of all possible terminations for three low-index (100, 110, 111) structures of spinel MgAl 2 O 4 was studied using a first-principles-based thermodynamic approach. The surface Gibbs free energy results indicate that the 100_AlO 2 termination is the most stable surface structure under ultrahigh va…
Excimers are evanescent quasi-particles that typically form during collisional intermolecular interactions and exist exclusively for their excited-state lifetime. We exploited the distinctive structure of metal quantum clusters to fabricate permanent excimer-like colloidal superstructures made of ground-state noninter…
The buckling of elastically restrained embedded microbeam under axial compression load is researched. The effects of small size, axial compression load and surrounding elastic medium are taken into account at the same time. Winkler elastic foundation approach is used to simulate the interaction between microbeam and e…
Although the term nanozymes was coined by us in 2004 to highlight the enzyme-like properties of gold nanoparticles passivated with a monolayer of Zn(II)-complexes in the cleavage of phosphate diesters, systems resembling those metallo-nanoparticles, like micelles and vesicles, have been the subject of investigation si…
The precipitation strengthening of Cu alloys inevitably accompanies lowering of their electric conductivity and ductility. We produced bulk Cu alloys arrayed with nanofibers of stiff intermetallic compound through a precipitation mechanism using conventional casting and heat treatment processes. We then successfully e…
The thickness-dependent surface states of MoS2 thin films grown by the chemical vapor deposition process on the SiO2-Si substrates are investigated by X-ray photoelectron spectroscopy. Raman and high-resolution transmission electron microscopy suggest the thicknesses of MoS2 films to be ranging from 3 to 10 layers. Bo…
The high production costs of titanium in comparison to other structural metals is the main limiting factor for the wide employment of titanium. Cost reduction can be addressed considering creative fabrication methods and/or formulating new chemical compositions. In this work the fabrication of low-cost iron-containing…
Pseudocapacitive materials are critical to the development of supercapacitors but usually suffer from poor conductivity and bad cycling property. Here, we describe the production of novel graphene oxide nanofibers (GONFs) via a partial oxidization and exfoliation method and concurrently report that highly crystallized…
BACKGROUND: The concerted action of three complementary cellulases from Clostridium thermocellum, engineered to be stable at elevated temperatures, was examined on a cellulosic substrate and compared to that of the wild-type enzymes. Exoglucanase Cel48S and endoglucanase Cel8A, both key elements of the natural cellulo…
In an attempt to reduce the reliance on fossil fuels, associated with severe environmental effects, the current research is focused on the identification of the thermoelectric potential of n-type Pb1−xTixTe alloys, with x values of up to 3%. A solubility limit of 0.5 at. % Ti in PbTe was identified, while beyond this…
Hierarchical, N-doped carbon nanosheets with very promising capacitive performance are prepared using a straightforward procedure.
Abstract The design and synthesis of aggregation-induced emission (AIE) luminogens have attracted rapidly growing interest owing to the fundamental significance and diverse applications in mechanosensors, optical recording, security papers, and optoelectronic devices. In this contribution we report design and synthesi…
Recent studies have shown that vapor phase synthesis of structurally isotropic two-dimensional (2D) MoS2 and WS2 produces well-defined domains with clean grain boundaries (GBs). This is anticipated to be vastly different for 2D anisotropic materials like ReS2 mainly due to large anisotropy in interfacial energy impose…
Chirality is a fundamental property of electrons with the relativistic spectrum found in graphene and topological insulators. It plays a crucial role in relativistic phenomena, such as Klein tunneling, but it is difficult to visualize directly. Here, we report the direct observation and manipulation of chirality and p…
Many organisms form elaborate mineralized structures, constituted of highly organized arrangements of crystals and organic macromolecules. The localization of crystals within these structures is presumably determined by the interaction of nucleating macromolecules with the mineral phase. Here we show that, preceding n…
Hot electrons generated through plasmonic excitations in metal nanostructures show great promise for efficiently driving chemical reactions with light. However, the lifetime, yield, and mechanism of action of plasmon-generated hot electrons involved in a given photocatalytic process are not well understood. Here, we d…
The damping ($Γ_a$) of the transverse acoustic (TA) phonon in single crystals of the relaxor $KTa_{1-x}Nb_xO_3$ with x=0.15-0.17 was studied by means of high resolution inelastic cold neutron scattering near the (200) B.Z. point where diffuse scattering is absent, although it is present near (110). In a wide range of…
We have utilised a high spatial resolution imaging method, Differential Phase Contrast (DPC) performed in a scanning transmission electron microscope (STEM), for precise measurement of the magnetic induction distribution in skyrmion states in noncentrosymmetric magnetically ordered materials. Applied to investigate th…
Relative motion between soft wet solids arises in a number of applications in natural and artificial settings, and invariably couples elastic deformation and fluid flow. We explore this in a minimal setting by considering a fluid-immersed negatively-buoyant cylinder moving along a soft inclined wall. Our experiments s…
Half-Heusler (HH) phases (space group F43m, Clb) are increasingly gaining attention as promising thermoelectric materials in view of their thermal stability, scalability, and environmental benignity as well as efficient power output. Until recently, the verifiable dimensionless figure of merit (ZT) of HH phases has re…