Materials Literature
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Infrared absorption spectroscopy has greatly benefited from the electromagnetic field enhancement offered by plasmonic surfaces. However, because of the localized nature of plasmonic fields, such field enhancements are limited to nanometer-scale volumes. Here, we demonstrate that a relatively small, but spatially unif…
Twisted stainless steel wires are used as wire electrodes for electrospinning the polyvinyl alcohol (PVA)/zinc citrate nanofiber mats. The morphology and diameter of the nanofibers in PVA/zinc citrate nanofiber mats are evaluated. We measured the antibacterial efficacy against Staphylococcus aureus (S. aureus) and Esc…
We passivated TEMPO-oxidized cellulose nanofibrils (TOCNF) toward human immunoglobulin G (hIgG) by modification with block and random copolymers of poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) and poly(oligo(ethylene glycol) methyl ether methacrylate) (POEGMA). The block copolymers reversibly adsorbed on TOCNF…
High pressure dielectric studies on the H-bonded liquid D-glucose and Orientationally Disordered Crystal (ODIC) 1,6-anhydro-D-glucose (levoglucosan) were carried out. It was shown that in both compounds, the structural relaxation is weakly sensitive to compression. It is well reflected in the low pressure coefficient…
Within the context of emergent researches linked to graphene, it is well known that h-BN nanosheets (BNNSs), also referred as 2D BN, are considered as the best candidate for replacing SiO2 as dielectric support or capping layers for graphene. As a consequence, the development of a novel alternative source for highly c…
The presence of stacking fault tetrahedra (SFTs) in face-centered-cubic metals substantially modifies the material response to external loading. These defects are extremely stable with increasing energetic stability as they grow in size. At the sizes visible within a transmission electron microscope, they appear nearl…
Controlling crystal nucleation is a crucial step in obtaining high quality protein crystals for structure determination by X-ray crystallography. Carbon nanomaterials (CNMs) including carbon nanotubes, graphene oxide, and carbon black provide a range of surface topographies, porosities and length scales; functionalisa…
A series of strong Lewis acid-free alkoxide/siloxide-based Mg electrolytes were deliberately developed with remarkable oxidative stability up to 3.5 V (vs. Mg/Mg(2+)). Despite the perception of ROMgCl (R=alkyl, silyl) as a strong base, ROMgCl acts like Lewis acid, whereas the role of MgCl2 in was unambiguously demonst…
Ruthenium hydride was synthesized at a hydrogen pressure of about 14 GPa in a diamond-anvil cell. Energy-dispersive x-ray diffraction was used to monitor the ruthenium crystal structure as a function of hydrogen pressure up to 30 GPa. The hydride formation was accompanied by phase transition from the original hcp stru…
The pharmacological treatment of Parkinson's disease (PD) is limited to dopamine agonists and anti-cholinergic drugs that do not stop the progress of disease. LDopa was introduced to the treatment in 1967; this drug is still the best and most commonly used drug since it generates a real improvement in patient quality…
For CH···O hydrogen bonds in assembled structures and the applications, one of the critical issues is how molecular spatial structures affect their interaction modes as well as how to translate the different modes into the macroscopic properties of materials. Herein, coumarin-derived isomeric hydrogelators with differ…
Colloidal quantum dots (CQDs) are promising materials for solar cells because their optoelectronic properties are easily adjusted by control of their size, structure and composition. We present calculations of the band gap and radiative lifetime for varying core diameter and shell thickness of CdSe/CdTe core/shell Typ…
This work focuses on achieving the modulation of optical and swelling properties of nanomaterials based on the self-assembly of thermostimuli polymers around metallic nanoparticles (NPs) for the obtention of functional plasmonic-polymer core/shell nanohybrids. Moreover, an important effort is made for understanding th…
Titanium dioxide (TiO2) is an attractive anode material for energy storage devices due to its low-volume-change and high safety. However, TiO2 anodes usually suffer from poor electrical and ionic conductivity, thus causing dramatic degradation of electrochemical performance at rapid charge/discharge rates, which has h…
Three compounds associating for the first time polyoxotungstates, bisphosphonates, and copper ions were structurally characterized. They consist in heteropolyanionic monodimensional materials where [Cu6(Ale)4(H2O)4](4-) (Ale = alendronate = [O3PC(O)(C3H6NH3)PO3](4-)) complexes alternate with polyoxometalate (POM) unit…
A series of fluoroalkyl-labeled BODIPY dyes have been synthesized with different substituents on the 2- and 6-positions and investigated in terms of their spectroscopic properties. The dyes were decorated with aryl, alkenyl, and alkynyl substituents, respectively. Those substituents are able to expend the dyes’ deloca…
We present thermal measurements of large-area (over $1000\phantom{\rule{0.28em}{0ex}}\ensuremath{\mu}{\mathrm{m}}^{2}$) monolayer graphene samples at cryogenic temperatures to study the electron-phonon thermal conductivity of graphene. By using two large samples with areas which differ by a factor of 10, we are able t…
A simple nonisocyanate route for synthesizing crystallizable and tough aliphatic thermoplastic polyureas (TPUreas) is described. Melt transurethane polycondensation of diethylene glycol bis(3-aminopropyl) ether with bis(hydroxyethyl) hexanediurethane and bis(hydroxyethyl) isophoronediurethane was conducted at 170 °C u…
Optimized ratio in the codelivery of therapeutics is of crucial importance to promote the synergism rather than the antagonistic effects. In this study, a self-healing spongy coating was described to facilitate the surface-mediated delivery of drug "cocktails" proportionally. The formation of spongy structures within…
The integration of semiconductor quantum dots (QDs) into homogeneous Förster resonance energy transfer (FRET) immunoassay kits for clinical diagnostics can provide significant advantages concerning multiplexing and sensitivity. Here we present a facile and functional QD-antibody conjugation method using three commerci…