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Permselectivity and thickness-dependent ion transport properties of overoxidized polyaniline: a mechanistic investigation

Subrata Mondal、M.V. Sangaranarayanan2016-01-01Physical Chemistry Chemical Physics

has been analyzed using cyclic voltammetry, hydrodynamic voltammetry and electrochemical impedance spectroscopy. This permselectivity vis a vis anion exclusivity arises from the incorporation of counter anions rather than by the formation of new functional groups in the polymer upon overoxidation - as inferred from FT…

Electrochemical sensors and biosensorsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Experimental and theoretical charge density assessments for the 4-perfluoropyridyl- and 4-perflurophenyl-1,2,3,5-dithiadiazolyl radicals

S. Domagała、Delia A. Haynes2016-01-01CrystEngComm

The results of an experimental density analysis of 4-perfluoropyridyl-1,2,3,5-dithiadiazolyl (NF-radical) are presented and compared with the previously reported analysis of the related 4-perfluorophenyl-1,2,3,5-dithiadiazolyl (F-radical). Both the NF- and F-radicals form dimers in their crystal lattice. The strong in…

Magnetism in coordination complexesNonlinear Optical Materials ResearchOrganic and Molecular Conductors Research

Isabgol–silk fibroin 3D composite scaffolds as an effective dermal substitute for cutaneous wound healing in rats

Thangavel Ponrasu、Pagidipally Vishal、Ramya Kannan 等 5 位作者2016-01-01RSC Advances

Psyllium husk based silk 3D scaffolds were developed <italic>via</italic> freeze drying method without adding any bioactive substances to enhance tissue repair during cutaneous wound healing in rats.

Electrospun Nanofibers in Biomedical ApplicationsWound Healing and TreatmentsSilk-based biomaterials and applications

Hierarchized band gap and enhanced optical responses of trivalent rare-earth metal nitrates due to (d–p)π conjugation interactions

Bing‐Hua Lei、Qingrong Kong、Zhihua Yang 等 6 位作者2016-01-01Journal of Materials Chemistry C

A hierarchized band gap, as well as enhanced linear and nonlinear optical responses, result from (d–p)π conjugation interactions in trivalent rare-earth metal nitrates.

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Understanding the Adsorption of Quinoxaline Derivatives as Corrosion Inhibitors for Mild Steel in Acidic Medium: Experimental, Theoretical and Molecular Dynamic Simulation Studies

Hassane Lgaz、R. Salghi2016-01-01Journal of Steel Structures & Construction

The anti-corrosive properties of (E)-3-styrylquinoxalin-2(1H)-one (STQ), (E)-1-benzyl-3-(4-methoxystyryl) quinoxalin-2(1H)-one (BMQ) and (E)-3-(2-(furan-2-yl) vinyl) quinoxalin-2(1H)-one (FVQ) were analyzed by different techniques such as: potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), wei…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilitySynthesis and Biological Evaluation

Effect of ampoule support on the growth of organic benzimidazole single crystals by vertical Bridgman technique for nonlinear optical applications

A. G. Gopala Krishna、N. Vijayan、Chandan Bagdia 等 8 位作者2016-01-01CrystEngComm

Benzimidazole single crystals were grown using a vertical Bridgman technique with modified ampoule design. The thermal fluctuations during the melt were effectively controlled by the glass ampoule support which was filled with alumina wool in order to maintain a proper temperature gradient throughout the growth proces…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchPhase-change materials and chalcogenides

Magnetic gas sensing exploiting the magneto-optical Kerr effect on ZnO nanorods/Co layer system

R. Ciprian、C. Baratto、Angelo Giglia 等 11 位作者2016-01-01RSC Advances

A new system based on a Co film covered by ZnO nanorods has been fabricated with sputtering technique. It represents a promising candidate for future generation of magnetic gas sensing devices.

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCharacterization and Applications of Magnetic Nanoparticles

Characterization of Ornamental Rock Residue and Potassium Liberation Via Organic Acid Application

Ramires Ventura Machado、Felipe Vaz Andrade、Renato Ribeiro Passos 等 6 位作者2016-01-01Revista Brasileira de Ciência do Solo

Organic acids present in organic matter and, or, exudates by microorganisms and plants can increase the liberation of potassium present in minerals. The objective of this study was to characterize the residue from ornamental rocks and evaluate the release of K from these residues after the application of organic acids…

Concrete and Cement Materials ResearchRecycling and utilization of industrial and municipal waste in materials productionClay minerals and soil interactions

A water-soluble gadolinium metallofullerenol: facile preparation, magnetic properties and magnetic resonance imaging application

Jie Li、Taishan Wang、Yongqiang Feng 等 9 位作者2016-01-01Dalton Transactions

A new water-soluble gadolinium metallofullerenol was prepared through a solid-liquid reaction. It was characterized to have an enhanced effective magnetic moment, and improved T1-weighted relaxivity and magnetic resonance imaging performance in the liver. This material prepared by a facile method has wide application…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes

Towards understanding the improved stability of palladium supported on TS-1 for catalytic combustion

Adi Setiawan、Jarrod Friggieri、Hadi Hosseiniamoli 等 7 位作者2016-01-01Physical Chemistry Chemical Physics

A novel Pd supported on TS-1 combustion catalyst was synthesized and tested in methane combustion under very lean and under highly humid conditions (<1%). A notable increase in hydrothermal stability was observed over 1900 h time-on-stream experiments, where an almost constant, steady state activity obtaining 90% meth…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

High thermoelectric performance in Sn-substituted α-As 2 Te 3

Jean‐Baptiste Vaney、Julie Carreaud、Gaëlle Delaizir 等 12 位作者2016-01-01Journal of Materials Chemistry C

Substitution of Sn for As in α-As <sub>2</sub> Te <sub>3</sub> enhances the thermoelectric performances with a maximum ZT of 0.8 at 523 K.

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsPerfectionism, Procrastination, Anxiety Studies

Fabrication of superhydrophobic aromatic cotton fabrics

Chao‐Hua Xue、Ling-Yun Deng、Shun-Tian Jia 等 4 位作者2016-01-01RSC Advances

Superhydrophobic fabrics with lasting fragrance were fabricated in light of the development trend of high value-added and multi-functional materials.

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPickering emulsions and particle stabilization

Polyhedron Cu 2 O@Ag composite microstructures: synthesis, mechanism analysis and structure-dependent SERS properties

Haiqing Luo、Jun Zhou、Hanhua Zhong 等 6 位作者2016-01-01RSC Advances

The morphological evolution of polyhedral Cu <sub>2</sub> O crystals and the LSPR and SERS characteristics of the as-synthesized polyhedral Cu <sub>2</sub> O@Ag CMs with different structures.

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanocluster Synthesis and Applications

Hydrogen-bonded networks of [Fe(bpp) 2 ] 2+ spin crossover complexes and dicarboxylate anions: structural and photomagnetic properties

Verónica Jornet‐Mollá、Yan Duan、Carlos Giménez‐Saiz 等 5 位作者2016-01-01Dalton Transactions

The paper reports the syntheses, crystal structures, thermal and (photo)magnetic properties of spin crossover salts of formula [Fe(bpp)2](C6H8O4)·4H2O (1·4H2O), [Fe(bpp)2](C8H4O4)·2CH3OH·H2O (2·2MeOH·H2O) and [Fe(bpp)2](C8H4O4)·5H2O (2·5H2O) (bpp = 2,6-bis(pyrazol-3yl)pyridine; C6H8O4 = adipate dianion; C8H4O4 = terep…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

pH-controlled assembly of three-dimensional tungsten oxide hierarchical nanostructures for catalytic oxidation of cyclohexene to adipic acid

Lei Wang、Mengqiu Huang、Zhangxian Chen 等 7 位作者2016-01-01CrystEngComm

Tungsten oxide has a wide range of applications in chromic devices and catalysis. Effective control over the morphology of tungsten oxide remains a major challenge. Here, we present a facile pH-controlled strategy for synthesizing three-dimensional tungsten oxide architectures with different morphologies without using…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsPolyoxometalates: Synthesis and Applications