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Emission in Gd 6 O 5 F 8 :Yb 3+ ,Er 3+ micro-particles for multimodal luminescence and temperature sensing upon 980 nm excitation

Shanshan Du、Xinlong Ma、Qinping Qiang 等 5 位作者2016-01-01Physical Chemistry Chemical Physics

ions, the visible up-conversion emissions first increase and then decrease, but NIR down-conversion emissions display a distinct trend, in which one peak at 1010 nm is highly suppressed and another at 1530 nm is increased quickly. Furthermore, the 980 nm excited optical temperature sensing property of the synthesized…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Synthesis and property studies of hollow nanostructures

Qingyi Lu、Feng Gao2016-01-01CrystEngComm

Hollow nanomaterials present an important family of nanostructures with low mass density, high porosity, large reaction surface area and good strain accommodation and have great application potentials in many fields. In this article, we reviewed our recent studies on the synthesis and property studies of hollow nanost…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Glycosylated lanthanide cyclen complexes as luminescent probes for monitoring glycosidase enzyme activity

Helen Burke、Thorfinnur Gunnlaugsson、Eoin M. Scanlan2016-01-01Organic & Biomolecular Chemistry

The development of synthetic chemical probes for the detection of enzymes is extremely important for biological, medicinal, and industrial applications. Here we report the synthesis of an array of novel glycosylated Tb(iii) complexes, their photophysical properties in solution, and their ability to function as lumines…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes

Interaction of Rhodamine 6G molecules with graphene: a combined computational–experimental study

Kan Zhang、Shansheng Yu、Baoming Jv 等 4 位作者2016-01-01Physical Chemistry Chemical Physics

In this work, the adsorption of Rhodamine 6G molecules on some graphene substrates is investigated using density functional theory. Some simple models, such as those of perfect graphene, defective graphene, *O/*OH modified graphene and B/N doping graphene, are constructed as substrates to simulate graphene oxide and B…

Graphene research and applicationsMolecular Junctions and NanostructuresGraphene and Nanomaterials Applications

Chiral and fractal: from simple design rules to complex supramolecular constructs

Damian Nieckarz、Paweł Szabelski2016-01-01Chemical Communications

Using theoretical modeling, we demonstrate the self-assembly of functional organic molecules into 2D fractal aggregates resembling the Sierpiński triangle (ST). It is shown for the first time that the fractal self-assembly can be realized in one-component systems comprising K- and A-shaped tectons whose arms meet to f…

Supramolecular Chemistry and ComplexesSupramolecular Self-Assembly in MaterialsSurface Chemistry and Catalysis

Influence of gas atmospheres and ceria on the stability of nanoporous gold studied by environmental electron microscopy and in situ ptychography

Sina Baier、Arne Wittstock、Christian Danvad Damsgaard 等 12 位作者2016-01-01RSC Advances

A novel complementary approach of environmental TEM and <italic>in situ</italic> hard X-ray ptychography was used to study the thermally induced coarsening of nanoporous gold under different atmospheres, pressures and after ceria deposition.

Catalytic Processes in Materials ScienceAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Glycidyl alkoxysilane reactivities towards simple nucleophiles in organic media for improved molecular structure definition in hybrid materials

X. Guillory、Arnaud Tessier、G.-O. Gratien 等 8 位作者2016-01-01RSC Advances

We report the first comprehensive study of the reactivity in organic media of (3-glycidyloxypropyl)trialkoxysilanes towards common nucleophiles. Their reactivity have to be emphasized in order to design and to improve new sol–gel hybrid synthesis.

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsSilicone and Siloxane Chemistry

A homoleptic, all-alkynyl-stabilized highly luminescent Au 8 Ag 8 cluster with a single crystal X-ray structure

Rui Zhang、Chongyang Zhao、Xiumin Li 等 7 位作者2016-01-01Dalton Transactions

A homoleptic, all-alkynyl-stabilized [Au8Ag8(ArC[triple bond, length as m-dash]C)16] (1, Ar = 3,5-di-tert-butylphenyl) cluster was synthesized and characterized with a single crystal X-ray structure. Reactions of 3,5-di-tert-butyl-phenylacetylene with Ag(i) and Au(i) gave [Ag(ArC[triple bond, length as m-dash]C)]n and…

Nanocluster Synthesis and ApplicationsPharmacological Effects and Toxicity StudiesInorganic Chemistry and Materials

Insoluble layer deposition and dilatational rheology at a microscale spherical cap interface

Anthony P. Kotula、Shelley L. Anna2016-01-01Soft Matter

The dilatational properties of insoluble monolayers are important for understanding the mechanics of biological systems and consumer products, but isolating the dilatational response of an interface is challenging due to the difficulties in separating dilatation from shear and other deformation modes. Oscillations of…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Solid solution Pb 1−x Eu x Te: constitution and thermoelectric behavior

Xinke Wang、Igor Veremchuk、Matej Bobnar 等 5 位作者2016-01-01Inorganic Chemistry Frontiers

The thermoelectric properties of polycrystalline materials on the basis of the solid solution Pb <sub>1−x</sub> Eu <sub>x</sub> Te prepared by spark-plasma-sintering are characterized. The solid solution undergoes a metal–semiconductor transition in parallel to the p–n transition around 500 K.

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsAdvanced Semiconductor Detectors and Materials

A combined experimental and computational study of the substituent effect on the photodynamic efficacy of amphiphilic Zn( ii )phthalocyanines

Anzhela Galstyan、Kristina Riehemann、Michael Schäfers 等 4 位作者2016-01-01Journal of Materials Chemistry B

Zinc(ii)phthalocyanines (Zn(ii)Pc) have shown promising applications in photodynamic therapy due to their high quantum yield of singlet oxygen generation; however, optimization of their overall properties are required before their clinical application as photosensitizers (PSs). The photosensitization efficiency of pho…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Depletion Layer Formation in Alkali Silicate Glasses by Electro-Thermal Poling

Charles T. McLaren、Marco Balabajew、Michael Gellert 等 5 位作者2016-01-01Journal of The Electrochemical Society

Electro-thermal poling of alkali-containing glasses has been known to enhance various physical and chemical properties due to the formation of an alkali ion depletion layer. We have investigated the role of alkali ion migration in depletion layer formation by in situ impedance spectroscopy, poling current measurements…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsSilicon Nanostructures and Photoluminescence

Tunable electronic structures of germanium monochalcogenide nanosheets via light non-metallic atom functionalization: a first-principles study

Yi Ding、Yanli Wang2016-01-01Physical Chemistry Chemical Physics

Germanium monochalcogenides, i.e. GeS and GeSe sheets, are isoelectronic analogues of phosphorene, which have been synthesized in recent experiments (P. Ramasamy et al., J. Mater. Chem. C, 2016, 4, 479). Utilizing first-principles calculations, we have investigated their tunable electronic and magnetic properties via…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Universal model for defect-related visible luminescence in ZnO nanorods

E. G. Barbagiovanni、Vincenzina Strano、G. Franzò 等 8 位作者2016-01-01RSC Advances

We study the optical properties of ZnO nanorods (NRs) fabricated by chemical bath deposition, hydrothermal, and the vapour–liquid–solid method (VLS). Scanning electron microscopy demonstrates differences in the structural properties for the various samples. The optical emission properties are studied by photoluminesce…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Engineering the hot spots in squared arrays of gold nanoparticles on a silver film

Anran Li、Sachin Kumar Srivastava、Ibrahim Abdulhalim 等 4 位作者2016-01-01Nanoscale

Density of nanoparticle (NP) arrays affects the hot spots distribution and strength in NP-metal film (NP-MF) geometry. In-depth understanding of the variation of electromagnetic (EM) field enhancement with NPs density is essential for wide applications of the NP-MF geometry such as surface-enhanced spectroscopies and…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanomaterials and Printing Technologies