Materials Literature
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Amorphous, highly thermal stable, Troger's base segments containing covalent triazine frameworks with high CO <sub>2</sub> adsorptions (up to 16.84 wt% at 273 K and 1.10 bar).
Polymer-derived silicon oxycarbides exhibiting ≤1 and 10 vol.% of segregated carbon finely dispersed within a glassy SixOyCz matrix have been investigated by UV Raman spectroscopy using a laser excitation of 4.8 eV (λ = 256.7 nm). Carbon exists as amorphous sp2–sp3 bonded component in SiOC/C (≤1 vol.%) pyrolyzed at 11…
A study has been undertaken on the effect of additives on the phase transition of ammonium nitrate(V) (AN). Results obtained using Differential Scanning Calorimetry (DSC) showed that organic compounds and potassium salts of organic compounds have an effect on the phase transition behavior of AN. The samples were furth…
In order to improve the scale inhibition efficiency of existing scale inhibitors for industrial water and to reduce the phosphorus pollution of water bodies, a new type of scale inhibitor with a hyper-branched structure has been developed.
In this work, doctor blading is proposed for the fabrication of strongly-coupled QD solids from a PbS nanoink for photodetection at telecom wavelengths.
Several novel aryl substituted 2-halogencinchomeronic dinitriles, possessing an intensive solid state fluorescence, were synthesized. The relationship between the chemical structures and photophysical properties of these compounds was investigated.
The structure of KMgPO <sub>4</sub> is formed by six-membered rings of tetrahedral MgO <sub>4</sub> and PO <sub>4</sub> , linked by common vertices and by large cavities that are occupied by K <sup>+</sup> cations.
Well-crystallized W-doped VO <sub>2</sub> with low phase transition temperature and excellent balance between <italic>T</italic> <sub>c</sub> and latent heat.
S QDs exhibit superior photostability and biocompatibility, making them promising probes for in vivo NIR-II imaging.
Photocatalytic partial oxidation of cyclohexane with O <sub>2</sub> and solar light by mesoporous silica with grafted Ti coupled to Fe oxide nanoparticles.
This study reports the preparation of a novel fluorinated dendrimer bearing PVDF branches by click chemistry and its characterization by several analytical methods.
The as-prepared Fe <sub>3</sub> O <sub>4</sub> /MIL-101(Fe) shows enhanced catalytic performance for the dimerization reaction of <italic>o</italic> -phenylenediamine <italic>via</italic> synergistic peroxidase-like activity.
The novel bio-based polymer networks with shape memory behavior were synthesized from polylactide-based tetraols and hexamethylene diisocyanate trimer.
Two multifunctional emitters based on asymmetric molecular design overcome the ACQ. The devices showed impressive performance and the emitters showed mechanochromic properties.
The delivery of anti-cancer agents to brain tumors represent a challenge because the blood-brain tumor barrier (BBTB) effectively limits the delivery of many agents. A new generation 3 (G3) dendrimer-based curcumin (Curc) conjugate was synthesized. The synthesized G3-Curc conjugate demonstrated full solubility in aque…
A series of boron-containing conjugated polymers with hierarchical porous structures have been prepared <italic>via</italic> Sonogashira–Hagihara coupling for catalysing stoichiometric homo-coupling reactions of aryl Grignard regents with size selectivity.
Bright Zn–Ni alloys can be obtained from the bath with additives. The mechanism of better corrosion resistance of bright Zn–Ni alloys compared to dull Zn–Ni alloys was analyzed by XPS and EIS.
A series of Fe(2+) spin crossover (SCO) complexes [Fe(5/6)](2+) employing hexadentate ligands (5/6) with cis/trans-1,2-diamino cyclohexanes (4) as central building blocks were synthesised. The ligands were obtained by reductive amination of 4 with 2,2'-bipyridyl-6-carbaldehyde or 1,10-phenanthroline-2-carbaldehyde 3.…
(x = 0.25, 0.5, 0.75) nanoparticles. The chemical composition and phase purity of the tetradymite-type materials were determined by EDX and XRD and the surface composition of the nanoparticles was further investigated by IR and XPS. In addition, the morphology of the nanoparticles was investigated by SEM and TEM.
ZnO nanomaterials are gaining lots of attention due to their biocompatible nature coupled with promising piezoelectric properties, envisioning a new generation of lead-free smart materials.