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Mid-infrared emission and quantitative analysis of energy transfer processes in Er3+ doped oxyfluogermanate glasses

Muzhi Cai、Beier Zhou、Fengchao Wang 等 7 位作者2015-06-26Journal of Applied Physics

Oxyfluogermanate glasses with good thermal stability were prepared by melt-quenching method. The investigation of 2.7 μm fluorescence spectra and energy transfer mechanism was performed pumped by an 808 nm laser diode. The 2.7 μm radiative transition probability and emission cross section are 32.62 s−1 and 12.88 × 10−…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

A BIOGENIC APPROACH FOR THE SYNTHESIS AND CHARACTERIZATION OF ZINC OXIDE NANOPARTICLES PRODUCED BY TINOSPORA CORDIFOLIA

L.F.A. Anand Raj、E Jayalakshmy2015-06-26International Journal of Pharmacy and Pharmaceutical Sciences

Objective : The study mainly focuses on the preparation and characterization of Zinc oxide nanoparticles using an aqueous stem extract of Tinospora cordifolia. Methods : Zinc Oxide nanoparticles were synthesized by a biological method using the stem extract of Tinospora cordifolia using Zinc acetate dehydrate in the p…

Nanoparticles: synthesis and applicationsPhytochemicals and Medicinal Plants

Spectroscopic ellipsometry, photoluminescence and Kelvin probe force microscopy studies of CdSe nanoparticles dispersed on ZnS thin film

Intu Sharma、Yogita Batra、B. R. Mehta2015-06-26Journal of Applied Physics

Structural, optical, and surface potential properties of CdSe nanoparticles (NPs) prepared on ZnS thin-films have been investigated. CdSe NPs/ZnS thin-films with varying CdSe NPs diameters are synthesised by sequential radio frequency magnetron sputtering technique. A blue shift in the optical absorption edge and enha…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Dimensional Reduction From 2D Layer to 1D Band for Germanophosphates Induced by the “Tailor Effect” of Fluoride

Chun‐Zuo Huang、Biao Liu、Lei Wen 等 8 位作者2015-06-26Inorganic Chemistry

The "tailor effect" of fluoride, exclusively as a terminal rather than a bridge, was applied successfully to design low-dimensional structures in the system of transition metal germanophosphates for the first time. Two series of new compounds with low-dimensional structures are reported herein. K[M(II)Ge(OH)2(H0.5PO4)…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationInorganic Fluorides and Related Compounds

Surface-Initiated Chain Growth Polyaramid Brushes

Frederick C. Prehn、Stephen G. Boyes2015-06-26Macromolecules

Synthesis of well-defined, surface-initiated poly( N -octyl- p -benzamide) brushes was demonstrated using a new “grafting from” chain growth technique. A solution-based chain growth polycondensation technique was adopted from literature and modified to form a polyaramid brush by taking advantage of the differences in…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Antioxidant Effect of Hydroxylated Diamond Nanoparticles Measured in Soybean Oil

Kinga Adach、Mateusz Fijałkowski、Janusz Skolimowski2015-06-26Fullerenes Nanotubes and Carbon Nanostructures

We investigated the antioxidant properties of detonation nanodiamond modified by Fenton's reagent. Diamond nanoparticles functionalized with hydroxyl groups were examined in soybean oil; the aim of this study was to determine their antioxidant properties by examining the effect on the lipid peroxidation process. In or…

Diamond and Carbon-based Materials ResearchElectrospun Nanofibers in Biomedical ApplicationsPorphyrin and Phthalocyanine Chemistry

Microstructure and wear mechanism change by Nb added in slag free self-shielded flux cored wire

D. S. Liu、Yanhong Wei、R. P. Liu2015-06-26Science and Technology of Welding & Joining

The iron based hardfacing alloys were produced using slag free self-shielded flux cored wires with varying niobium contents. The results show that NbC acted as the nucleus of primary M 7 (C, B) 3 (M = Cr, Fe mainly) carbides and decreased the amount of M 7 (C,B) 3 carbides when niobium was added into the alloys. When…

High Entropy Alloys StudiesAdvanced materials and compositesMetal Alloys Wear and Properties

Isoprenoid Biosynthesis in Pathogenic Bacteria: Nuclear Resonance Vibrational Spectroscopy Provides Insight into the Unusual [4Fe‐4S] Cluster of the E. coli LytB/IspH Protein

Isabelle Faus、Annegret Reinhard、Sergej Rackwitz 等 12 位作者2015-06-26Angewandte Chemie International Edition

The LytB/IspH protein catalyzes the last step of the methylerythritol phosphate (MEP) pathway which is used for the biosynthesis of essential terpenoids in most pathogenic bacteria. Therefore, the MEP pathway is a target for the development of new antimicrobial agents as it is essential for microorganisms, yet absent…

Enzyme Structure and FunctionMetal-Catalyzed Oxygenation MechanismsATP Synthase and ATPases Research

Interplay between magnetic order at Mn and Tm sites alongside the structural distortion in multiferroic films ofo−TmMnO3

Yoav William Windsor、Mahesh Ramakrishnan、Laurenz Rettig 等 10 位作者2015-06-26Physical Review B

We employ resonant soft x-ray diffraction to individually study the magnetic ordering of the Mn and the Tm sublattices in single-crystalline films of orthorhombic $(o\text{\ensuremath{-}})\phantom{\rule{0.16em}{0ex}}\mathrm{TmMn}{\mathrm{O}}_{3}$. The same magnetic ordering wave vector of $(0\phantom{\rule{0.16em}{0ex…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Amorphization and Directional Crystallization of Metals Confined in Carbon Nanotubes Investigated by in Situ Transmission Electron Microscopy

Dai‐Ming Tang、Cuilan Ren、Ruitao Lv 等 14 位作者2015-06-26Nano Letters

The hollow core of a carbon nanotube (CNT) provides a unique opportunity to explore the physics, chemistry, biology, and metallurgy of different materials confined in such nanospace. Here, we investigate the nonequilibrium metallurgical processes taking place inside CNTs by in situ transmission electron microscopy usi…

Carbon Nanotubes in CompositesAdvanced Electron Microscopy Techniques and ApplicationsNanopore and Nanochannel Transport Studies

Electronic and magnetism properties of two-dimensional stacked nickel hydroxides and nitrides

Xiaolin Wei、Zhen‐Kun Tang、Gencai Guo 等 5 位作者2015-06-26Scientific Reports

Two-dimensional (2D) layered materials receive a lot of attention because of their outstanding intrinsic properties and wide applications. In this work, the structural, electronic and magnetic properties of nickel hydroxides (Ni(OH)2) and nitrides XN (X = B, Al, and Ga) heterostructures are studied by first-principles…

ZnO doping and properties2D Materials and ApplicationsGa2O3 and related materials

Adhesion Tuning at Superhydrophobic States: From Petal Effect to Lotus Effect

Guangming Gong、Juntao Wu、Jin Xu 等 4 位作者2015-06-26Macromolecular Materials and Engineering

The influence of the micro topology on the solid/water wetting and adhesion behaviors is studied in this work. By simply tailoring the morphology, superhydrophobicity can be achieved on a weak hydrophobic surface. And the further fine‐tuning of the surficial geometry realizes the conversion of superhydrophobic states,…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Improving the helium gas barrier properties of epoxy coatings through the incorporation of graphene nanoplatelets and the influence of preparation techniques

Louis Johann van Rooyen、J. Karger‐Kocsis、L. D. Kock2015-06-26Journal of Applied Polymer Science

ABSTRACT Graphene/epoxy nanocomposite coatings were formulated by applying different dispersion and preparation methods to determine whether the coatings might be a potential gas barrier material for irradiated graphite waste which is known to release radioactive gases like tritium ( 3 H 2 ). Helium was used as a subs…

Graphene research and applicationsHigh voltage insulation and dielectric phenomenaGraphite, nuclear technology, radiation studies

Biomass Oxidation: Formyl CH Bond Activation by the Surface Lattice Oxygen of Regenerative CuO Nanoleaves

Prince Nana Amaniampong、Quang Thang Trịnh、Bo Wang 等 6 位作者2015-06-26Angewandte Chemie

Abstract An integrated experimental and computational investigation reveals that surface lattice oxygen of copper oxide (CuO) nanoleaves activates the formyl CH bond in glucose and incorporates itself into the glucose molecule to oxidize it to gluconic acid. The reduced CuO catalyst regains its structure, morphology,…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Water Dynamics in Nanoporous Alteration Layer Coming from Glass Alteration: An Experimental Approach

Diane Rébiscoul、Julien Cambedouzou、Ibrahim Matar Briman 等 6 位作者2015-06-26The Journal of Physical Chemistry C

Protons dynamics in borosilicate glasses of various compositions (SiO 2 /B 2 O 3 /NaO/CaO/X, with X = Al 2 O 3 or ZrO 2 ) at various stages of alteration have been characterized at a picosecond scale using quasielastic neutron scattering (QENS). The results obtained were compared to the one from porous silica-based ma…

Concrete and Cement Materials ResearchGlass properties and applicationsClay minerals and soil interactions

Regularity in Time for Weak Solutions of a Continuum Model for Epitaxial Growth with Elasticity on Vicinal Surfaces

Irene Fonseca、Giovanni Leoni、Xin Lü2015-06-26Communications in Partial Differential Equations

The evolution equation derived by Xiang (SIAM J. Appl. Math. 63:241–258, 2002) to describe vicinal surfaces in heteroepitaxial growth is (1) where h denotes the surface height of the film, and H is the Hilbert transform. Existence of solutions was obtained by Dal Maso et al. (Arch. Rational Mech. Anal. 212: 1037–1064)…

Solidification and crystal growth phenomenaAdvanced Mathematical Modeling in EngineeringFluid Dynamics and Thin Films

Improved impact strength of epoxy by the addition of functionalized multiwalled carbon nanotubes and reactive diluent

Wellington Marcos da Silva、Hélio Ribeiro、Juliana Cardoso Neves 等 5 位作者2015-06-26Journal of Applied Polymer Science

ABSTRACT Multiwalled carbon nanotubes (MWCNTs), both oxidized and amine functionalized (triethylenetetramine—TETA), have been used to improve the mechanical properties of nanocomposites based on epoxy resin. The TGA and XPS analysis allowed the evaluation of the degree of chemical modification on MWCNTs. Nanocomposite…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Precipitating Sodium Dodecyl Sulfate to Create Ultrastable and Stimulable Foams

Li Zhang、Alesya Mikhailovskaya、Pavel Yazhgur 等 8 位作者2015-06-26Angewandte Chemie

Abstract Ultrastable foams are made very simply by adding salt (NaCl or KCl) to sodium dodecyl sulfate. The addition of high concentrations of salt leads to the precipitation of the surfactant on the bubble surfaces and as crystals in the interstices between the bubbles. As a consequence, the ageing of the foams is st…

Enhanced Oil Recovery TechniquesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Influence of Guest Exchange on the Magnetization Dynamics of Dilanthanide Single‐Molecule‐Magnet Nodes within a Metal–Organic Framework

Xuejing Zhang、Veacheslav Vieru、Xiaowen Feng 等 13 位作者2015-06-26Angewandte Chemie

Abstract Multitopic organic linkers can provide a means to organize metal cluster nodes in a regular three‐dimensional array. Herein, we show that isonicotinic acid N ‐oxide (HINO) serves as the linker in the formation of a metal–organic framework featuring Dy 2 single‐molecule magnets as nodes. Importantly, guest sol…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Realizing Tunable Inverse and Normal Doppler Shifts in Reconfigurable RF Metamaterials

Jia Ran、Yewen Zhang、Xiaodong Chen 等 7 位作者2015-06-26Scientific Reports

The Doppler effect has well-established applications in astronomy, medicine, radar and metrology. Recently, a number of experimental demonstrations of the inverse Doppler effect have begun to appear. However, the inverse Doppler effect has never been observed on an electronically reconfigurable system with an external…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies