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Obtaining Highly Crystalline Barium Sulphate Nanoparticles via Chemical Precipitation and Quenching in Absence of Polymer Stabilizers

Ángela B. Sifontes、Edgar Cañizales、Jhoan Toro‐Mendoza 等 9 位作者2015-01-01Journal of Nanomaterials

Here we report the synthesis of barium sulphate (BaSO 4 ) nanoparticles from Ba(OH) 2 /BaCl 2 solutions by a combined method of precipitation and quenching in absence of polymer stabilizers. Transmission electron microscopy (HRTEM), Fourier transforms infrared spectroscopy (FTIR), and X‐ray diffraction (XRD) were empl…

Ferroelectric and Piezoelectric MaterialsX-ray Diffraction in CrystallographyPigment Synthesis and Properties

Constant capacitance in nanopores of carbon monoliths

Alejandra García‐Gómez、Gelines Moreno‐Fernández、Belén Lobato 等 4 位作者2015-01-01Physical Chemistry Chemical Physics

The results obtained for binder-free electrodes made of carbon monoliths with narrow micropore size distributions confirm that the specific capacitance in the electrolyte (C2H5)4NBF4/acetonitrile does not depend significantly on the micropore size and support the foregoing constant result of 0.094 ± 0.011 F m(-2).

Carbon Nanotubes in CompositesSupercapacitor Materials and FabricationConducting polymers and applications

Ruthenium-caged antisense morpholinos for regulating gene expression in zebrafish embryos

Julianne C. Griepenburg、Teresa L. Rapp、Patrick J. Carroll 等 5 位作者2015-01-01Chemical Science

. One-cell-stage zebrafish embryos microinjected with Ru-MO and incubated in the dark for 24 h developed normally, consistent with caging, whereas irradiation at 450 nm dissociated one 3-ethynylpyridine ligand (ϕ = 0.33) and uncaged the MO to achieve gene knockdown. As demonstrated, Ru photolinkers provide a versatile…

Chemical Synthesis and AnalysisPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Bidirectional photoswitching of magnetic properties at room temperature: ligand-driven light-induced valence tautomerism

Alexander Witt、Frank W. Heinemann、Marat M. Khusniyarov2015-01-01Chemical Science

molecules per s under our conditions. Consequently, this work may open new horizons in applications of molecular switches based on VT metal complexes in molecular devices functioning at room temperature.

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence Chemistry

New nanoplatforms based on UCNPs linking with polyhedral oligomeric silsesquioxane (POSS) for multimodal bioimaging

Xiaoqian Ge、Liang Dong、Lining Sun 等 7 位作者2015-01-01Nanoscale

A new and facile method was used to transfer upconversion luminescent nanoparticles from hydrophobic to hydrophilic using polyhedral oligomeric silsesquioxane (POSS) linking on the surface of upconversion nanoparticles. In comparison with the unmodified upconversion nanoparticles, the POSS modified upconversion nanopl…

Luminescence Properties of Advanced MaterialsLuminescence and Fluorescent MaterialsSilicone and Siloxane Chemistry

Facile, green and affordable strategy for structuring natural graphite/polymer composite with efficient electromagnetic interference shielding

Xin Jiang、Ding‐Xiang Yan、Yu Bao 等 6 位作者2015-01-01RSC Advances

The mechanical mixing and hot compaction method was firstly used to fabricate graphite/polymer segregated composite for efficient electromagnetic interference shielding.

Electromagnetic wave absorption materialsFlame retardant materials and propertiesFiber-reinforced polymer composites

Polysaccharide-assisted rapid exfoliation of graphite platelets into high quality water-dispersible graphene sheets

Ilke Uysal‐Unalan、Chaoying Wan、Silvia Trabattoni 等 5 位作者2015-01-01RSC Advances

High quality graphene has been obtained by polysaccharide-assisted ultrasonication in aqueous medium. This approach provides an economical, solvent-free, high-yield, and industrially scalable route for new applications of graphene-based nanocomposites.

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications

A Database of Static Clothing Thermal Insulation and Vapor Permeability Values of Non-Western Ensembles for Use in ASHRAE Standard 55, ISO 7730 and ISO 9920

George Havenith、Kalev Kuklane、Jintu Fan 等 8 位作者2015-01-01PolyU Institutional Research Archive (Hong Kong Polytechnic University)

Four different thermal manikins (male and female shapes)in three different laboratories (UK, Sweden, and China) were used to determine the clothing thermal insulation values of 52 non-Western, mainly indoor clothing ensembles in order to expand the existing clothing database for use with ANSI/ASHRAE Standard 55-2013,…

Thermoregulation and physiological responsesTextile materials and evaluationsColor perception and design

Simple preparation of positively charged silver nanoparticles for detection of anions by surface-enhanced Raman spectroscopy

A. W. Stewart、Seth C. Murray、Steven E. J. Bell2015-01-01The Analyst

Modification of citrate and hydroxylamine reduced Ag colloids with thiocholine bromide, a thiol functionalized quaternary ammonium salt, creates particles where the zeta potential is switched from the normal values of ca.-50 mV to ca. +50 mV. These colloids are stable but can be aggregated with metal salts in much the…

Gold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and ApplicationsNanocluster Synthesis and Applications

Optically switchable transistors comprising a hybrid photochromic molecule/n-type organic active layer

Karl Börjesson、Martin Herder、Lutz Grubert 等 8 位作者2015-01-01Journal of Materials Chemistry C

Photoswitchable transistors based on a blend of an n-type fullerene derivative and a photochromic diarylethene can be gated either through the gate electrode or by photoisomerization of the diarylethene molecules.

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

La 5 Ti 2 Cu 1−x Ag x S 5 O 7 photocathodes operating at positive potentials during photoelectrochemical hydrogen evolution under irradiation of up to 710 nm

Takashi Hisatomi、S. Okamura、Jingyuan Liu 等 9 位作者2015-01-01Energy & Environmental Science

Photoelectrodes of Al-doped La <sub>5</sub> Ti <sub>2</sub> Cu <sub>1−x</sub> Ag <sub>x</sub> S <sub>5</sub> O <sub>7</sub> powder generate a photocathodic current attributable to the hydrogen evolution reaction at +0.7 V <italic>vs.</italic> RHE.

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

First evidence of light-induced spin transition in molybdenum( iv )

Nathalie Bridonneau、Jérôme Long、J. L. Cantin 等 9 位作者2015-01-01Chemical Communications

Photo-induced spin transition in a molybdenum-zinc complex has been evidenced and fully characterized by Squid magnetometry and several spectroscopies performed under irradiation (IR, EPR, etc.). The phenomenon has been confirmed by X-ray diffraction and DFT calculations yielding a Light-Induced Excited Spin State Tra…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Red to near infrared ultralong lasting luminescence from Mn 2+ -doped sodium gallium aluminum germanate glasses and (Al,Ga)-albite glass-ceramics

Pengfei Li、Mingying Peng、Lothar Wondraczek 等 5 位作者2015-01-01Journal of Materials Chemistry C

Red to near infrared ultralong lasting luminescence was observed from Mn <sup>2+</sup> -doped sodium gallium aluminum germanate glasses and (Al,Ga)-albite glass-ceramics.

Luminescence Properties of Advanced MaterialsGlass properties and applicationsRandom lasers and scattering media

Tunable blue-green emission and energy transfer properties in β-Ca 3 (PO 4 ) 2 :Eu 2+ , Tb 3+ phosphors with high quantum efficiencies for UV-LEDs

Kai Li、Yang Zhang、Xiaojing Li 等 6 位作者2015-01-01Dalton Transactions

A series of Eu(2+) and Tb(3+) singly-doped and co-doped β-Ca3(PO4)2 phosphors have been synthesized via the high-temperature solid-state reaction method. Thermogravimetric (TG) analysis, fourier transform infrared (FT-IR) spectra, X-ray diffraction (XRD) patterns and Rietveld refinements, photoluminescence (PL) spectr…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsRadiation Detection and Scintillator Technologies