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Surface grafted poly(ε-caprolactone) prepared using organocatalysed ring-opening polymerisation followed by SI-ATRP

Francesca Ercole、Andrew E. Rodda、Laurence Meagher 等 5 位作者2014-01-01Polymer Chemistry

The controlled ring-opening polymerisation (ROP) of an ATRP initiator-containing lactone, γ-BMPCL, and its copolymerisation with ε-caprolactone is reported. One resulting copolymer was successfully used as a substrate for surface initiated ATRP to produce surface-grafted poly(oligo(ethylene glycol) methacrylate) brush…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

A kinetics study on promising hydrogen storage properties of Mg-based thin films at room temperature

Jianglan Qu、Yang Liu、Gongbiao Xin 等 5 位作者2014-01-01Dalton Transactions

Pd-Mg-Pd thin films with variable thickness of Mg layers were prepared. Their optical and electrical changes in both gasochromic and chemochromic processes were compared to investigate the kinetics of Mg-based thin films at room temperature. Hydrogen absorption and desorption kinetics of Pd-Mg-Pd thin films were stron…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Dual-stage growth factor release within 3D protein-engineered hydrogel niches promotes adipogenesis

Midori Greenwood‐Goodwin、Eric S. Teasley、Sarah C. Heilshorn2014-01-01Biomaterials Science

We developed a strategy for dual-stage delivery of fibroblast growth factor 1 (FGF-1) and bone morphogenetic protein 4 (BMP-4) within 3D biomimetic hydrogels to promote adipogenesis of human adipose-derived stromal cells.

Electrospun Nanofibers in Biomedical Applications3D Printing in Biomedical ResearchTissue Engineering and Regenerative Medicine

Bi-Continuous Nanoporous Structure Formation via Compound Decomposition

Qing Chen2014-01-01Journal of The Electrochemical Society

During a dealloying process, reactive components in an alloy are selectively dissolved, leaving behind a bi-continuous porous structure composed of the remaining more noble constituents. This morphology has attracted attention in a variety of applications such as catalysis, actuation and sensing. Here, we show that si…

Electrocatalysts for Energy ConversionAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Synthesis of chiral core based triazole dendrimers with m-terphenyl surface unit and their antibacterial studies

Ayyavu Thirunarayanan、Sebastian Raja、G Mohanraj 等 4 位作者2014-01-01RSC Advances

Antibacterial activity against <italic>Shigella dysenteriae</italic> , <italic>Staphylococcus aureus</italic> and <italic>Serratia marcescen</italic> was studied with <italic>S</italic> -BINOL based triazole dendrimers <bold>1</bold> , <bold>2</bold> and <bold>3</bold> with <italic>m</italic> -terphenyl surface units.…

Chemical Synthesis and AnalysisClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

Redox-exchange induced heterogeneous RuO2-conductive polymer nanowires

Zhe Gui、Jonathon Duay、Junkai Hu 等 4 位作者2014-01-01Physical Chemistry Chemical Physics

A redox exchange mechanism between potassium perruthenate (KRuO4) and the functional groups of selected polymers is used here to induce RuO2 into and onto conductive polymer nanowires by simply soaking the polymer nanowire arrays in KRuO4 solution. Conductive polymer nanowire arrays of polypyrrole (PPY) and poly(3,4-e…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Crystal chemical characteristics of ellestadite-type apatite: implications for toxic metal immobilization

Yu‐Hui Fang、C. Ritter、Timothy J. White2014-01-01Dalton Transactions

The ellestadite apatites Ca10[(SiO4)x(PO4)6-2x(SO4)x]Cl2 were studied by powder X-ray and neutron diffraction to establish baseline crystallographic data. These synthetic materials, unlike mineral specimens that are well equilibrated, show no Si/P/S ordering and conform to P63/m symmetry. Phosphate-rich ellestadites w…

Concrete and Cement Materials ResearchRecycling and utilization of industrial and municipal waste in materials productionNuclear materials and radiation effects

Chemical processes employing inorganic layered compounds for inorganic and inorganic–organic hybrid materials

Yoshiyuki Sugahara2014-01-01Journal of the Ceramic Society of Japan

Recent developments in the preparation of inorganic and inorganic–organic hybrid materials from inorganic layered compounds are reviewed. The focus is placed on three topics: preparation of new ion-exchangeable layered perovskites and a tungstic acid from Aurivillius phases via selective leaching of bismuth oxide shee…

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsThermal Expansion and Ionic Conductivity

Characterization of carbon-coated magnetic nanoparticles using clinical blood coagulation assays: effect of PEG-functionalization and comparison to silica nanoparticles

Lukas Bircher、Oliver M. Theusinger、Silvan Locher 等 10 位作者2014-01-01Journal of Materials Chemistry B

, independent of the surface functionalization, and only minor differences in receptor expression on platelets (GP-IIb-IIIa, CD62, and CD63) relative to control samples were observed. Interestingly, the inter-subject variance of the clotting time is similar to the nanoparticle-induced effect in a single subject with a…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsCharacterization and Applications of Magnetic Nanoparticles

Tunable supercapacitor performance of potentiodynamically deposited urea-doped cobalt hydroxide

Palanisamy Vinothbabu、Perumal Elumalai2014-01-01RSC Advances

The influence of the basal length of Co(OH) <sub>2</sub> on supercapacitor performance was examined in detail by adding simple urea molecules during deposition. It was observed that the specific capacitance of Co(OH) <sub>2</sub> could be tuned from 700 to 1200 F g <sup>−1</sup> . This high specific capacitance was at…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Impact of Vanadium Addition on API X100 Steel

Shahrooz Nafisi、Muhammad Arafin、Robert Glodowski 等 5 位作者2014-01-01ISIJ International

Laboratory heats of an API X100 steel (Mn–Mo–Nb) with two levels of vanadium (0.004% and 0.063%) were melted and control rolled simulating a coiled plate production process. Extensive microstructural analyses were performed, including optical, EBSD and TEM. Texture analyses of the two alloys were also compared. Mechan…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and Creep

Effect of Cu on the Precipitation of Deleterious Phases and the Mechanical Properties of 27Cr&ndash;7Ni Hyper Duplex Stainless Steels

Soon-Hyeok Jeon、Il-Jeong Park、Hye-Jin Kim 等 6 位作者2014-01-01MATERIALS TRANSACTIONS

Cu addition to the base alloy reduces the total amount of deleterious phases such as chromium nitride and sigma and chi phases. In particular, Cu addition to the base alloy results in pronounced suppression of the amount of sigma phase whereas it slightly facilitates the precipitation of chromium nitride and chi phase…

Metal and Thin Film MechanicsMicrostructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metals

An exemplary relationship between the extent of cofacial aggregation and fluorescence quantum yield as exhibited by quaternized amphiphilic phthalocyanines

Thiago Teixeira Tasso、Yasuhiro Yamasaki、Taniyuki Furuyama 等 4 位作者2014-01-01Dalton Transactions

The aggregation equilibrium of a series of positively-charged water-soluble phthalocyanines (Pcs) was studied in aqueous solution by means of absorption and fluorescence techniques. The aggregation equilibrium in water depends on the bridging atoms between the pyridyl groups and the Pc core, and on the central metal o…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesSurface Chemistry and Catalysis

Promoting hepatocyte spheroid formation and functions by coculture with fibroblasts on micropatterned electrospun fibrous scaffolds

Yaowen Liu、Lei Zhang、Jiaojun Wei 等 6 位作者2014-01-01Journal of Materials Chemistry B

It remains as a great challenge to maintain the viability and functions of hepatocytes in vitro, and the construction of various scaffold materials and establishment of hepatocyte coculture systems are essential for the reconstruction of engineered liver devices. In our previous study, micropatterned electrospun fibro…

Electrospun Nanofibers in Biomedical Applications3D Printing in Biomedical ResearchTissue Engineering and Regenerative Medicine

Photoresponsive superhydrophobic surfaces from one-pot solution spin coating mediated by polydopamine

Jing Zhang、Weidong Zhang、Nianchen Zhou 等 5 位作者2014-01-01RSC Advances

Smart stimuli-responsive superhydrophobic surfaces with reversibly switchable wettability have received considerable attention due to their various potential applications. We demonstrate here a new but versatile approach for preparing photoresponsive superhydrophobic surfaces. Fluorinated azobenzene derivatives or pol…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Polymer Precursor-Derived Carbon

Amit K. Naskar、Wesley P. Hoffman2014-01-01ACS symposium series

Self-assembly of amphiphiles is used as a tool for structuring carbonaceous materials in one and two dimensions. The dynamics of low-molecular weight amphiphiles are combined with the stability of their high-molecular weight analogues in order to control the self-assembly of these molecules. Two concepts for structuri…

Polymer Surface Interaction StudiesPorphyrin and Phthalocyanine ChemistrySupramolecular Self-Assembly in Materials

SPLITTING SCHEMES FOR A NAVIER-STOKES-CAHN-HILLIARD MODEL FOR TWO FLUIDS WITH DIFFERENT DENSITIES

Francisco、Guillen-Gonzalez、Giordano2014-01-01Acta Scientiarum Naturalium Universitatis Sunyatseni

在这个工作,我们在设计 effcient 上集中数字计划接近交上的一个热力学地一致的 Navier-Stokes/Cahn-Hilliard 问题[3 ] 与不同密度为二不可压缩的液体的混合建模。模型基于能以一个自然方法描述象微滴 coalescense 或微滴分散一样的拓扑的转变的一条弥漫接口的阶段地途径。我们现在的切开计划,海军司烧的去耦计算无条件地从 Cahn-Hilliard 那分开,它是精力马厩直到潜在的近似的选择。一些数字实验被执行验证正确性和计划的精确性,并且关于不同物理参数学习计划的敏感。[从作者抽象]

Solidification and crystal growth phenomena