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Site-Selective Direct Silver Metallization on Surface-Modified Polyimide Layers

Kensuke Akamatsu、Shingo Ikeda、Hidemi Nawafune2003-10-28Langmuir

Herein, we report on direct fabrication of silver circuit patterns on polyimide resin, the method of which relies on potassium hydroxide-induced chemical modification of the polyimide surface to introduce carboxylic acid groups and incorporation of silver ions through subsequent ion exchange followed by UV-irradiation…

Advanced Sensor and Energy Harvesting MaterialsNanomaterials and Printing TechnologiesSynthesis and properties of polymers

Ultrafast spectroscopy of propagating coherent acoustic phonons in GaN/InGaN heterostructures

Rongliang Liu、Chang Sub Kim、G. D. Sanders 等 9 位作者2003-10-28arXiv

We show that large amplitude, coherent acoustic phonon wavepackets can be generated and detected in In$_x$Ga$_{1-x}$N/GaN epilayers and heterostructures in femtosecond pump-probe differential reflectivity experiments. The amplitude of the coherent phonon increases with increasing Indium fraction $x$ and unlike other c…

Mesoscale and Nanoscale PhysicsMaterials Science

A Novel Family ofl-Amino Acid-Based Biodegradable Polymer−Lipid Conjugates for the Development of Long-Circulating Liposomes with Effective Drug-Targeting Capacity

Josbert M. Metselaar、Peter de Bruin、Leo W. T. de Boer 等 10 位作者2003-10-28Bioconjugate Chemistry

The objective of this study was to develop biodegradable polypeptide-lipid conjugates for the design of polymer-coated long-circulating liposomes (LCL). Lipid conjugates of poly(hydroxyalkyl L-asparagine/L-glutamine) were synthesized and incorporated into 0.15 microm dipalmitoyl phosphatidylcholine (DPPC)-cholesterol…

Nanoparticle-Based Drug DeliveryLipid Membrane Structure and BehaviorRNA Interference and Gene Delivery

Electron correlation in the two-dimensional triangle lattice of Na$_x$CoO$_2$

J. Sugiyama、J. H. Brewer、E. J. Ansaldo 等 7 位作者2003-10-28arXiv

Magnetism of layered cobaltites Na$_x$CoO$_2$ with $x$ = 0.6 and 0.9 has been investigated by a positive muon spin rotation and relaxation ($μ^+$SR) spectroscopy together with magnetic susceptibility and specific heat measurements, using single crystal samples in the temperature range between 250 and 1.8 K. Zero-field…

Materials ScienceStrongly Correlated Electrons

Percolative conductivity in alkaline earth silicate melts and glasses

M. Malki、M. Micoulaut、F. Chaimbault 等 5 位作者2003-10-28arXiv

Ion conducting $(CaO)_x(SiO_2)_{1-x}$ glasses and melts show a threshold behaviour in dc conductivity near $x=x_t=0.50$, with conductivities increasing linearly at $x>x_t$. We show that the behaviour can be traced to a rigid ($x<0.50$) to floppy ($x>0.50$) elastic phase transition near $x=x_t$. In the floppy phase, co…

Materials Science

Persistent Spin Currents in Helimagnets

Jan Heurich、Jürgen König、A. H. MacDonald2003-10-28arXiv

We demonstrate that weak external magnetic fields generate dissipationless spin currents in the ground state of systems with spiral magnetic order. Our conclusions are based on phenomenological considerations and on microscopic mean-field theory calculations for an illustrative toy model. We speculate on possible appl…

Materials Science

Structure of densified germanium dioxide

Matthieu Micoulaut2003-10-28arXiv

Classical molecular dynamics simulations are used to study the structure of densified germanium dioxide ($GeO_2$). It is found that the coordination number of germanium changes with increasing density (pressure) while pressure released systems do not exhibit a marked change in local structure as compared to the virgin…

Materials Science

Structural Characteristics and Redox Behaviors of Ce1-xCuxOy Solid Solutions

Wenjuan Shan、Wenjie Shen、Can Li2003-10-28Chemistry of Materials

Nanosized Ce 1 - x Cu x O y materials were prepared by complexation−combustion method. The structural characteristics and redox behaviors were investigated using X-ray diffraction (XRD), temperature programmed reduction (H 2 -TPR), UV−Vis, and Raman spectroscopies. In XRD patterns, no evidence of CuO diffraction peaks…

Catalytic Processes in Materials ScienceRadioactive element chemistry and processingCatalysis and Oxidation Reactions

Synthesis and Dielectric Properties of Polyimide-Tethered Polyhedral Oligomeric Silsesquioxane (POSS) Nanocomposites via POSS-diamine

Chyi‐Ming Leu、Yao-Te Chang、Kung‐Hwa Wei2003-10-28Macromolecules

Polyimide-tethered polyhedral oligomeric silsesquioxane, (R 7 R‘Si 8 O 12 ) (POSS), nanocomposites with well-defined architectures are prepared by the copolymerization reaction of a new type of diamine monomer: POSS-diamine, 4,4‘-oxydianiline (ODA), and pyromellitic dianhydride (PMDA). This type of polyimide-side-chai…

Advanced ceramic materials synthesisSynthesis and properties of polymersSilicone and Siloxane Chemistry

Performance and Emission Studies on the Effect of Injection Timing and Diesel Replacement on a 4-S LPG-Diesel Dual-Fuel Engine

C. V. Sudhir、Vijay Desai、Suresh Y. Kumar 等 4 位作者2003-10-27SAE technical papers on CD-ROM/SAE technical paper series

&lt;div class="htmlview paragraph"&gt;Reducing the emissions and fuel consumption are no longer future goals; instead they are the demands of the day. People are concerned about rising fuel costs and effects of emissions on the environment. Diesel engines are the major contributors to the increased levels of pollutant…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceVehicle emissions and performance

Immobilization of chitosan on nylon 6,6 and pet granules through hydrolysis pretreatment

X. Zhang、Renbi Bai2003-10-27Journal of Applied Polymer Science

Abstract Chitosan has been increasingly studied as an adsorbent for removing heavy metal ions and organic compounds from aqueous solutions. Most of the studies used chitosan in the form of flakes, powder, or hydrogel beads. This research investigates the immobilization of chitosan on other granular materials to overco…

Hydrogels: synthesis, properties, applicationsNanocomposite Films for Food PackagingPolymer Surface Interaction Studies

CFD Analysis and Experimental Validation of the Inlet Flow Distribution in Close Coupled Catalytic Converters

Marco Badami、Federico Millo、A. Zuarini 等 4 位作者2003-10-27SAE technical papers on CD-ROM/SAE technical paper series

&lt;div class="htmlview paragraph"&gt;The unsteady flow effects in two different close coupled catalytic converters were investigated in order to achieve a better understanding of the steady state experimental tests which are usually performed to evaluate a flow distribution.&lt;/div&gt; &lt;div class="htmlview paragr…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Preparation and properties of water‐resistant soy dreg/benzyl konjac glucomannan composite plastics

Yun Chen、Lina Zhang、Yongshang Lu 等 5 位作者2003-10-27Journal of Applied Polymer Science

Abstract ABTSRACT: Biodegradable plastics based on soy dreg (SD) were prepared with glycerol as a plasticizer via compression molding at 110–160°C. The effects of the glycerol content and molding temperature on the processability and mechanical properties were investigated. For enhanced water resistivity of the SD pla…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Novel Structural Transformation around Ln(III) and Unusual Bending of Acetylacetonato Chelate in A Series of New 3d–4f Dinuclear Complexes [(hfac)3Ln(μ-bpypz)Cr(acac)2]

R. Kawahata、Toshiaki Tsukuda、Takashi Yagi 等 7 位作者2003-10-27Chemistry Letters

Abstract A new series of discrete [(hfac)3Ln(μ-bpypz)Cr(acac)2] dinuclear complexes has demonstrated the novel LnIII ion size depedent structural transformation around LnIII as well as diastereospecifically assembled chiral configuration along with the unusual bending of the acetylacetonate chelate ring in CrIII.

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Anionic copolymerization of lauryl lactam and polycaprolactone for the production of a poly(ester amide) triblock copolymer

In Su Kim、James L. White2003-10-27Journal of Applied Polymer Science

Abstract This article examines the anionic polymerization of lauryl lactam into polyamide 12 and the copolymerization of lauryl lactam with a diisocyanate‐end‐capped polycaprolactone used to produce a poly(ester amide) block copolymer. The molecular weights of the polyester polyols used in the preparation of the diiso…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

Cationic Polymerization of 1,2-Epoxypropane by an Acid Exchanged Montmorillonite Clay in the Presence of Ethylene Glycol

Ahmed Yahiaoui、Mohammed Belbachir、Aïcha Hachemaoui2003-10-27International Journal of Molecular Sciences

The polymerization of propylene oxide (PO) catalysed by maghnite-H+ (mag-H+) in the presence of ethylene glycol was investigated. Mag-H+ is a montmorillonite silicate sheet clay was prepared through a straight forward proton exchange process. It was found that the cationic polymerization of PO was initiated by mag-H+…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

Preparation of epoxy resin/silica hybrid composites for epoxy molding compounds

Ying‐Ling Liu、Yu‐Lo Lin、Chih‐Ping Chen 等 4 位作者2003-10-27Journal of Applied Polymer Science

Abstract Phenolic novolac/silica and cresol novolac epoxy/silica hybrids were prepared through in situ sol‐gel reaction of tetraethoxysilane (TEOS). The formed hybrids were utilized as a curing agent and an epoxy resin in epoxy curing compositions, respectively. Via the two‐step preparation route, the resulting epoxy…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesSilicone and Siloxane Chemistry

Synthesis, characterization, and blood compatibility of copolymers of polyamidoamines and n‐vinylpyrrolidone

R. K. Dey、Alok R. Ray2003-10-27Journal of Applied Polymer Science

Abstract Two new polyamidoamines derived from piperazine (Pip)/cyclohexylamine (CHA) and N,N ′‐methylene bisacrylamide (MBA) were synthesized and subsequently copolymerized with N ‐vinylpyrrolidone (NVP) under suitable reaction conditions to yield the respective copolymers (Pip–MBA–NVP and CHA–MBA–NVP). The synthesize…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Relationship among phase morphology, oil resistance, and thermal aging properties in CPE/NR blends: effect of blending conditions

Chakrit Sirisinha‬、Pongdhorn Sae‐Oui、Jantagarn Guaysomboon2003-10-27Journal of Applied Polymer Science

Abstract The CPE/NR blends with blend ratio of 50/50% by weight were prepared with various blending conditions. The resistance to oil and thermal aging of the blends was investigated and correlated with phase morphology. The NR dispersed phase size in blends was found to decrease with increasing rotor speed up to 45 r…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Liquid Phase Hydrogenation of Phenol to Cyclohexenone Over A Pd–La–B Amorphous Catalyst

Li Zhuang、Hexing Li、Wei‐Lin Dai 等 4 位作者2003-10-27Chemistry Letters

Abstract A La-doped Pd–B amorphous catalyst (Pd–La–B) was prepared by chemical reduction of mixed PdCl2 and LaCl3 with KBH4. The La-dopant played a key role in stabilizing the amorphous structure since only the crystalline Pd–B was obtained without the La-dopant. During liquid phase phenol hydrogenation, the as-prepar…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis for Biomass Conversion