Materials Literature
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Myelin figures are long thin cylindrical structures that typically grow as a dense tangle when water is added to the concentrated lamellar phase of certain surfactants. We show that, starting from a well-ordered initial state, single myelin figures can be produced in isolation thus allowing a detailed study of their g…
Abstract Summary: Denim jeans have consistently been fashionable around the world. This fabric inspired strong opinions from historians, teenagers, and movie stars, and has acquired different styles throughout the years. Most jeans today are stonewashed; this technique first become popular in 1970. Now, in addition to…
<div class="htmlview paragraph">Diesel particulate filters (DPF) have been shown to effectively reduce particulate emissions from diesel engines. However, uncontrolled DPF regeneration can easily damage the DPF. In this paper, three different types of uncontrolled DPF regeneration are defined. They are: Type A:…
Structural, electrical resistivity, and magnetization properties of 200-MeV Ag+15-ion-irradiated Co-implanted ZnO thin films are presented. The structural studies show the presence of Co clusters whose size is found to increase with increase of Co implantation. The implanted films were irradiated with 200-MeV Ag+15 io…
The effects of ionizing radiation (electron beam) on poly(epsilon-caprolactone) (PCL) were studied by analyzing changes in viscosity-average and weight-average molecular weight and radius of gyration, and by performing sol-gel analysis and swelling tests. Samples were irradiated under various conditions: solid and mol…
Generation 5 ethylenediamine (EDA)-cored poly(amidoamine) (PAMAM) dendrimers (E5, E denotes the EDA core and 5 the generation number) with different degrees of acetylation and carboxylation were synthesized and used as a model system to investigate the effect of charge and the influence of dendrimer surface modificati…
Abstract Biodegradable, amphiphilic, linear (diblock and triblock) and star‐shaped (three‐armed and four‐armed) poly[(ethylene glycol)‐ block ‐(ε‐caprolactone)] copolymers (PEG–PCL copolymers) were synthesized by ring‐opening polymerization of ε‐caprolactone (CL) with stannous octoate as a catalyst, in the presence of…
By application of a density functional approach within the PBE and $\mathrm{PBE}+\mathrm{U}$ approximations we investigate the ground state terminations of the polar $\mathrm{MnO}(111)$ surface being in thermodynamic equilibrium with an oxygen reservoir. In the allowed range of the oxygen chemical potential and for re…
<div class="htmlview paragraph">A 1D+1D numerical model describing the ammonia based SCR process of NO and NO<sub>2</sub> on vanadia-titania catalysts is presented. The model is able to simulate coated and extruded monoliths. Basing on a fundamental investigation of the catalytic processes a reaction…
Abstract Summary: Plasma deposited allylamine films were studied by “in situ” ToF‐SSIMS, XPS and NEXAFS Spectroscopy before exposure to ambient air. The influence of external plasma parameters such as duty cycle, plasma power, and monomer flow rate on (i) unsaturation, (ii) branching and cross‐linking, (iii) nitrogen…
The thermal conductivity of [011¯0]-oriented ZnO nanobelts 19–41Å in size is characterized over the temperature range of 500–1500K using the Green-Kubo approach. Values obtained are one order of magnitude lower than that for bulk ZnO single crystal. Surface scattering of phonons and the high surface-to-volume ratios o…
Surface-enhanced Raman scattering (SERS) efficiency assessment of truncated tetrahedral Ag nanoparticle arrays with different vertical dimensions prepared by nanosphere lithography provides the experimental evidence of the electromagnetic (EM) coupling sensitivity to the nanoparticle heights. It is demonstrated that t…
Noncovalent interactions between purified HiPCO single-wall carbon nanotubes (SWNT) and a [60]fullerene-pyrene dyad, synthesized through a regioselective double-cyclopropanation process, produce stable suspensions in which the tubes are very well dispersed, as evidenced by microscopy characterization. Cyclic voltammet…
Contrast-enhanced magnetic resonance imaging (CE-MRI) is a dynamic technique for imaging vasculature. However, the currently used gadolinium (Gd) chelates, such as Gd-DTPA, restrict the time window for image acquisition due to their rapid elimination from blood and their rapid diffusion into the extravascular space, w…
A transient lateral photovoltaic effect (LPVE) has been observed in p-La0.7Sr0.3MnO3∕n-Si heterojunctions. Under the nonuniform irradiation of a pulsed laser, the LPVE shows high sensitivity to the spot position on the La0.7Sr0.3MnO3 surface. A mechanism based on the well established model for the LPVE in conventional…
Superelastic NiTi shape memory alloy (SMA) wires and bars are studied to determine their damping and recentering capability for applications in the structural control of buildings subjected to earthquake loadings. These studies improve the knowledge base in regard to the use of SMAs in seismic design and retrofit of s…
We report that the H2 storage method using Ni-mediated CNTs is a viable candidate for fuel cell applications. It is demonstrated that a single Ni coated on the carbon nanotubes’ (CNT) surfaces can store up to 5 H2. In this respect, at high Ni-coverage, Ni-dispersed single-walled CNTs are considered to be capable of re…
A method for synthesizing bulk nanocrystalline Cu by an electric brush-plating technique is reported. This brush-plated nanocrystalline Cu has a fine (26nm) and quite uniform grain structure and predominant high-angle grain boundaries. A pronounced strain rate sensitivity of the stress with an m of 0.104 and the Coble…
Electrospinning produces polymeric fibers with diameters in the range of 10μm–10nm by accelerating a charged polymer jet under a high electric field. We report the preparation of conducting nanocomposite fibers of poly(methyl methacrylate) (PMMA) and multiwalled carbon nanotubes (MWCNTs) by electrospinning. The fibers…
By the combination of optical tweezer manipulation and digital video microscopy, the flexural rigidity of single glycolipid "nano" tubes has been measured below the transition temperature at which the lipid tubules are transformed into vesicles. Consequently, we have found a clear reduction of the rigidity obviously b…