Materials Literature
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A series of Al, Ti, Zn and Zr compounds, i.e., their metal alkoxides, organic acid and enolate salts, halid and oxide, were evaluated as intramolecular transesterification catalysts for the thermal depolymerization reaction of poly(L-lactic acid) oligomer resulting in LL-lactide, meso-lactide and DD-lactide by gas chr…
A summary of the outstanding characteristics of the polarizable continuum model (PCM), compared with other effective Hamiltonian methods to treat chemical problems in solution, is accompanied with a more detailed exposition of the computational features recently introduced for the calculation of molecular properties i…
In the light of a recent study which identified the beneficial influence of poorly crystallised ferrihydrite Fe5HO8·4H2O on the activity of CO conversion catalysts comprising gold nanoparticles on oxidic iron, we have investigated three series of ferrihydrite-rich samples prepared by coprecipitation. The samples were…
Ag nanoparticles have been synthesised within a mesoporous template-structured silica film by a chemical route which includes ion-exchange with Ag(NH3)2+ followed by reduction.
The effects of chromium picolinate (CrPic) supplementation and resistance training (RT) on skeletal muscle size, strength, and power and whole body composition were examined in 18 men (age range 56-69 yr). The men were randomly assigned (double-blind) to groups (n = 9) that consumed either 17.8 micromol Cr/day (924 mi…
Silver metal has the highest room-temperature electrical conductivity of any substance; however, it has found limited acceptance in the electronic industry (e.g., silver filled epoxy) due to the high rate of metal corrosion and migration causing dendrites and electrical failures. With decreasing transistor feature siz…
The organic solvents employed in liposome preparation, such as chlorinated solvents, diethyl ether or methanol, although usually removed by evaporation, may remain as traces in the final formulation representing a possible risk for human health and influencing the stability of the vesicles. In order to solve the above…
We have investigated the complex ac conductivity of for , temperatures and frequencies . In addition, results from dc measurements are presented. From the frequency dependence of the complex conductivity we find hopping of Anderson-localized charge carriers as the dominant transport process in certain temperature and…
It is shown that certain regions of commercially available 500 kV non-ceramic insulators have surface electric fields that are above the threshold for water drop corona. Observations made in a full scale accelerated aging chamber, and in service, demonstrate that water drop corona occurs on such insulators. A correlat…
Readily available R8Si8O12 frameworks react selectively with aqueous Et4NOH to afford discrete incompletely-condensed silsesquioxanes: reaction of R8Si8O12 (2a, R = c-C6H11; 2b, R = Bui) with Et4NOH first produces endo-D2-R8Si8O11(OH)2 (3a, R = c-C6H11; 3b, R = Bui), which reacts further with Et4NOH to produce endo-C2…
We report measurements of the dc magnetization, the low-field ac magnetic susceptibility, and the electrical resistivity of large (up to 0.5 ${\mathrm{cm}}^{3}$) single-grain samples of icosahedral $R\ensuremath{-}\mathrm{M}\mathrm{g}\ensuremath{-}\mathrm{Z}\mathrm{n}$ $(R=\mathrm{Y},$ Tb, Dy, Ho, and Er). The dc magn…
Elastomeric networks of poly(dimethylsiloxane) (PDMS) were reinforced with silica particles introduced in two rather different ways. The first was by the simple blending of separately-prepared particles into hydroxyl-terminated PDMS chains that were subsequently end-linked, and the second was by in-situ precipitation…
The synthesis of three new derivatives of tert-butylcalix[4]arene bearing four carbamoylmethylphosphine oxide (CMPO) groups as ligating functions on the narrow rim is described. These are easily prepared in 65–80% yield via acylation of the corresponding fixed cone aminoalkoxy (C2 to C4) derivatives with p-nitrophenyl…
Magnetic properties of anisotropic M-type Sr-ferrite containing La and Co (Sr1-xLaxCoxFe12-xO19) was investigated in detail. At a composition of x = 0.3, the magnetic properties for permanent magnets were much improved, with the highest values of Br = 4.45 kG, HcJ = 4.82 kOe, and (BH)max = 4.86 MGOe. The temperature d…
The high-temperature reaction of pure metals with silicon diimide Si(NH) 2 in a specially developed radiofrequency furnace has been successfully applied to the synthesis of novel highly condensed nitridosilicates. With SrCO 3 as an additional starting material this procedure has now been extended to the synthesis of o…
The elastic moduli of yttria (Y 2 O 3 ) samples that were made from powders with various particle morphologies were studied by means of ultrasonic measurements. The soundwave velocities in the longitudinal and transverse modes were measured. The elastic moduli were calculated from the sound velocities and density. For…
The electrical and dielectric properties of co-continuous polystyrene (PS)/poly(methylmethacrylate)(PMMA) blends loaded with carbon black (CB) of a special grade (BP 1000) have been studied. They strongly depend on the selective localization of the CB particles at the blend interface quite consistently with the double…
Continuous mammalian cell lines are important hosts for the production of biological pharmaceuticals. However, these cell lines show some severe disorders in primary metabolism, which they have in common with many cancer cells. This leads to a high throughput of substrates giving a low energy yield and ample toxic sid…
Using a model potential function we have performed a molecular dynamics simulation of several static and dynamical properties of glycerol in the crystal, glass and liquid phases. Comparison with available experimental data shows an excellent agreeent and proves the validity of the potential model used. For the calcula…
The behavior of a system of macroscopic particles introduced in a nematic liquid crystal is studied theoretically. The energy of the pair interparticle interaction associated with the director elastic field deformation is found. The interaction intensity and character are studied as functions of the distance, the geom…