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Dielectric properties of ultrafine grained BaTiO/sub 3/

Aziz Shaikh、R. W. Vest、Gwenaëlle Vest1989-07-01IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control

The dielectric constant and spontaneous polarization of fine-grained BaTiO(3) prepared from powder produced by metalloorganic decomposition technology were studied. The room-temperature dielectric constant of BaTiO(3) was found to increase sharply with increase in grain size, reach a maximum at about 0.4 mum, and decr…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Mechanism for the Role of Magnesia in the Sintering of Alumina Containing Small Amounts of a liquid Phase

Charles A. Bateman、Stephen J. Bennison、Martin P. Harmer1989-07-01Journal of the American Ceramic Society

Microstructural morphology in A1 2 0 3 containing trace amounts (∼0.25 vol%) of a silicate‐based amorphous phase was studied, as a finction of MgO additions, using transmission electron microscopy. Incipient abnormal grains develop during hot‐pressing of undoped Al 2 O 3 powder and are characterized by a large aspect…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisNuclear materials and radiation effects

Synthesis of poly(α‐malic acid) and its hydrolysis behavior in vitro

Tatsuro Ouchi、Atsushi Fujino1989-07-01Die Makromolekulare Chemie

Abstract Biodegradable poly(α‐malic acid) ( 7 ) was synthesized by means of ring‐opening homopolymerization of malide dibenzyl ester ( 5 ), which is a cyclic dimer of β‐benzyl malate. In order to obtain a high‐molecular‐weight biodegradable lactic acid type polyester having pendent modifiable groups, ring‐opening copo…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthetic Organic Chemistry Methods

Growth of polypropylene particles in heterogeneous Ziegler-Natta polymerization

Masahiro Kakugo、Hajime Sadatoshi、Jiro Sakai 等 4 位作者1989-07-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGrowth of polypropylene particles in heterogeneous Ziegler-Natta polymerizationMasahiro Kakugo, Hajime Sadatoshi, Jiro Sakai, and Masakazu YokoyamaCite this: Macromolecules 1989, 22, 7, 3172–3177Publication Date (Print):July 1, 1989Publication History Published online1 May 2…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesPolymer Science and PVC

Micellar effects on the aggregation of tetraanionic porphyrins. Spectroscopic characterization of free-base meso-tetrakis(4-sulfonatophenyl)porphyrin, (TPPS)H2, and (TPPS)M (M = zinc(II), copper(II), and vanadyl) in aqueous micellar media

Karl M. Kadish、G. B. Maiya、C. Araullo 等 4 位作者1989-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMicellar effects on the aggregation of tetraanionic porphyrins. Spectroscopic characterization of free-base meso-tetrakis(4-sulfonatophenyl)porphyrin, (TPPS)H2, and (TPPS)M (M = zinc(II), copper(II), and vanadyl) in aqueous micellar mediaKarl M. Kadish, G. B. Maiya, C. Araul…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesElectrochemical Analysis and Applications

Structure of the Gene for the Arylphorin-type Storage Protein SP 2 of Bombyx mori

Tomoko Fujii、Hiroshi Sakurai、Susumu Izumi 等 4 位作者1989-07-01Journal of Biological Chemistry

Two forms of storage proteins termed "SP 1" and "SP 2", respectively, accumulate in a stage-dependent fashion in the larval hemolymph of the silkworm Bombyx mori. We have cloned and analyzed the genomic sequence encoding SP 2, an arylphorin-type storage protein. The SP 2 structural gene contains five exons spanning ov…

Insect Resistance and GeneticsInvertebrate Immune Response MechanismsSilk-based biomaterials and applications

Magnetic coupling in zero- and one-dimensional magnetic systems formed by nickel(II) and nitronyl nitroxides. Magnetic phase transition of a ferrimagnetic chain

Andréa Caneschi、Dante Gatteschi、Jean Renard 等 5 位作者1989-07-01Inorganic Chemistry

Two novel compounds formed by nickel(I1) hexafluoroacetylacetonate and nitronyl nitroxide radicals NITR = 2-R-4,4,5,5- tetramethyl-4,5-dihydro-1H-imidazole-l-oxy3l- oxide, with R = methyl, Me, and phenyl, Ph, were synthesized. The compound Ni(hfac)2(NITPh)2 crystallizes in the monoclinic system, space group P2,/c, wit…

Magnetism in coordination complexesSpectroscopy and Quantum Chemical StudiesNonlinear Dynamics and Pattern Formation

Starburst Molecules for Amorphous Molecular Materials. 4,4′,4″-Tris(N,N-diphenylamino)triphenylamine and 4,4′,4″-Tris[N-(3-methylphenyl)-N-phenylamino]triphenylamine

Yasuhiko Shirota、Tomokazu Kobata、Naoki Noma1989-07-01Chemistry Letters

Abstract A novel class of starburst molecules for making amorphous glassy organic materials, 4,4′,4″-tris(N,N-diphenylamino)triphenylamine (TDATA) and 4,4′,4″-tris[N-(3-methylphenyl)-N-phenylamino]triphenylamine (MTDATA), are synthesized and characterized. Their electrochemical and electronic properties as well as uni…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

JUSIFA—A new user-dedicated ASAXS beamline for materials science

H.‐G. Haubold、K. Gruenhagen、Michael Wagener 等 12 位作者1989-07-01Review of Scientific Instruments

The fully computer-controlled user-dedicated small-angle scattering facility JUSIFA was set up for general use at the DORIS Synchrotron Radiation Source in DESY (Hamburg). This beamline is especially designed for anomalous scattering studies of anisotropic samples in materials science and enables ASAXS studies to be u…

Advanced X-ray Imaging TechniquesElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Voltage Transformer Ferroresonance from an Energy Transfer Standpoint

R.G. Andrei、B.R. Halley1989-07-01IEEE Power Engineering Review

A novel approach to determine whether ferroresonance can occur is developed. It is based on the energy transferred from the system to the voltage transformer during the switching transient. This approach is used to develop a practical test criterion to indicate if ferroresonance can occur at a specific station. The nu…

Power Systems Fault DetectionMagnetic Properties and ApplicationsPower Transformer Diagnostics and Insulation

Mesogenic Semicarbazones and Amino Oxadiazoles-I

N. K. Chudgar、S. N. Shah、R. A. Vora1989-07-01Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics

Number of semicarbazones of 4(4′-n-alkoxybenzoyloxy) benzaldehydes are synthesized. They are cy-clized to respective amino-oxadiazoles. Both the series of compounds exhibit mesomorphism. However, the decomposition is a major problem for semicarbazones. Compounds of both the series are characterized by elemental analys…

Conducting polymers and applicationsInorganic and Organometallic ChemistrySynthesis and properties of polymers

Metal cluster topology. 10. Polyhedral gallium cluster anions in intermetallic phases of gallium and alkali metals

R. Bruce King1989-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetal cluster topology. 10. Polyhedral gallium cluster anions in intermetallic phases of gallium and alkali metalsR. B. KingCite this: Inorg. Chem. 1989, 28, 14, 2796–2799Publication Date (Print):July 1, 1989Publication History Published online1 May 2002Published inissue 1 J…

Advanced Chemical Physics StudiesNanocluster Synthesis and ApplicationsInorganic Chemistry and Materials

A Probabilistic Approach to Quantifying Uncertainties in the Progression of Severe Accidents

M. Khatib-Rahbar、E.G. Cazzoli、M. Lee 等 6 位作者1989-07-01Nuclear Science and Engineering

A probabilistic approach to quantifying uncertainties in the progression of severe reactor accidents is formulated and applied to the Source Term Code Package. It is shown that quantification of uncertainties at the basic level of input parameters reveals broad time-dependent uncertainties in the core melt progression…

Nuclear Materials and PropertiesRisk and Safety AnalysisNuclear and radioactivity studies

Note: Strain Invariants Expressed as Average Stretches

E. A. Kearsley1989-07-01Journal of Rheology

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation E. A. Kearsley; Note: Strain Invariants Expressed as Average Stretches. J. Rheol. 1 July 1989; 33…

Textile materials and evaluations

High-temperature sulfidation-regeneration of copper(II) oxide-alumina sorbents

V. Patrick、George R. Gavalas、Maria Flytzani‐Stephanopoulos 等 4 位作者1989-07-01Industrial & Engineering Chemistry Research

Thermogravimetric analysis (TGA) and flow-reactor experiments were used to study sulfidation-regeneration of highly porous CuO-Al_2O_3 sorbents. In TGA studies, sulfidation of reduced sorbents produced a high-temperature form of digenite (Cu_(9+x)S_5) as the major crystalline product. When a platinum pan was used in t…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCopper-based nanomaterials and applications

Composition and temperature dependence of the dielectric, piezoelectric and elastic properties of pure PZT ceramics

Zhenjun Zhuang、M. J. Haun、S. J. Jang 等 4 位作者1989-07-01IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control

Pure (undoped) piezoelectric lead zirconate titanate (PZT) ceramic samples at compositions across the ferroelectric region of the phase diagram were prepared from sol-gel-derived fine powders. Excess lead oxide was included in the PZT powders to obtain dense (95-96% of theoretical density) ceramics with large grain si…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesOptical and Acousto-Optic Technologies

Phosphoric acid on oxide carriers. 2. Surface acidity and reactivity toward olefins

Gianguido Ramis、Pier Francesco Rossi、Guido Busca 等 6 位作者1989-07-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhosphoric acid on oxide carriers. 2. Surface acidity and reactivity toward olefinsGianguido Ramis, Pier Francesco Rossi, Guido Busca, Vincenzo Lorenzelli, Aldo La Ginestra, and Pasquale PatronoCite this: Langmuir 1989, 5, 4, 917–923Publication Date (Print):July 1, 1989Publi…

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Ferromagnetic behavior in linear charge-transfer complexes. Structural and magnetic characterization of octamethylferrocene salts: [Fe(C5Me4H)2].bul.+ [A].bul.- (A = TCNE, TCNQ)

Joel S. Miller、Daniel T. Glatzhofer、Dermot O’Hare 等 6 位作者1989-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFerromagnetic behavior in linear charge-transfer complexes. Structural and magnetic characterization of octamethylferrocene salts: [Fe(C5Me4H)2].bul.+ [A].bul.- (A = TCNE, TCNQ)Joel S. Miller, Daniel T. Glatzhofer, Dermot M. O'Hare, William M. Reiff, Animesh Chakraborty, and…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchFerrocene Chemistry and Applications

First-order phase transition in order-disorder ferroelectrics

C. L. Wang、Zhi Qin、D. L. Lin1989-07-01Physical review. B, Condensed matter

A four-spin coupling term is introduced to the pseudospin model Hamiltonian to account for the recently observed first-order phase transition in order-disorder ferroelectrics. The critical behavior is investigated and characteristic temperatures are calculated. We have also expressed the free energy in terms of micros…

Physics of Superconductivity and MagnetismAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Effect of platinum loading on the photocatalytic activity and luminescence of cadmium sulfide powder

Toshio Uchihara、Michio Matsumura、Atsushi Yamamoto 等 4 位作者1989-07-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of platinum loading on the photocatalytic activity and luminescence of cadmium sulfide powderToshio Uchihara, Michio Matsumura, Atsushi Yamamoto, and Hiroshi TsubomuraCite this: J. Phys. Chem. 1989, 93, 15, 5870–5874Publication Date (Print):July 1, 1989Publication His…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films