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High Performance Electrode for Medium-Temperature Solid Oxide Fuel Cells: Control of Microstructure of La(Sr)CoO[sub 3] Cathodes with Highly Dispersed Pt Electrocatalysts

Hiroyuki Uchida、Shin-ichi Arisaka、Masahiro Watanabe2002-01-01Journal of The Electrochemical Society

High Performance Electrode for Medium-Temperature Solid Oxide Fuel Cells: Control of Microstructure of La ( Sr ) CoO3 Cathodes with Highly Dispersed Pt Electrocatalysts , Uchida, Hiroyuki, Arisaka, Shin-ichi, Watanabe, Masahiro

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Delayed Fracture Properties of 1500 MPa Bainite/Martensite Dual-phase High Strength Steel and Its Hydrogen Traps.

Jiangshao Gu、Kaidi Chang、H. S. Fang 等 4 位作者2002-01-01ISIJ International

It is very imperative to improve delayed fracture properties of high strength steel, which may enlarge its usage. The published literature shows that the susceptibility to hydrogen embrittlement of a novel 1 500 MPa bainite/martensite dual-phase high strength steel is inferior to that of conventional quench-tempered h…

Microstructure and Mechanical Properties of SteelsFatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metals

Cyclic molecular materials based on [M 2 O 2 S 2 ] 2+ cores (M = Mo or W)

Emmanuel Cadot、F. Sécheresse2002-01-01Chemical Communications

The purpose of this article is to illustrate how conventional precursors can serve, when used with a drop of imagination, to the synthesis of sophisticated inorganic rings and wheels. The self-condensation of the [M2O2S2]2+ fragments under acido-basic process produces, in the presence or absence of guest species, line…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Synthesis of Novolac/Layered Silicate Nanocomposites by Reaction Exfoliation Using Acid-Modified Montmorillonite

Hongsheng Wang、Tong Zhao、Linjie Zhi 等 5 位作者2002-01-01Macromolecular Rapid Communications

Novolac/layered silicate nanocomposites were synthesized by condensation polymerization of phenol and formaldehyde catalyzed by H-montmorillonite (H-MMT). Exfoliation of the clay was investigated by X-ray diffraction and transmission electron microscopy (TEM). It turned out that the intra-gallery condensation of pheno…

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisSilicone and Siloxane Chemistry

Friction Behavior of Boric Acid and Annealed Boron Carbide Coatings Studied by In Situ Raman Tribometry

S. David Dvorak、Kathryn J. Wahl、I. L. Singer2002-01-01Tribology Transactions

The sliding friction behavior of boric acid and annealed boron carbide coatings has been investigated by in situ Raman tribometry. Reciprocating sliding tests were performed in air (∼20% relative humidity) at 1 mm/s with a transparent sapphire hemisphere dead weight loaded against the coated substrates. A homebuilt mi…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchLubricants and Their Additives

Microscopic characterization of electron field emission

L. Nilsson、O. Gröening、O.M. Kuettel 等 5 位作者2002-01-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

We report on the functional capabilities of a scanning anode field emission microscope (SAFEM) which combined with a phosphor screen is used to investigate and correlate individual electron emission site characteristics of low threshold thin film electron emitters in the micrometer regime. Spatially recorded extractio…

Carbon Nanotubes in CompositesAdvanced Electron Microscopy Techniques and ApplicationsForce Microscopy Techniques and Applications

Co-doping of Diamond with Boron and Sulfur

Sally C. Eaton、Alfred B. Anderson、John C. Angus 等 5 位作者2002-01-01Electrochemical and Solid-State Letters

Sulfur incorporation in diamond was achieved by co-doping using and trimethylboron. Particle induced X-ray emission, X-ray photoelectron spectroscopy, and secondary-ion mass spectroscopy confirmed the presence of sulfur, which was more concentrated in the near-surface region. The films were examined by Mott-Schottky a…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Investigation of three-dimensional heat and mass transfer in a metal hydride reactor

Mahmut D. Mat、Y�ksel Kaplan、Kemal Aldaş2002-01-01International Journal of Energy Research

A mathematical model for three-dimensional heat and mass transfer in metal–hydrogen reactor is presented. The model considers three-dimensional complex heat, and mass transfer and chemical reaction in the reactor. The main parameter in hydriding processes is found to be the equilibrium pressure, which strongly depends…

Fusion materials and technologiesHydrogen Storage and MaterialsNuclear Materials and Properties

Electrochemical Glucose Detection Using Nickel-Implanted Boron-Doped Diamond Electrodes

Keisuke Ohnishi、Yasuaki Einaga、Hideo Notsu 等 7 位作者2002-01-01Electrochemical and Solid-State Letters

Nickel-implanted boron-doped diamond electrodes (Ni-DIA) were fabricated in view of their application for carbohydrate detection. This electrode produced well-defined and reproducible voltammograms for 1 mM glucose in alkaline media. The electrode exhibited excellent electrochemical stability with low background curre…

Electrochemical sensors and biosensorsDiamond and Carbon-based Materials ResearchAnalytical Chemistry and Sensors

Influence of Hydrogen Content on the α/β Phase Transformation Temperatures and on the Thermal-Mechanical Behavior of Zy-4, M4 (ZrSnFeV), and M5™ (ZrNbO) Alloys During the First Phase of LOCA Transient

J-C Brachet、L. Portier、T. Forgeron 等 10 位作者2002-01-01OpenAlex

To simulate the end-of-life behavior of cladding tubes during the first phase of a LOCA transient, one may assume that the main effect of a long service exposure on the cladding deformation behavior during LOCA arises from the hydrogen uptake associated with the cladding oxidation at high burn-up. Thus, the recent met…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Optimization of Gd[sub 2]O[sub 3]-Based Red Phosphors Using Combinatorial Chemistry Method

Soo Yeon Seo、Kee‐Sun Sohn、Hee Dong Park 等 4 位作者2002-01-01Journal of The Electrochemical Society

Combinatorial chemistry was applied to the optimization of phosphors for displays. The phosphor is a promising candidate for red field emission display (FED) phosphors. Screening was performed in terms of cathodoluminescence at a low voltage excitation and photoluminescence. We developed a ternary material library of…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsAmmonia Synthesis and Nitrogen Reduction

Formation of 1 ∶ 1 and 2 ∶ 2 complexes of Ce(iii) with the heteropolytungstate anion α2-[P2W17O61]10−, and their interaction with proline. The structure of [Ce2(P2W17O61)2(H2O)8]14−

Masahiro Sadakane、Angelo Ostuni、Michael T. Pope2002-01-01Journal of the Chemical Society Dalton Transactions

The “1 ∶ 1” complex of Ce3+ and α2-[P2W17O61]10− is formed in an equimolar solution of Ce(NO3)3 and K10[P2W17O61], but attempts to isolate a solid yield salts of the 1 ∶ 2 complexes first described by Peacock and Weakley in 1971. With a 3-fold excess of Ce3+ however, a crystalline ammonium salt (anion 1) could be isol…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Effect of gamma, ethylene oxide, electron beam, and plasma sterilization on the behaviour of SR-PLLA fibres in vitro

Juha‐Pekka Nuutinen、Claude Clerc、Tuija Virta 等 4 位作者2002-01-01Journal of Biomaterials Science Polymer Edition

The aim of this study was to evaluate the effect of various sterilization processes on the physical and mechanical properties of self-reinforced bioabsorbable fibres made out of polylactide (PLLA). The samples were sterilized using plasma, ethylene oxide (one and two cycles), gamma (25 kGy at room temperature, 25 kGy…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Quantum Confined Atoms of Doped ZnO Nanocrystals

R. N. Bhargava、Vishal Chhabra、T. Som 等 5 位作者2002-01-01physica status solidi (b)

The luminescent properties of ZnO nanocrystals doped with divalent manganese and europium ions show efficient broad-band emission at room temperature. These ZnO based quantum confined atoms potentially offer efficient nanophosphors that can be excited in the near UV range for applications in the solid state lighting,…

ZnO doping and propertiesPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

High-temperature transformations of organised mesoporous alumina

Jiřı́ Čejka、Patricia J. Kooyman、Lenka Veselá 等 5 位作者2002-01-01Physical Chemistry Chemical Physics

The high-temperature behaviour of organised mesoporous alumina was investigated using X-ray powder diffraction, nitrogen adsorption isotherms and transmission electron microscopy. Based on the combination of these methods it has been shown that organised mesoporous alumina synthesised using long-chain carboxylic acids…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisAerogels and thermal insulation

Influence of chemical treatments on the electrokinetic properties of cellulose fibres

Laly A. Pothan、Cornelia Bellman、Lekshmi Kailas 等 4 位作者2002-01-01Journal of Adhesion Science and Technology

Changes in the surface composition of chemically treated cellulose fibres obtained from the sheath of banana plants were investigated using electrokinetic (ζ-potential) measurements. Scanning electron microscopy (SEM) was used to observe changes in the surface morphology of the fibres. Spectroscopic methods were also…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesMaterial Properties and Processing

Influence of Insoluble Excipients on Film Coating Systems

Linda A. Felton、James W. McGinity2002-01-01Drug Development and Industrial Pharmacy

Insoluble excipients are added to polymeric film coating solutions and dispersions to improve the physical appearance of dosage forms, enhance the stability of photolytic drugs, and aid in processing. These insoluble additives, however, may significantly affect the physical, mechanical, adhesive, and drug-release prop…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Synthesis and microstructure of Pd/SiO 2 nanosized particles by reverse micelle and sol–gel processing

Dong-Sik Bae、Kyong-Sop Han、James H. Adair2002-01-01Journal of Materials Chemistry

Pd/SiO2 nanosized particles have been synthesized using a reverse micelle technique combined with metal alkoxide hydrolysis and condensation. The size of the particles and the thickness of the coating can be controlled by manipulating the relative rates of the hydrolysis and condensation reaction of tetraethyl orthosi…

Catalytic Processes in Materials ScienceSurfactants and Colloidal SystemsMesoporous Materials and Catalysis

Density profiles in a spherical infall model with non–radial motions

N. Hiotelis2002-01-01Astronomy and Astrophysics

A generalized version of the Spherical Infall Model (SIM) is used to study the effect of angular momentum on the final density profile of a spherical structure. The numerical method presented is able to handle a variety of initial density profiles (scale or not scale free) and no assumption of self-similar evolution i…

Nonlocal and gradient elasticity in micro/nano structuresHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Identification of the 2-Methylcitrate Pathway Involved in the Catabolism of Propionate in the Polyhydroxyalkanoate-Producing Strain Burkholderia sacchari IPT101 T and Analysis of a Mutant Accumulating a Copolyester with Higher 3-Hydroxyvalerate Content

Christian Brämer、Luiziana Ferreira da Silva、José Gregório Cabrera Gomez 等 5 位作者2002-01-01Applied and Environmental Microbiology

Burkholderia sacchari IPT101(T) induced the formation of 2-methylcitrate synthase and 2-methylisocitrate lyase when it was cultivated in the presence of propionic acid. The prp locus of B. sacchari IPT101(T) is required for utilization of propionic acid as a sole carbon source and is relevant for incorporation of 3-hy…

Biofuel production and bioconversionbiodegradable polymer synthesis and propertiesMicrobial Metabolic Engineering and Bioproduction