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Heat, Pressure and Light-Induced Interconversion of Bisdithiazolyl Radicals and Dimers

Kristina Lekin、Hoa Phan、Stephen M. Winter 等 13 位作者2014-05-22Journal of the American Chemical Society

The heterocyclic bisdithiazolyl radical 1b (R1 = Me, R2 = F) crystallizes in two phases. The α-phase, space group P2₁/n, contains two radicals in the asymmetric unit, both of which adopt slipped π-stack structures. The β-phase, space group P2₁/c, consists of cross-braced π-stacked arrays of dimers in which the radical…

Organometallic Complex Synthesis and CatalysisOrganic Light-Emitting Diodes ResearchMagnetism in coordination complexes

High drug load, stable, manufacturable and bioavailable fenofibrate formulations in mesoporous silica: a comparison of spray drying versus solvent impregnation methods

Shiqi Hong、Shoucang Shen、David Cheng Thiam Tan 等 11 位作者2014-05-22Drug Delivery

Encapsulation of drugs in mesoporous silica using co-spray drying process has been recently explored as potential industrial method. However, the impact of spray drying on manufacturability, physiochemical stability and bioavailability in relation to conventional drug load processes are yet to be fully investigated. U…

Nanoparticle-Based Drug DeliveryDrug Solubulity and Delivery SystemsMesoporous Materials and Catalysis

How to Prepare Biological Samples and Live Tissues for Scanning Electron Microscopy (SEM)

Kobra Tahemanesh、A. Kashi、Shahla Chaichian 等 11 位作者2014-05-22Galen Medical Journal

In this article we review the application and procedures involved in scanning electron microscope (SEM) to observe biological and live tissues through using SEM at high resolution. We discuss practical methods for optimizing tissue preservation to achieve the two principal goals of biological specimen preparation: (a)…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesAnodic Oxide Films and Nanostructures

Quantum Dot and Superparamagnetic Nanoparticle Interaction with Pathogenic Fungi: Internalization and Toxicity Profile

Nicolás Rispail、Laura De Matteis、Ana R Santos 等 17 位作者2014-05-22ACS Applied Materials & Interfaces

For several years now, nanoscaled materials have been implemented in biotechnological applications related to animal (in particular human) cells and related pathologies. However, the use of nanomaterials in plant biology is far less widespread, although their application in this field could lead to the future developm…

Nanoparticles: synthesis and applicationsQuantum Dots Synthesis And Properties

Effects of Chitosan Coatings Incorporated with Garlic Oil on Quality Characteristics of Shrimp

Emine Aşik、Kezban Candoğan2014-05-22Journal of Food Quality

Abstract The effect of chitosan‐based edible coatings ( CC ) incorporated with garlic ( A llium sativum ) oil at 0.5, 1.0 and 1.5% on shrimp ( P arapenaeus longirostris ) meat quality was investigated during refrigerated storage (4 C ) for 11 days. CC application resulted in lower pH ( P < 0.05) as compared with th…

Essential Oils and Antimicrobial ActivityMeat and Animal Product QualityNanocomposite Films for Food Packaging

Liquid Metal: An Innovative Solution to Uniform Graphene Films

Mengqi Zeng、Lifang Tan、Jiao Wang 等 6 位作者2014-05-22Chemistry of Materials

The self-limited chemical vapor deposition of uniform single-layer graphene on Cu foils generated significant interest when it was initially discovered. Soon after, the fabrication of real uniform graphene was found to need extremely precise control of the growth conditions. Slight deviations terminate the self-limiti…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchThermal properties of materials

A Compilation of Corrosion Potentials for Magnesium Alloys

Taylor Cain、Leslie G. Bland、N. Birbilis 等 4 位作者2014-05-22CORROSION

A compilation of the reported corrosion potentials for Mg alloys and selected intermetallic compounds is presented. This study presents a galvanic series for Mg alloys based on a collection of data reported elsewhere, along with some experimental results. The paper classifies the relative potential bands that are real…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Polylysine Crosslinked AIE Dye Based Fluorescent Organic Nanoparticles for Biological Imaging Applications

Meiying Liu、Xiqi Zhang、Xiqi Zhang 等 9 位作者2014-05-22Macromolecular Bioscience

Fluorescent organic nanoparticles based on aggregation induced emission dyes are fabricated through a ring-opening reaction using polylysine as the linker. The fluorescent organic nanoparticles obtained are characterized by a series of techniques including UV-vis absorption spectroscopy, fluorescence spectroscopy, Fou…

Molecular Sensors and Ion DetectionNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Analytical Formulae for Calculation of X-Ray Detector Solid Angles in the Scanning and Scanning/Transmission Analytical Electron Microscope

Nestor J. Zaluzec2014-05-22Microscopy and Microanalysis

Closed form analytical equations used to calculate the collection solid angle of six common geometries of solid-state X-ray detectors in scanning and scanning/transmission analytical electron microscopy are presented. Using these formulae one can make realistic comparisons of the merits of the different detector geome…

Particle Detector Development and PerformanceX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Influence of the Oxygen Substoichiometry and of the Hydrogen Incorporation on the Electronic Band Structure of Amorphous Tungsten Oxide Films

Maria Vasilopoulou、Ioannis Kostis、N. Vourdas 等 8 位作者2014-05-22The Journal of Physical Chemistry C

The influence of the oxygen substoichiometry and of the hydrogen incorporation on the electronic structure of amorphous tungsten oxide films was investigated. It was found that both of them cause the appearance of intermediate bands (IBs) within the energy gap; approximately 3 and 1 eV below the edge of the conduction…

Glass properties and applicationsTransition Metal Oxide NanomaterialsGa2O3 and related materials

Strengthening of Graphene Aerogels with Tunable Density and High Adsorption Capacity towards Pb2+

Zhuo Han、Zhihong Tang、Shuling Shen 等 6 位作者2014-05-22Scientific Reports

Graphene aerogels (GAs) with high mechanical strength, tunable density and volume have been prepared only via soaking graphene hydrogels (GHs) in ammonia solution. The density and volume of the obtained GAs are controlled by adjusting the concentration of ammonia solution. Although volume of the GAs decreases with inc…

Graphene research and applicationsSupercapacitor Materials and FabricationGraphene and Nanomaterials Applications

A Trinuclear Defect‐Grid Iron(II) Spin Crossover Complex with a Large Hysteresis Loop that is Readily Silenced by Solvent Vapor

Markus Steinert、Benjamin Schneider、Sebastian Dechert 等 5 位作者2014-05-22Angewandte Chemie International Edition

A new type of [2×2] matrix-like complexes with one vertex devoid of a metal ion has been selectively synthesized. The defect-grid triiron(II) complex exhibits a sharp and complete spin-crossover (SCO) from the 1HS-2LS to the 2HS-1LS state (HS: high spin; LS: low spin) with wide hysteresis near room temperature. Althou…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Gadolinium Contrast Agents for CNS Imaging: Current Concepts and Clinical Evidence

Emanuel Kanal、Kenneth R. Maravilla、Howard A. Rowley2014-05-22American Journal of Neuroradiology

SUMMARY: The aim of this article was to review the properties of the various gadolinium-based contrast agents used for CNS imaging along with the clinical evidence and published data that highlight the impact these different properties can have on diagnostic performance. In addition, approaches to optimizing image acq…

Advanced MRI Techniques and ApplicationsMedical Imaging Techniques and ApplicationsLanthanide and Transition Metal Complexes

Flexoelectric Control of Defect Formation in Ferroelectric Epitaxial Thin Films

Daesu Lee、Byung Chul Jeon、Aram Yoon 等 11 位作者2014-05-22Advanced Materials

Flexoelectric control of defect formation and associated electronic function is demonstrated in ferroelectric BiFeO3 thin films. An intriguing, so far never demonstrated, effect of internal electric field (Eint ) on defect formation is explored by a means of flexoelectricity. Our study provides novel insight into defe…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsElectronic and Structural Properties of Oxides

Direct formation of small Cu 2 O nanocubes, octahedra, and octapods for efficient synthesis of triazoles

Ya-Huei Tsai、Kaushik Chanda、Yi‐Ting Chu 等 5 位作者2014-05-22Nanoscale

In most studies describing the preparation of Cu2O crystals of various morphologies, the particle sizes are normally hundreds of nanometers to micrometers due to rapid particle growth, so they are not exactly nanocrystals. Here we report surfactant-free formation of sub-100 nm Cu2O nanocrystals with systematic shape e…

Copper-based nanomaterials and applicationsNanomaterials for catalytic reactionsQuantum-Dot Cellular Automata

A Diamagnetic Trap with 1D Camelback Potential

Oki Gunawan、Yudistira Virgus2014-05-22arXiv

The ability to trap matter is of great importance in experimental physics since it allows isolation and measurement of intrinsic properties of the trapped matter. We present a study of a three dimensional (3D) trap for a diamagnetic rod in a pair of diametric cylindrical magnets. This system yields a fascinating 1D ca…

Materials Sciencephysics.class-ph

Constraints on Jones transmission matrices from time-reversal invariance and discrete spatial symmetries

N. P. Armitage2014-05-22arXiv

Optical spectroscopies are most often used to probe dynamical correlations in materials, but they are also a probe of symmetry. Polarization anisotropies are of course sensitive to structural anisotropies, but have been much less used as a probe of more exotic symmetry breakings in ordered states. In this paper a Jone…

Materials ScienceStrongly Correlated Electronsphysics.optics

Electrostatic Assembly of Peptide Nanofiber–Biomimetic Silver Nanowires onto Graphene for Electrochemical Sensors

Jinhui Wang、Xiaojia Zhao、Jingfeng Li 等 7 位作者2014-05-22ACS Macro Letters

High Resolution Image Download MS PowerPoint Slide Biomacromolecules and their assemblies have the unique ability for biomimetic promotion of the formation of novel and functional nanomaterials. In this work, artificial peptide nanofibers were created with a special designed peptide molecule that contains complex moti…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsSupramolecular Self-Assembly in Materials

Thickness and growth-condition dependence of \emph{in-situ} mobility and carrier density of epitaxial thin-film Bi$_2$Se$_3$

Jack Hellerstedt、Mark Edmonds、J. H. Chen 等 6 位作者2014-05-22arXiv

Bismuth selenide Bi$_2$Se$_3$ was grown by molecular beam epitaxy while carrier density and mobility were measured directly \emph{in situ} as a function of film thickness. Carrier density shows high interface n-doping (1.5 x 10$^{13}$ cm$^{-2}$) at the onset of film conduction, and bulk dopant density of $\sim$5 x 10$…

Materials Science

Dirac materials

T. O. Wehling、A. M. Black-Schaffer、A. V. Balatsky2014-05-22arXiv

A wide range of materials, like d-wave superconductors, graphene, and topological insulators, share a fundamental similarity: their low-energy fermionic excitations behave as massless Dirac particles rather than fermions obeying the usual Schrodinger Hamiltonian. This emergent behavior of Dirac fermions in condensed m…

Mesoscale and Nanoscale PhysicsMaterials Science