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Electrospun rubber fibre mats with electrochemically controllable pore sizes

Thomas Kerr-Phillips、Vincent Woehling、Remi Agniel 等 8 位作者2015-01-01Journal of Materials Chemistry B

Electroactive, elastomeric, microfiber mats that show controllable pore size variation upon electrochemical stimulation are produced from semi-interpenetrating polymer networks (s-IPNs). This type of porous, elastomeric scaffolds that are mechanically dynamic under electrochemical stimuli could find new applications i…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

One-step femtosecond laser patterning of light-trapping structure on dye-sensitized solar cell photoelectrodes

Xi Zhang、Hewei Liu、Xuezhen Huang 等 4 位作者2015-01-01Journal of Materials Chemistry C

films. As a result, much more light was trapped in the photoelectrodes. Grating and orthogonal-grid patterns were studied, and the light trapping performance was optimized through the adjustment of pattern spacing, which was easily realized in the laser ablation process. With a 5-μm-spacing orthogonal-grid pattern, DS…

TiO2 Photocatalysis and Solar CellsLaser Material Processing TechniquesSilicon Nanostructures and Photoluminescence

Fabrication of a three-dimensional graphene coating for solid-phase microextraction of polycyclic aromatic hydrocarbons

Shuaihua Zhang、Zhi Li、Xiumin Yang 等 5 位作者2015-01-01RSC Advances

A novel three-dimensional graphene (3D-G) coated fiber for solid-phase microextraction (SPME) was fabricated <italic>via</italic> a sol–gel coating method on stainless steel wires.

Graphene research and applicationsAnalytical chemistry methods developmentAdditive Manufacturing and 3D Printing Technologies

Doubly crosslinked microgel-colloidosomes: a versatile method for pH-responsive capsule assembly using microgels as macro-crosslinkers

Wenkai Wang、Amir H. Milani、Louise Carney 等 7 位作者2015-01-01Chemical Communications

A new family of pH-responsive microgel-colloidosomes was prepared using microgel particles as the building blocks and macro-crosslinker. Our simple and versatile method used covalent inter-linking of vinyl-functionalised microgel particles adsorbed to oil droplets to form shells of doubly crosslinked microgels (DX MGs…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Control of micro/mesoporosity in non-hydrolytic hybrid silicophosphate xerogels

Aleš Stýskalík、David Škoda、Z. Moravec 等 6 位作者2015-01-01Journal of Materials Chemistry A

Non-hydrolytic sol–gel reactions of acetoxysilanes with trimethylsilyl esters of phosphoric and phosphonic acids provide hybrid xerogels with large surface areas (up to 700 m <sup>2</sup> g <sup>−1</sup> ). The presence of SiO <sub>6</sub> structural units in bridged-phosphoryl xerogels is related to their microporosi…

Mesoporous Materials and CatalysisAerogels and thermal insulationSilicone and Siloxane Chemistry

Investigation of thermal evolution of copper nanoclusters encapsulated in carbon nanotubes: a molecular dynamics study

Hamed Akbarzadeh、Mohsen Abbaspour、Sirous Salemi 等 4 位作者2015-01-01Physical Chemistry Chemical Physics

We have studied the heating and cooling processes of CuN nanoclusters encapsulated in CNTs with different diameters and chiralities in the range of 100-1700 K. We have investigated all of the possible effects: the effects of the nanocluster size, CNT diameter, and CNT chirality on the thermodynamic, structural, and dy…

Graphene research and applicationsFullerene Chemistry and Applicationsnanoparticles nucleation surface interactions

New highly efficient electrochemical synthesis of dispersed Ag 2 O particles in the vicinity of the cathode with controllable size and shape

Quoc‐Thai Pham、Bui The Huy、Yong‐Ill Lee2015-01-01Journal of Materials Chemistry C

Silver( <sc>i</sc> ) oxide (Ag <sub>2</sub> O) hexapod particles were electrochemically synthesized with high efficiency in an aqueous solution of silver nitrate and sodium sulfate.

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Bridging the Gap between SERS Enhancement and Reproducibility by Salt Aggregated Silver Nanoparticles

Sam Mehigan、Ciarán Smyth、Eithne M. McCabe2015-01-01Nanomaterials and Nanotechnology

Silver colloid based nanostructures are a very common means of achieving strong SERS signals. This is due to the hot spots that are formed in between the nanoparticles, as well as their ease of synthesis. They are frequently dismissed, however, as irreproducible when compared to other metal nanostructures, due to the…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesSpectroscopy Techniques in Biomedical and Chemical Research

Pressure-dependent helix inversion of poly(quinoxaline-2,3-diyl)s containing chiral side chains in non-aqueous solvents

Yuuya Nagata、Ryohei Takeda、Michinori Suginome2015-01-01Chemical Communications

Poly(quinoxaline-2,3-diyl)s with chiral (S)-2-butoxymethyl side chains dissolved in 1,2-dichloroethane experience a reversible pressure-dependent helix inversion from P- to M-helical structures between 0.1 MPa and 200 MPa.

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Efficient enhancement of magnetic anisotropy by optimizing the ligand-field in a typically tetranuclear dysprosium cluster

Jiang Liu、Yan‐Cong Chen、Zhong-Xia Jiang 等 8 位作者2015-01-01Dalton Transactions

The perturbation to the ligand field around the lanthanide ion may significantly contribute to the magnetic dynamics of single molecule magnets. This can be demonstrated by two typical Dy4 cluster-based single molecular magnets (SMMs), [Dy4X2(μ3-OH)2(μ-OH)2(2,2-bpt)4(H2O)4]X2·2H2O·4EtOH (X = Cl and Br for and , respec…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

Thermal evolution of the crystal structure of proton conducting BaCe 0.8 Y 0.2 O 3−δ from high-resolution neutron diffraction in dry and humid atmosphere

Annika K. Eriksson Andersson、Sverre M. Selbach、Tor Grande 等 4 位作者2015-01-01Dalton Transactions

The crystal structure of the proton conducting perovskite BaCe(0.8)Y(0.2)O(3-δ) (BCY20) has been studied via high-resolution in situ neutron diffraction performed in controlled dry and humid (heavy water) oxygen flow. Two phase transitions, cubic Pm3[combining macron]m→R3[combining macron]c (775 °C)→Imma (250 °C) were…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Supercritical fluid deposition of Ru nanoparticles onto SiO 2 SBA-15 as a sustainable method to prepare selective hydrogenation catalysts

Jacobo Morère、M.J. Torralvo、Concepción Pando 等 5 位作者2015-01-01RSC Advances

Ru/SiO <sub>2</sub> SBA-15 materials prepared using supercritical CO <sub>2</sub> (scCO <sub>2</sub> ) are efficient and selective catalysts in partial hydrogenation reactions.

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingMesoporous Materials and Catalysis

Functionalized iron oxide nanoparticles for controlling the movement of immune cells

Ethan E. White、Alex Pai、Yi‐Ming Weng 等 10 位作者2015-01-01Nanoscale

Immunotherapy is currently being investigated for the treatment of many diseases, including cancer. The ability to control the location of immune cells during or following activation would represent a powerful new technique for this field. Targeted magnetic delivery is emerging as a technique for controlling cell move…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryPhagocytosis and Immune Regulation

Study of the Synergistic Effect of Nanoporous Nickel Phosphates on Novel Intumescent Flame Retardant Polypropylene Composites

Shibin Nie、Chi Zhang、Chao Peng 等 6 位作者2015-01-01Journal of Spectroscopy

A char forming agent (CFA) and silica-gel microencapsulated ammonium polyphosphate (Si-MCAPP) were selected to form novel intumescent flame retardant system to prepare flame retardant polypropylene (PP) composites, and then the influences of nanoporous nickel phosphates (NiP) on the thermal and flame retardant propert…

Flame retardant materials and propertiesMagnesium Oxide Properties and ApplicationsEnvironmental and Industrial Safety

Enzymatically generated long polyT-templated copper nanoparticles for versatile biosensing assay of DNA-related enzyme activity

Feifei Peng、Zhuoliang Liu、Wang Li 等 6 位作者2015-01-01Analytical Methods

Terminal deoxynucleotidyl transferase-generated long poly(thymine) DNA can be used as an efficient template to synthesize fluorescent copper nanoparticles, providing a versatile method for detecting various enzymes with low background noise and high sensitivity.

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Composition controlled synthesis of PCL–PEG Janus nanoparticles: magnetite nanoparticles prepared from one-pot photo-click reaction

Sepideh Khoee、Yousef Bagheri、Ali Hashemi2015-01-01Nanoscale

The aim of this study is to investigate the effect of polymer nature on the morphology of synthesized nanoparticles. Super paramagnetic iron oxide nanoparticles (SPIONs) were prepared by co-precipitation method and then reacted with (3-mercaptopropyl) trimethoxysilane to obtain thiol-decorated SPIONs. Acrylated poly(c…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Polymer Synthesis and CharacterizationPickering emulsions and particle stabilization

A combined molecular dynamic and quantum mechanic study of the solvent and guest molecule effect on the stability and length of heterocyclic peptide nanotubes

Mohammad Izadyar、Mohammad Khavani、Mohammad Reza Housaindokht2015-01-01Physical Chemistry Chemical Physics

Molecular dynamic simulations were performed to investigate the stability of heterocyclic peptide nanotubes composed of 1,4-disubstituted-1,2,3-triazol ε-amino acid. 45 ns MD simulations were conducted on the cyclic peptide nanotube (CPNT) and cyclic peptide dimer in methanol, chloroform, and water and revealed that t…

DNA and Nucleic Acid ChemistryChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials