Materials Literature
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Abstract Die einfache Koordination der Lewis‐Säure B(C 6 F 5 ) 3 an klassische, nicht‐emittierende Aldehyde führt zu Festkörperphotolumineszenz. Das Variieren der elektronischen Eigenschaften der Carbonylverbindungen ermöglicht eine Wellenlängenmodulation der Festkörperemission, durch die das gesamte sichtbare Spektru…
Abstract A microcellular combustible ordnance material composed of 70 % RDX (cyclotrimethylene trinitramine) and 30 % PMMA (poly methyl methacrylate) was fabricated using the solvent method and foamed by supercritical CO 2 as foaming agent. This material has a number of advantages and many find potential application i…
We report the excitation of the non-steady-state photoelectro-motive force in a monoclinic gallium oxide crystal. The crystal grown in an oxygen atmosphere is insulating and highly transparent for a visible light, nevertheless, the formation of dynamic space-charge gratings and observation of the photo-EMF signal is a…
PDMPO (2-(4-pyridyl)-5-((4-(2-dimethylaminoethylaminocarbamoyl)methoxy)phenyl)oxazole), has unique silica specific fluorescence and is used in biology to understand biosilicification. This 'silicaphilic' fluorescence is not well understood nor is the response to local environmental variables like solvent and pH. We in…
The invention of the transistor in 1947 represented the starting point for a fast-paced development of semiconductor technology, thus setting the grounds for the electronics industry toward continuously improved functionalities. Related technological progress supported a steady trend toward more and more compact and c…
The most common method of synthesizing colloidal quantum dots (QDs) relies on an increasing particle size through increasing reaction time. We demonstrate a synthesis where the QD size is programmable through the use of a secondary phosphine sulfide precursor. The reaction runs to thermodynamic completion, resulting i…
Different thermomechanical processes have been used to modify the microstructure of elelctrolytic tough pitch copper (ETP‐Cu) in terms of texture, mean grain and grain boundary length fraction. Electron backscatter diffraction (EBSD) and linear sweep voltammetry measurements were performed to study the relation betwee…
The novel phosphate RbCuAl(PO4)2 was prepared by hydrothermal synthesis at 553 K. Its crystal structure was determined using single-crystal X-ray diffraction data and refined against F(2) to R = 0.026. The compound crystallizes in the monoclinic space group P21/c, with unit-cell parameters a = 5.0723(8) Å, b = 14.070(…
We propose a perpendicular elliptical silicon nanohole (PE-SiNH) array for light absorption in thin film silicon solar cells. Our analysis shows that this architecture is capable of increasing the absorption of a thin film silicon solar cell by 11.3% in comparison to that of the optimal circular SiNH array. The proces…
Very few research has focused on Mn 3 O 4 @carbon nanorod-structured materials for supercapacitor electrode. A facile process has been developed to prepare Mn 3 O 4 @carbon core-shell hybrid nanorods for supercapacitor electrode materials. The core Mn 3 O 4 polycrystals, which are 50 nm in diameter and 500 nm in lengt…
Nanosheet compounds Pd11 (SiiPr)2 (SiiPr2 )4 (CNtBu)10 (1) and Pd11 (SiiPr)2 (SiiPr2 )4 (CNMes)10 (2), containing two Pd7 (SiiPr)(SiiPr2 )2 (CNR)4 plates (R=tBu or Mes) connected with three common Pd atoms, were investigated with DFT method. All Pd atoms are somewhat positively charged and the electron density is accu…
Peer reviewed: Yes
Systems in which the heat flux depends on the direction of the flow are said to present thermal rectification. This effect has attracted much theoretical and experimental interest in recent years. However, in most theoretical models the effect is found to vanish in the thermodynamic limit, in disagreement with experim…
In this paper, we consider the glass transition as a kinetic process and establish one universal equation for the pressure coefficient of the glass transition temperature, dTg/dp, which is a thermodynamic characteristic of this process. Our findings challenge the common previous expectations concerning key characteris…
Pyrene-functional PMMAs were prepared via ATRP-controlled polymerization and click reaction, as efficient dispersing agents for the exfoliation of few-layered graphene sheets (GS) in easily processable low boiling point chloroform. In parallel, detailed atomistic simulations showed fine dispersion of the GS/polymer hy…
ABSTRACT Fabrication of semicrystalline syndiotactic polypropylene (sPP) nanofibers by solution electrospinning was studied. It was found that sPP nanofibers with an average diameter of 230 nm were successfully fabricated via solution electrospinning with methylcyclohexane as solvent at room temperature (25°C). The ob…
We demonstrate the synthesis of a microporous covalent-network membrane derived from co-continuous blends of a porogenic urea network and a polyimide (PI). We show that the urea networks in the PI matrix may be thermally rearranged while selectively expelling small molecular fragments, thereby forming a new network be…
We establish a reliable quantum-mechanical approach to evaluate the vibrational properties of donor-acceptor molecular crystals. The anthracene-PMDA (PMDA = pyromellitic dianhydride) crystal, where anthracene acts as the electron donor and PMDA as the electron acceptor, is taken as a representative system for which ex…
In the past, perfect metamaterial absorbers (PMAs) have required nanolithography patterning to boost broadband absoprtion. Tapered structures, in particular, are shown to achieve close-to-unity absorption over broadband using adiabatic light coupling. A nontapered PMA is desirable due to the fact that it is easier to…
In the present study, the bifiller system incorporating various amount of multiwalled carbon nanotubes (MWCNTs) and 3 wt% clay in polypropylene is investigated to obtain composites with multifunctional performance. The dispersion state of two nanofillers in the polypropylene matrix was characterized by applying TEM an…