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Gold nanoparticles supported by imidazolium-based porous organic polymers for nitroarene reduction

Yanqing Su、Xiaoju Li、Yangxin Wang 等 5 位作者2016-01-01Dalton Transactions

C NMR experiments for reaction mechanism studies. In comparison with gold NPs supported by a non-ionic analogue from the Yamamoto reaction of tetrakis(4-bromophenyl)methane (Au@POP-TPM), Au@Im-POP-2 exhibits high catalytic activity, good selectivity of aniline and superior recyclability in nitrobenzene reduction. The…

Metal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsNanomaterials for catalytic reactions

Effect of Different Nanoparticles on Seed Germination and Seedling Growth in Rice

Yi Hao、Ze-Tian Zhang、Yukui Rui 等 9 位作者2016-01-01OpenAlex

The aim of this study was to investigate the phytotoxicity of Fe 2 O 3 nanocubes, Fe 2 O 3 short nanorods, Fe 2 O 3 long nanorods, TiO 2 NPs; and MWCNTs to rice (Oryza sativa L.) seedlings during germination, including rice germination ratio, root length, shoot length and fresh weight. Our investigation found that all…

Nanoparticles: synthesis and applicationsGeochemistry and Elemental AnalysisSilicon Effects in Agriculture

Factors controlling nanosized Ni–Al 2 O 3 catalysts synthesized by solution combustion for slurry-phase CO methanation: the ratio of reducing valences to oxidizing valences in redox systems

Yuan Gao、Fanhui Meng、Xin Li 等 5 位作者2016-01-01Catalysis Science & Technology

The ratio of urea to nitrates was investigated with regard to the precursor solution, combustion process, and Ni-Al <sub>2</sub> O <sub>3</sub> catalyst structures and activity.

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Single ion magnets based on lanthanoid polyoxomolybdate complexes

José J. Baldoví、Yan Duan、Carlos Bustos 等 12 位作者2016-01-01Dalton Transactions

= Tb, Dy, Ho, Er, Yb and Nd}. In addition, these two families represent the first SIMs based on polyoxomolybdates. A magneto-structural analysis of these families is presented, which is based on an effective crystal field model, and compared with the results reported in analogous lanthanoid SIMs based on polyoxotungst…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Facile fabrication of silk protein sericin-mediated hierarchical hydroxyapatite-based bio-hybrid architectures: excellent adsorption of toxic heavy metals and hazardous dye from wastewater

Pradyot Koley、Makoto Sakurai、Toshiaki Takei 等 4 位作者2016-01-01RSC Advances

Facilely fabricated silk protein sericin-mediated hierarchical hydroxyapatite hybrid architectures show excellent adsorption of toxic heavy metal ions of Pb( <sc>ii</sc> ), Cd( <sc>ii</sc> ) and Hg( <sc>ii</sc> ) and a hazardous dye, Congo red (CR), from wastewater.

Bone Tissue Engineering MaterialsProtein Hydrolysis and Bioactive PeptidesSilk-based biomaterials and applications

Facile synthesis and characterization of a reduced graphene oxide/halloysite nanotubes/hexagonal boron nitride (RGO/HNT/h-BN) hybrid nanocomposite and its potential application in hydrogen storage

R. Naresh Muthu、S. Rajashabala、R. Kannan2016-01-01RSC Advances

The hydrogen storage performance of hybrid nanocomposites composed of reduced graphene oxide, acid treated halloysite nanotubes and hexagonal boron nitride nanoparticles (RGO/A-HNT/h-BN) was studied.

Graphene research and applicationsClay minerals and soil interactionsLayered Double Hydroxides Synthesis and Applications

PCL–PEG graft copolymers with tunable amphiphilicity as efficient drug delivery systems

Assala Al Samad、Audrey Béthry、E. Koziolová 等 9 位作者2016-01-01Journal of Materials Chemistry B

) was found. The influence of copolymer amphiphilicity on the drug loading was evaluated with various drugs including anticancer drugs (paclitaxel, ABT-199), drugs to overcome multidrug resistance in cancer cells (curcumin, elacridar), an anti-inflammatory drug (dexamethasone) and an antibacterial drug (clofazimine).…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Geometric Evolution of Flux from a Corroding One-Dimensional Pit and Its Implications on the Evaluation of Kinetic Parameters for Pit Stability

Jayendran Srinivasan、C. Liu、Robert G. Kelly2016-01-01Journal of The Electrochemical Society

The flux from a one-dimensional (1-D) artificial pit electrode corroding under a salt film was examined using experimental and modeling techniques.Finite element simulations showed that the flux at shallow depths was consistently lower than analytically determined calculations for 1-D Fickian diffusion.This deviation…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Directed self-assembly of inorganic nanoparticles at air/liquid interfaces

Juan J. Giner‐Casares、Javier Reguera2016-01-01Nanoscale

Inorganic nanoparticles (NPs) appear as the forefront functional structure in nanotechnology. The preparation of functional materials based on inorganic NPs requires their assembly onto well-defined structures. Within this context, self-assembly at air-liquid interfaces is probably the best candidate for a universal p…

Gold and Silver Nanoparticles Synthesis and ApplicationsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Colossal dielectric performance of pure barium titanate ceramics consolidated by spark plasma sintering

Xin Yang、Dapeng Li、Z. H. Ren 等 11 位作者2016-01-01RSC Advances

The pure BaTiO <sub>3</sub> nanoceramics have a high permittivity up to 6 × 10 <sup>4</sup> and a low dielectric loss. The polaron dipoles configured by oxygen vacancies and Ti <sup>3+</sup> cations within grains could contribute to the colossal dielectric permittivity of the ceramics.

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

CoOOH ultrathin nanoflake arrays aligned on nickel foam: fabrication and use in high-performance supercapacitor devices

Dongbin Zhang、Xianggui Kong、Yufei Zhao 等 5 位作者2016-01-01Journal of Materials Chemistry A

A CoOOH/NF ultrathin nanoflake array is fabricated by a facile two-step method. Furthermore, an asymmetric supercapacitor was assembled with CoOOH/NF and reduced graphene oxide, displaying excellent properties as energy storage devices.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

The peculiar behavior of the molecular dynamics of a glass-forming liquid confined in native porous materials – the role of negative pressure

Magdalena Tarnacka、Wycliffe K. Kipnusu、Ewa Kamińska 等 6 位作者2016-01-01Physical Chemistry Chemical Physics

In this paper, we combine Broadband Dielectric Spectroscopy (BDS) at ambient and high pressure, and positron annihilation lifetime spectroscopy (PALS) data of 2-ethylhexanol in the bulk state and when infiltrated in native silica nanopores to elucidate the relative role of surface effects on the Debye and structural r…

Material Dynamics and PropertiesIonic liquids properties and applicationsGlass properties and applications

Photoinduced Phase Transitions in Rod-shaped Azobenzene with Different Alkyl Chain Length

Yasuo Norikane、Emi Uchida、Satoko Tanaka 等 6 位作者2016-01-01Journal of Photopolymer Science and Technology

The direct and reversible solid-liquid phase transitions by photochromic reactions at constant temperature are of interest because of potential applications in reusable adhesives, photoresists and so on. We report photoinduced solid-liquid phase transitions in rod-shaped azobenzenes, possessing a methyl group at the 3…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistrySynthesis and properties of polymers

Lightweight Refractory Concrete Based on Aluminum-Magnesium-Phosphate Binder

В. А. Абызов2016-01-01Procedia Engineering

The paper is discussing the results of works on preparation of refractory concrete based on aluminum-magnesia-phosphate binder. The modification of magnesia phosphate binder by aluminum allows increasing the stability of the binder, as well as the material working temperature. The choice of aluminum is based on the fa…

Recycling and utilization of industrial and municipal waste in materials productionInnovations in Concrete and Construction MaterialsMagnesium Oxide Properties and Applications

Tailored mesoporous silica nanosystem with enhanced permeability of the blood–brain barrier to antagonize glioblastoma

Yuanyuan You、Li–Ye Yang、Lizhen He 等 4 位作者2016-01-01Journal of Materials Chemistry B

Cancer-targeted drug delivery systems with permeability of the blood-brain barrier (BBB) have become of great interest for the rational design of high-efficiency anticancer agents. Herein, a tailored mesoporous silica nanoparticles (MSNs) nanosystem modified by RGD (arginine-glycine-aspartate) peptide was designed and…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsSupramolecular Self-Assembly in Materials

Engineering the crystallinity of tin disulfide deposited at low temperatures

Giyul Ham、Seokyoon Shin、Joo Hyun Park 等 7 位作者2016-01-01RSC Advances

We report here that SnS <sub>2</sub> films deposited at 150 °C and annealed at below 350 °C have good potential for using 2D SnS <sub>2</sub> in flexible electronic devices.

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films