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Tensile Properties and Morphology of Oil Palm Empty Fruit Bunch Regenerated Cellulose Biocomposite Films

Nur Liyana Izyan Zailuddin、Salmah Husseinsyah2016-01-01Procedia Chemistry

The regenerated cellulose (RC)biocomposite films were prepared using casting method where oil palm empty fruit bunch (OPEFB) and microcrystalline cellulose (MCC) were dissolved in N-dimethylacetamide/lithium chloride (DMAc/LiCl)solution. The increasing of OPEFB contents up to 2 wt% increased the tensile strength and m…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

Organic charge-transfer complexes for the selective accommodation of aromatic isomers using anthracene derivatives and TCNQ

Arshad Khan、Mingliang Wang、Rabia Usman 等 8 位作者2016-01-01New Journal of Chemistry

Four organic-charge transfer (CT) complexes ( <bold>Ct1–Ct4</bold> ) have been reported. <bold>Ct1</bold> discerns <italic>p</italic> -xylene in the presence of a xylene mixture.

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsOrganic and Molecular Conductors Research

New sandwich-type lanthanide complexes based on closed-macrocyclic Schiff base and phthalocyanine molecules

Feng Gao、Xiaowan Feng、Liu Yang 等 4 位作者2016-01-01Dalton Transactions

Two new sandwich-type lanthanide complexes with the general formula [(Pc)2Ln3(L)(OAc)(OCH3)2] (Ln(3+) = Dy(3+) () and Er(3+) ()) were successfully synthesized and structurally characterized based on closed-macrocyclic Schiff base and phthalocyanine molecules. The magnetic properties and structure-property relationship…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes

Rare double spin canting antiferromagnetic behaviours in a [Co 24 ] cluster

Guang‐Ming Liang、Qing‐Ling Ni、Hua‐Hong Zou 等 5 位作者2016-01-01Chemical Communications

A fish-basket-shaped [Co24] cluster, [Co24(μ3-O)4(ampc)4(μ3-OH)4(μ2-OH)4(NO3)5(HCO2)22(H2O)10]·[(HCO2)·2(CH3OH)·x(H2O)], was woven by bridging oxygen atoms from O(2-), OH(-), NO3(-) and HCO2(-) groups, and stabilized terminally by a semi-rigid organic ligand 4',4'-[(dimethylamino)dimethylene]-bis[(1,1'-biphenyl)-2-car…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesNanocluster Synthesis and Applications

Ion-mediated charge transport in ionomeric electrolytes

Keran Lu、Janna K. Maranas、Scott T. Milner2016-01-01Soft Matter

Ionomers, or single-ion conductors, serve as a model system to study ion transport in polymeric systems. Conductivity is a system property that depends on the net charge transport in the system. The mechanism through which ions are transported can dramatically change the contribution of an ion's self-motion (i.e. diff…

Advanced Battery Materials and TechnologiesFuel Cells and Related MaterialsConducting polymers and applications

Synthesis of Graphene with Noble Metals Nanoparticles on its Surface

Yu. V. Ioni、E. Yu. Buslaeva、С. П. Губин2016-01-01Materials Today Proceedings

Graphene sheets can be considered as a promising a support material for the catalytic nanoparticles. Here, we present a new approach for the preparation of graphene with noble metals nanoparticle on its surface using supercritical propanol - 2 as a reducing agent for nanocomposites graphene oxide- Pd or Pt nanoparticl…

Advancements in Battery MaterialsGraphene research and applicationsFullerene Chemistry and Applications

Optically recoverable, deep ultraviolet (UV) stable and transparent sol–gel fluoro siloxane hybrid material for a UV LED encapsulant

Jun-Young Bae、Hwea-Yoon Kim、Young‐Woo Lim 等 5 位作者2016-01-01RSC Advances

A UV transparent and stable fluoro-siloxane hybrid material was prepared for a deep UV-LED encapsulant. The hybrimer was fabricated by hydrosilylation reaction of vinyl-fluoro oligosiloxane resin.

Aerogels and thermal insulationSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Density functional theory study of Li binding to graphene

Guangmin Yang、Xiaofeng Fan、Zhicong Liang 等 5 位作者2016-01-01RSC Advances

Using first-principle calculations, we studied the interaction between Li and graphene by considering the two kinds of models, which are related to the configurations of Li adsorption and the concentration of Li on graphene.

Advancements in Battery MaterialsGraphene research and applicationsExtraction and Separation Processes

Molecular dynamics study on the mechanical response and failure behaviour of graphene: performance enhancement via 5–7–7–5 defects

G. Rajasekaran、Avinash Parashar2016-01-01RSC Advances

A one atom-thick sheet of carbon exhibits outstanding elastic moduli and tensile strength in its pristine form but structural defects which are inevitable in graphene due to its production techniques can alter its structural properties.

Graphene research and applicationsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Nanoplasmonics tuned “click chemistry”

Inga Tijunelyte、Erwann Guénin、Nathalie Lidgi‐Guigui 等 7 位作者2016-01-01Nanoscale

Nanoplasmonics is a growing field of optical condensed matter science dedicated to optical phenomena at the nanoscale level in metal systems. Extensive research on noble metallic nanoparticles (NPs) has emerged within the last two decades due to their ability to keep the optical energy concentrated in the vicinity of…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Electron transport study on functionalized armchair graphene nanoribbons: DFT calculations

Eduardo Gracia‐Espino、Florentino Lopéz‐Urías、Humberto Terrones 等 4 位作者2016-01-01RSC Advances

Quantum transport studies are performed on doped (boron, nitrogen, oxygen, silicon, phosphorus, and sulfur) and functionalized (borane, amine, hydroxyl, thiol, silane, silene, phosphine, and phosphorane) armchair graphene nanoribbons by means of density functional theory.

Graphene research and applications2D Materials and ApplicationsMolecular Junctions and Nanostructures

Characterization of Alginate/Silver Nanobiocomposites Synthesized by Solution Plasma Process and Their Antimicrobial Properties

Sangwoo Nam、Davoodbasha MubarakAli、Jung‐Wan Kim2016-01-01Journal of Nanomaterials

Solution plasma process (SPP) was adopted to prepare alginate/silver nanoparticle (AL/AgNP) biocomposites. The biocomposites were synthesized in solutions of varying concentrations of AgNO 3 (1−5 mM) and alginate (0.1−0.3%, w/w) by discharging plasma for 7 min at 800 V with 30 kHz frequency using a pulsed unipolar pow…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsLaser-Ablation Synthesis of Nanoparticles

Memorized chiral arrangement of gemini surfactant assemblies in nanometric hybrid organic–silica helices

Naoya Ryu、Yutaka Okazaki、Kana Hirai 等 8 位作者2016-01-01Chemical Communications

Hybrid nanohelices were obtained from silicification of self-assemblies of gemini surfactants with tartrate counterions. The chiral arrangement of these non-chiral gemini surfactants was preserved in the silica matrix even after the counterion exchange for a non-chiral bromide, and was capable of inducing the chiral o…

Surfactants and Colloidal SystemsMesoporous Materials and CatalysisPorphyrin and Phthalocyanine Chemistry

Salt-induced formation of hollow and mesoporous CoO x /SiO 2 spheres and their catalytic behavior in toluene oxidation

Liang-Yi Lin、Hsunling Bai2016-01-01RSC Advances

The CoO <sub>x</sub> /SiO <sub>2</sub> spherical particles with hollow or mesoporous structure were successfully prepared by spray pyrolysis by using the NaCl and NaNO <sub>3</sub> as <italic>in situ</italic> formed templates for the first time.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Screening for high-spin metal organic frameworks (MOFs): density functional theory study on DUT-8(M 1 ,M 2 ) (with M i = V,…,Cu)

Sebastian Schwalbe、Kai Trepte、Gotthard Seifert 等 4 位作者2016-01-01Physical Chemistry Chemical Physics

We present a first principles study of low-spin (LS)/high-spin (HS) screening for 3d metal centers in the metal organic framework (MOF) DUT-8(Ni). Various density functional theory (DFT) codes have been used to evaluate numerical and DFT related errors. We compare highly accurate all-electron implementations with the…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesAdvanced NMR Techniques and Applications

Evaporable lanthanide single-ion magnet

Chen Gao、Qian Yang、Bing‐Wu Wang 等 5 位作者2016-01-01CrystEngComm

Two thermally stable single-ion magnets containing a dysprosium ion with the ligand fod (1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octadione) and bpy (2,2′-bipyridine) or phen (1,10-phenathroline) were synthesized, named 1Dy (Dyfod3bpy) and 2Dy (Dyfod3phen). They both have 6 oxygen atoms and 2 nitrogen atoms around t…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies