Materials Literature
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Template-assisted synthesis is one of the most recognised techniques for fabrication of silver nanoclusters (AgNCs). However, this process is time consuming, toxic and expensive. In this study, the authors report a completely novel approach for the green and facile synthesis of AgNCs using Matricaria chamomilla, witho…
ABSTRACT A simple design of wideband wide‐angle ultrathin low profile metamaterial microwave absorber has been presented. The unit cell of proposed design is composed of an inclined metallic hexagonal patch printed on a grounded dielectric substrate. The simulation result shows 10‐dB absorption bandwidth of 5.02 GHz f…
The detailed temperature dependence of the infrared-active mode in ${\mathrm{Fe}}_{1.03}\mathrm{Te}$ (${T}_{N}\ensuremath{\simeq}68$ K) and ${\mathrm{Fe}}_{1.13}\mathrm{Te}$ (${T}_{N}\ensuremath{\simeq}56$ K) has been examined, and the position, width, strength, and asymmetry parameter have been determined using an as…
In this work, we used Ag- and Mn-doped ZnInS/ZnS quantum dots (QDs) acting as a new generation of nontoxic dual-emission QDs with simultaneous tunable emission wavelengths and dual-emission ratiometric, which makes nontoxic dual-emission QDs with broad zone tunability in the color coordinate. The Ag-doped ZnInS ternar…
Quantum mechanics/molecular mechanics calculations are employed to assign previously recorded experimental spectroscopic signatures of the intermediates occurring during the photo-induced repair of (6-4) photolesions by photolyases to specific molecular structures. Based on this close comparison of experiment and theo…
A promising strategy for increasing the performance of supercapacitors is proposed. Until now, a popular strategy for increasing the specific capacity of the electrode consists of grafting redox molecules onto a high surface area carbon structure to add a faradaic contribution to the charge storage. Unfortunately, the…
Abstract Reducing hexaazatrinaphthylene (HAN) with potassium in the presence of 18‐c‐6 produces [{K(18‐c‐6)}HAN], which contains the S=1/2 radical [HAN] .− . The [HAN] .− radical can be transferred to the cobalt(II) amide [Co{N(SiMe 3 ) 2 } 2 ], forming [K(18‐c‐6)][(HAN){Co(N′′) 2 } 3 ]; magnetic measurements on this…
Purpose This paper aims to evaluate the corrosion behavior of Ti-6Al-4V parts produced with electron beam melting (EBM) machine and compare it with wrought Ti-6Al-4V alloy. Design/methodology/approach Potentiodynamic and potentiostatic tests were applied on EBM Ti-6Al-4V in 3.5 per cent mass NaCl solution to determine…
This article reports ways to functionalize hydroxyl-terminated polybutadiene (HTPB) by azide groups to impart energetic properties to the polymer. Two different synthetic approaches were explored to synthesize azide-functionalized hydroxyl-terminated polybutadiene (azide-HTPB). The functionalized polymer was analyzed…
Waterborne polyurethane (WPU) is a versatile and environment-friendly material with growing applications in both industry and academia. Silk fibroin (SF) is an attractive material known for its structural, biological and hemocompatible properties. The SF reinforced waterborne polyurethane (WPU) is a promising scaffold…
One important aspect of the magneto-structural transition in MnCoGe-based materials is the reduction in saturation magnetization from the orthorhombic to the hexagonal phase. Here, by combining an element specific magnetization probe such as x-ray magnetic circular dichroism and band structure calculations, we show th…
Using temperature-resolved dielectric spectroscopy in the range 25--320 K we investigate the macroscopic response, phase symmetry, and order/disorder states in bulk ferroelectric ${\text{K}}_{1\ensuremath{-}y}{\text{Li}}_{y}{\text{Ta}}_{1\ensuremath{-}x}{\text{Nb}}_{x}$ (KLTN). Four long-range symmetry phases are iden…
Copper zinc tin sulfide (CZTS) is a promising material for harvesting solar energy due to its abundance and non-toxicity. However, its poor performance hinders their wide application. In this paper gold (Au) nanoparticles are successfully incorporated into CZTS to form Au@CZTS core-shell nanostructures. The photocatho…
One of the fourteen Grand Challenges for Engineering articulated by the US National Academy of Engineering is 'Engineer Better Medicines'. Although there are many ways that better medicines could be engineered, one of the most promising ideas is to improve our ability to deliver the therapeutic molecule more precisely…
This study investigated the microstructure and thermal conductivity of as-cast and as-extruded binary Mg–Mn alloys. The large grains and fine α-Mn particles contained in the as-cast alloys were observed. After extrusion, the average grain sizes significantly decreased, typical basal fibre texture was generated and hig…
A large out-of-plane piezoelectricity can be induced in graphene by carbon substitution. Several simple substitutions are considered where C atoms are replaced by heavier group-IV elements (Si, Ge, and Sn). A more complex functionalization (namely, pyrrolic N-doped graphene) is also investigated where different functi…
As a consequence of an inter- (or intra-) molecular hydrogen bond, cellulose molecular chains or cellulose nanoparticles have a strong force for aggregation. Therefore, on one hand the broad use of cellulose nanoparticles is stifled by the lack of effective methods for the preparation of them. On the other hand, resea…
In this work we provide a thorough examination of the nonlinear dielectric properties of a succinonitrile-glutaronitrile mixture, representing one of the rare examples of a plastic crystal with fragile glassy dynamics. The detected alteration of the complex dielectric permittivity under high fields can be explained co…
We envision that CaWO4 (CWO) nanocrystals have the potential for use in biomedical imaging and therapy because of the unique ways this material interacts with high-energy radiation. These applications, however, require development of nanoparticle (NP) formulations that are suitable for in vivo applications; primarily,…
We have investigated the structure and magneto-transport properties of Co2Mn(Ge0.75Ga0.25) (CMGG) Heusler alloy thin films with near-stoichiometric and Mn-rich compositions in order to understand the effect of Co-Mn anti-sites on bulk spin polarization. Anomalous x-ray diffraction measurements using synchrotron radiat…