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Role of the Cu substrate in the growth of ultra-flat crack-free highly-crystalline single-layer graphene

Benjamin Huet、Jean‐Pierre Raskin2018-01-01Nanoscale

Producing ultra-flat crack-free single-layer high-quality graphene over large areas has remained the key challenge to fully exploit graphene's potential into next-generation technological applications. In this regard, we show that epitaxial Cu(111) film represents the most promising catalyst for the chemical vapor dep…

Graphene research and applicationsZnO doping and propertiesGraphene and Nanomaterials Applications

Spin-crossover compounds based on iron( ii ) complexes of 2,6-bis(pyrazol-1-yl)pyridine (bpp) functionalized with carboxylic acid and ethyl carboxylic acid

Víctor García‐López、Mario Palacios‐Corella、Alexandre Abhervé 等 7 位作者2018-01-01Dalton Transactions

Four new salts of the iron(ii) complex of the 2,6-bis(pyrazol-1-yl)pyridine ligand functionalized with a carboxylic acid group (bppCOOH) of formulas [Fe(bppCOOH)2](BF4)2 (1(BF4)2), [Fe(bppCOOH)2](CF3SO3)2·yMe2CO (1(CF3SO3)2·yMe2CO), [Fe(bppCOOH)2](AsF6)2·yMe2CO (1(AsF6)2·yMe2CO) and [Fe(bppCOOH)2](SbF6)2·yMe2CO (1(SbF…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Invisible-ink-assisted pattern and written surface-enhanced Raman scattering substrates for versatile chem/biosensing platforms

Chien‐Wei Lee、Han Seo Ko、Shih-Hui Gilbert Chang 等 4 位作者2018-01-01Green Chemistry

Because of the amphiphilic attraction to tannic acid and sharp nano-Au-SERS response, a single substrate enabled wide label-free sensing toward ionic compounds, hydrophobic molecules, biological responses, and chemical reactions.

Gold and Silver Nanoparticles Synthesis and ApplicationsBiosensors and Analytical DetectionAdvanced Nanomaterials in Catalysis

Non-Mie optical resonances in anisotropic biomineral nanoparticles

Roman E. Noskov、Ivan I. Shishkin、Hani Barhom 等 4 位作者2018-01-01Nanoscale

The optical properties of nanoparticles have attracted continuous attention owing to their high fundamental and applied importance across many disciplines. A recently emerged field of all-dielectric nanophotonics employs optically induced electric and magnetic Mie resonances in dielectric nanoparticles with a high ref…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsNonlinear Optical Materials Studies

Highly stretchable polymer-dispersed liquid crystal-based smart windows with transparent and stretchable hybrid electrodes

Jin-Yeong Park、Han‐Ki Kim2018-01-01RSC Advances

We report on highly stretchable polymer dispersed liquid crystal (PDLC)-based smart windows using Ag nanowires (NWs) and conductive PEDOT:PSS hybrid electrodes. By bar coating a Ag NW and PEDOT:PSS mixed ink on a transparent and stretchable polyurethane (PU) substrate, we fabricated highly transparent and stretchable…

Liquid Crystal Research AdvancementsAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics

Synthesis and characterization of novel electrochromic devices derived from redox-active polyamide–TiO 2 hybrids

Bo-Cheng Pan、Wei‐Hao Chen、Tzong‐Ming Lee 等 4 位作者2018-01-01Journal of Materials Chemistry C

Novel polyamides with hydroxyl groups and their hybrids have been successfully synthesized for the fabrication of novel electrochromic devices with enhanced electrochemical responsivity and stability.

Conducting polymers and applicationsTransition Metal Oxide NanomaterialsAnalytical Chemistry and Sensors

A facile method for green synthesis of Nd2O3 nanoparticles using aqueous extract of Terminalia catappa leaf

Miska Sanda Lembang、Yoki Yulizar、S Sudirman 等 4 位作者2018-01-01AIP conference proceedings

Metal oxide nanoparticles are usually synthesized using chemical materials that harmful for the environment. In this research, neodimium oxide nanoparticles (Nd2O3 NPs) has been green synthesized by a facile and eco-friendly method using aqueous extract of Terminalia catappa leaf (TLE) as weak base source and Nd(NO3)3…

Nanoparticles: synthesis and applicationsHeavy Metals in Plants

Efficient cosubstrate enzyme pairs for sequence-specific methyltransferase-directed photolabile caging of DNA

Michael Heimes、Leonie Kolmar、Clara Brieke2018-01-01Chemical Communications

Supplemented with synthetic surrogates of their natural cosubstrate S-adenosyl-l-methione (AdoMet), methyltransferases represent a powerful toolbox for the functionalization of biomolecules. By employing novel cosubstrate derivatives in combination with protein engineering, we show that this chemo-enzymatic method can…

RNA Interference and Gene DeliveryPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Dynamical stabilization in delafossite nitrides for solar energy conversion

Nathan J. Szymanski、Lauren N. Walters、Olle Hellman 等 5 位作者2018-01-01Journal of Materials Chemistry A

Ternary delafossite nitrides of the form ABN <sub>2</sub> (for A = Cu, Ag, Au and B = V, Nb, Ta), which become dynamically stabilized at finite temperatures, exhibit mechanical, electronic, and optical properties making them suitable for application in solar energy conversion.

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Insight Into the Compatibility Between C6F12O and Metal Materials: Experiment and Theory

Yi Li、Xiaoxing Zhang、Shuangshuang Tian 等 8 位作者2018-01-01IEEE Access

C6F12O has been introduced as a potential substitute to the most greenhouse gas SF6used in the medium-voltage (MV) electrical equipment due to its great insulation and environmental performance. While there are few studies on the compatibility between C6F12O and metal materials used in the equipment which needs to be…

High voltage insulation and dielectric phenomenaGa2O3 and related materialsInorganic Fluorides and Related Compounds

Studies on HPHT synthesis and N defects of N-rich B-doped diamonds

Xinyuan Miao、Liangchao Chen、Hongan Ma 等 8 位作者2018-01-01CrystEngComm

In this paper, high-quality N-rich single crystal diamonds with different boron additive contents were synthesized in NiMnCo alloy with high Ni content by the temperature gradient growth method under HPHT (high pressure and high temperature) conditions.

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Cooperative Assembly of Asymmetric Carbonaceous Bivalve-Like Superstructures from Multiple Building Blocks

Lei Xie、Haiyan Wang、Chun‐Hong Chen 等 7 位作者2018-01-01Research

The assembly of superstructures from building blocks is of fundamental importance for engineering materials with distinct morphologies and properties, and deepening our understanding of self-assembly processes in nature. Up to now, it is still a great challenge in materials science to construct multiple-component supe…

Supercapacitor Materials and FabricationSupramolecular Self-Assembly in MaterialsPickering emulsions and particle stabilization

Mechanism of sulfidation of small zinc oxide nanoparticles

Progna Banerjee、Prashant K. Jain2018-01-01RSC Advances

ZnO has industrial utility as a solid sorbent for the removal of polluting sulfur compounds from petroleum-based fuels. Small ZnO nanoparticles may be more effective in terms of sorption capacity and ease of sulfidation as compared to bulk ZnO. Motivated by this promise, here, we study the sulfidation of ZnO NPs and u…

Advanced Photocatalysis TechniquesZnO doping and propertiesGas Sensing Nanomaterials and Sensors

MnO2-gated Nanoplatforms with Targeted Controlled Drug Release and Contrast-Enhanced MRI Properties: from 2D Cell Culture to 3D Biomimetic Hydrogels

Yupeng Shi、Flavien Guenneau、Xiaolin Wang 等 5 位作者2018-01-01Nanotheranostics

Multifunctional nanomaterials combining diagnosis and therapeutic properties have attracted a considerable attention in cancer research. Yet some important challenges are still to be faced, including an optimal coupling between these two types of properties that would be effective within complex biological tissues. To…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsNanoplatforms for cancer theranostics

A lotus-inspired janus hybrid film enabled by interfacial self-assembly and in situ asymmetric modification

Yun Liang、Jiangwei Shi、Peng Xiao 等 9 位作者2018-01-01Chemical Communications

A lotus leaf inspired Janus hybrid film was exquisitely fabricated through a self-assembly process at the air/water interface with subsequent in situ asymmetric modification at the oil/water interface. The interfacial asymmetric decoration strategy thus provides a novel pathway for achieving a 2D Janus hybrid film wit…

Surface Modification and SuperhydrophobicityAdvanced Materials and MechanicsPickering emulsions and particle stabilization

Charged impurity-tuning of midgap states in biased Bernal bilayer black phosphorus: an anisotropic electronic phase transition

P.T.T. Le、Kavoos Mirabbaszadeh、Masoumeh Davoudiniya 等 4 位作者2018-01-01Physical Chemistry Chemical Physics

In this paper, we analytically investigate the electronic density of states (DOS) of bilayer Bernal black phosphorus (BBP) in order to study the anisotropic electronic phase transition. We employ the Green's function approach, the Born approximation, and the tight-binding Hamiltonian model including ten intra-layer an…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Superwettability with antithetic states: fluid repellency in immiscible liquids

Pingan Zhu、Tiantian Kong、Ye Tian 等 6 位作者2018-01-01Materials Horizons

Diatom-frustule-inspired surfaces are designed to stabilize the antithetic Cassie and Wenzel states for under-liquid super-repellency in virtually all two-fluid systems.

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsPickering emulsions and particle stabilization