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Synthesis of ultra-small hollow silica nanoparticles using the prepared amorphous calcium carbonate in one-pot process

Yuki Nakashima、Chika Takai、Hadi Razavi‐Khosroshahi 等 5 位作者2018-01-19Advanced Powder Technology

The ultra-small hollow silica nanoparticles were synthesized using the prepared amorphous calcium carbonate (ACC) particles as a template. The ACC particles were firstly prepared by carbonation method, which procedure was conducted in the methanol solvent to form the Ca(OCH3)2 layers on the ACC particles. An effect of…

Polymer Surface Interaction StudiesCalcium Carbonate Crystallization and InhibitionLayered Double Hydroxides Synthesis and Applications

Effects of gold core size on regulating the performance of doxorubicin-conjugated gold nanoparticles

Dongyan Wu、Huaisong Wang、Xiaoshuang Hou 等 8 位作者2018-01-19Nano Research

Studies on the influence of one critical parameter (e.g., size), targeting a specific disease, while keeping other factors unchanged, are important for improving understanding and application of the molecular design of biomedical nanomaterials. In this study, we used doxorubicin (Dox)-conjugated gold nanoparticles (GN…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and Applications

Computational Chemistry‐Guided Design of Selective Chemoresponsive Liquid Crystals Using Pyridine and Pyrimidine Functional Groups

Huaizhe Yu、Tibor Szilvási、Prabin Rai 等 6 位作者2018-01-19Advanced Functional Materials

Abstract Computational chemistry‐guided designs of chemoresponsive liquid crystals (LCs) with pyridine or pyrimidine groups that bind to metal‐cation‐functionalized surfaces to provide improved selective responses to targeted vapor species (dimethylmethylphosphonate (DMMP)) over nontargeted species (water) are reporte…

Liquid Crystal Research AdvancementsMicro and Nano RoboticsAdvanced Materials and Mechanics

Large‐Scale Fabrication of MoS2 Ribbons and Their Light‐Induced Electronic/Thermal Properties: Dichotomies in the Structural and Defect Engineering

Yuan Li、Emily C. Moy、Akshay A. Murthy 等 12 位作者2018-01-19Advanced Functional Materials

Abstract Controlled design and patterning of layered transition metal dichalcogenides (TMDs) into specific dimensions and geometries hold great potential for next‐generation micro/nanoscale electronic applications. Herein, the large‐scale fabrication of MoS 2 ribbons with widths ranging from micro‐ to nanoscale is rep…

2D Materials and ApplicationsAdvanced Sensor and Energy Harvesting MaterialsAdvanced Thermoelectric Materials and Devices

Wide applicability of high-Tc pairing originating from coexisting wide and incipient narrow bands in quasi-one-dimensional systems

Karin Matsumoto、Daisuke Ogura、Kazuhiko Kuroki2018-01-19Physical review. B./Physical review. B

We study superconductivity in the Hubbard model on various quasi-one-dimensional lattices with coexisting wide and narrow bands originating from multiple sites within a unit cell, where each site corresponds to a single orbital. The systems studied are the two-leg and three-leg ladders, the diamond chain, and the cris…

Physics of Superconductivity and MagnetismIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Polyimides as cathodic materials in lithium batteries: Effect of the chemical structure of the diamine monomer

Guiomar Hernández、Maitane Salsamendi、Sofia M. Morozova 等 8 位作者2018-01-19Journal of Polymer Science Part A Polymer Chemistry

ABSTRACT Polyimides are being investigated as alternative, environmentally friendly and safe organic electrode materials for lithium and sodium batteries. However, further improvements need the proper chemical design of these polymers. In this paper, the effect of chemical structure of polyimides on their performance…

Advanced Battery Materials and TechnologiesDielectric materials and actuatorsSynthesis and properties of polymers

Thermo-Responsive Starch-g-(PAM-co-PNIPAM): Controlled Synthesis and Effect of Molecular Components on Solution Rheology

Yifei Fan、Nadia Boulif、Francesco Picchioni2018-01-19Polymers

A series of highly branched random copolymers of acrylamide (AM) and N-isopropylacrylamide (NIPAM) have been prepared from a waxy potato starch-based macroinitiator by aqueous Cu0-mediated living radical polymerization (Cu0-mediated LRP). The NIPAM intake in the copolymer was varied between 0% and 50 mol % to evaluate…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Palladium nanoparticles immobilized on cyclodextrin‐decorated halloysite nanotubes: Efficient heterogeneous catalyst for promoting copper‐ and ligand‐free Sonogashira reaction in water–ethanol mixture

Samahe Sadjadi2018-01-19Applied Organometallic Chemistry

Combining the excellent features of halloysite nanoclay and cyclodextrin, a novel hybrid system was designed and synthesized based on covalent attachment of tosylated cyclodextrin to thiosemicarbazide‐functionalized halloysite nanoclay and used for the immobilization of Pd nanoparticles. The resulting hybrid, Pd@HNTs‐…

Crystal Structures and PropertiesClay minerals and soil interactionsLayered Double Hydroxides Synthesis and Applications

Surface Modification to Fabricate Superhydrophobic and Superoleophilic Alumina Membranes for Oil/Water Separation

Hongyan Tang、Liting Hao、Junchao Chen 等 6 位作者2018-01-19Energy & Fuels

A facile approach for fabrication of superhydrophobic and superoleophilic alumina membranes through surface modification is presented in this work. The modified alumina membranes were prepared through thermal decomposition of polytetrafluoroethylene (PTFE) materials on the surface of alumina membranes. Contact angle (…

Membrane Separation TechnologiesSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Rare earth doped M-type hexaferrites; ferromagnetic resonance and magnetization dynamics

Vipul Sharma、Shweta Kumari、Bijoy K. Kuanr2018-01-19AIP Advances

M-type hexagonal barium ferrites come in the category of magnetic material that plays a key role in electromagnetic wave propagation in various microwave devices. Due to their large magnetic anisotropy and large magnetization, their operating frequency exceeds above 50 GHz. Doping is a way to vary its magnetic propert…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

Dual Drug Delivery System Based on Biodegradable Organosilica Core–Shell Architectures

Jiang-Lan Li、Yin‐Jia Cheng、Chi Zhang 等 8 位作者2018-01-19ACS Applied Materials & Interfaces

To overcome drug resistance, efficient cancer therapeutic strategies using a combination of small-molecule drugs and macromolecule drugs is highly desired. However, because of their significant differences in molecular weight and size, it is difficult to load them simultaneously in one vector and to release them indiv…

Bone Tissue Engineering MaterialsNanoparticle-Based Drug DeliverySupramolecular Self-Assembly in Materials

Preparation of homogeneous mullite‐based fibrous ceramics by starch consolidation

Wenjie Zang、Tao Jia、Xue Dong 等 7 位作者2018-01-19Journal of the American Ceramic Society

Abstract Silica sol is one of the frequently used binders in high‐temperature resisting fibrous porous ceramics, but in the drying process, it can diffuse with water and influence the uniformity of ceramics. To solve this diffusion problem and fabricate homogeneous fibrous porous ceramics, cationic starch was firstly…

Advanced ceramic materials synthesisRecycling and utilization of industrial and municipal waste in materials productionAdvanced materials and composites

Temperature Scanning Stress Relaxation of an Autonomous Self-Healing Elastomer Containing Non-Covalent Reversible Network Junctions

Amit Das、Aladdin Sallat、Frank Böhme 等 8 位作者2018-01-19Polymers

In this work, we report about the mechanical relaxation characteristics of an intrinsically self-healable imidazole modified commercial rubber. This kind of self-healing rubber was prepared by melt mixing of 1-butyl imidazole with bromo-butyl rubber (bromine modified isoprene-isobutylene copolymer, BIIR). By this melt…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Effect of titanium dioxide nanoparticles on glucose homeostasis after oral administration

Zhangjian Chen、Yun Wang、Xiang Wang 等 9 位作者2018-01-19Journal of Applied Toxicology

Abstract As food additives, titanium dioxide nanoparticles (TiO 2 NPs) have been widely used in various products that are usually simultaneously consumed with a high content of sugar, thus necessitating research on the effect of TiO 2 NPs on glucose homeostasis. We conducted an animal study to explore the effect of or…

Nanoparticles: synthesis and applicationsHeavy Metal Exposure and ToxicityDye analysis and toxicity

Pair Distribution Function Analysis of Structural Disorder by Nb5+ Inclusion in Ceria: Evidence for Enhanced Oxygen Storage Capacity from Under-Coordinated Oxide

Craig I. Hiley、Helen Y. Playford、Janet M. Fisher 等 7 位作者2018-01-19Journal of the American Chemical Society

to balance the charge, via hydrothermal synthesis in sodium hydroxide solution. Pair distribution function analysis using reverse Monte Carlo refinement reveals that the small pentavalent substituent resides in irregular coordination positions in an average fluorite lattice, displaced away from the ideal cubic coordin…

Catalytic Processes in Materials ScienceRadioactive element chemistry and processingCatalysis and Oxidation Reactions

Interfacial Characterization by Pull-Out Test of Bamboo Fibers Embedded in Poly(Lactic Acid)

Quentin Viel、Antonella Esposito、J. M. Saiter 等 5 位作者2018-01-19Fibers

In this work, the apparent shear strength at the interface between a bamboo fiber and the surrounding poly(lactic acid) (PLA) matrix is quantified. A method for processing pull-out test samples within a controlled embedded length is proposed and the details of the test procedure are presented, along with a critical di…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesBamboo properties and applications

Non-flipping 13 C spins near an NV center in diamond: hyperfine and spatial characteristics by density functional theory simulation of the C 510 [NV]H 252 cluster

A P Nizovtsev、S Ya Kilin、A L Pushkarchuk 等 9 位作者2018-01-19New Journal of Physics

Single NV centers in diamond coupled by hyperfine interaction ( hfi ) to neighboring 13 C nuclear spins are now widely used in emerging quantum technologies as elements of quantum memory adjusted to a nitrogen-vacancy (NV) center electron spin qubit. For nuclear spins with low flip-flop rate, single shot readout was d…

Graphene research and applicationsQuantum and electron transport phenomenaDiamond and Carbon-based Materials Research

Development of Self-Healing d-Gluconic Acetal-Based Supramolecular Ionogels for Potential Use as Smart Quasisolid Electrochemical Materials

Shipeng Chen、Baohao Zhang、Nanxiang Zhang 等 9 位作者2018-01-19ACS Applied Materials & Interfaces

Formation of supramolecular ionic liquid (IL) gels (ionogels) induced by low-molecular-mass gelators (LMMGs) is an efficient strategy to confine ILs, and the negligible influence of LMMGs on the electrochemical properties of ILs makes ionogels ideal quasisolid electrochemical materials. Furthermore, the stimuli-respon…

Metal-Organic Frameworks: Synthesis and ApplicationsIonic liquids properties and applicationsSupramolecular Self-Assembly in Materials

Development of Antimicrobial Biocomposite Films to Preserve the Quality of Bread

Kelly J. Figueroa-López、Margarita María Andrade‐Mahecha、Olga Lucía Torres Vargas2018-01-19Molecules

This study focused on the development of gelatin-based films with incorporation of microcrystalline cellulose as reinforcement material. Clove (Syzygium aromaticum), nutmeg (Myristica fragrans), and black pepper (Piper nigrum) oleoresins containing antimicrobial compounds of natural origin were incorporated into the f…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesMicroencapsulation and Drying Processes

A Facile Space-Confined Solid-Phase Sulfurization Strategy for Growth of High-Quality Ultrathin Molybdenum Disulfide Single Crystals

Dawei Li、Zhiyong Xiao、Sai Mu 等 16 位作者2018-01-19Nano Letters

Single-crystal transition metal dichalcogenides (TMDs) and TMD-based heterojunctions have recently attracted significant research and industrial interest owing to their intriguing optical and electrical properties. However, the lack of a simple, low-cost, environmentally friendly, synthetic method and a poor understan…

Perovskite Materials and Applications2D Materials and ApplicationsChalcogenide Semiconductor Thin Films