Materials Literature
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Molecular dynamics simulations have been performed to study the fundamental thermodynamic and mechanical properties of single-crystalline skutterudite CoSb3 in the nanometric scale. The several interesting thermodynamic predictions, including linear thermal expansion coefficient, specific heat capacity, thermal conduc…
Monolithic oxide–metal composite thermoelectric generators (TEGs) were fabricated using multilayer co-fired ceramic technology. These devices consisted of Ni0.9Mo0.1 and La0.035Sr0.965TiO3 as p- and n-type thermoelectric materials, and Y0.03Zr0.97O2 was used as an insulator, sandwiched between p- and n-type layers. To…
SmNiO3 (SNO) thin films were deposited on LaAlO3 (LAO), SrTiO3, SrLaAlO4, Si, and Al2O3 (sapphire) substrates by RF magnetron sputtering and studies were conducted to understand how film structure and composition influence the insulator-metal transition properties. It is observed that the compressive strain induces th…
Phase switching in GeTe thin films (grown using a modified metal organic chemical vapor deposition system) upon pulsed femtosecond and nanosecond laser irradiation has been studied. Two in situ methods, i.e., optical microscopy and real-time reflectivity measurements, have been used in order to compare the optical res…
The structural, magnetic, transport, thermal, and magnetothermal properties of quaternary Heusler alloys Ni50Mn38−xFexSb12 have been studied. Powder x-ray diffraction and temperature dependence of magnetization studies reveal that with the addition of Fe in the Mn site, the martensitic transition shifts to low tempera…
We report strain-induced coercive field changes in patterned 300 × 100 × 35 nm3 Ni nanostructures deposited on Si/SiO2 substrate using the magnetoelastic effect. The coercive field values change as a function of the applied anisotropy strain (∼1000 ppm) between 390 and 500 Oe, demonstrating that it is possible to grad…
The development of electro-conductive yarns and the characterization of their conductive properties has gained importance over the past years. However, for their later application, not only the electro-conductive properties of the yarns are important, but also their mechanical characteristics. Hence, this paper presen…
BACKGROUND/PURPOSE: Cryopreservation is necessary for the long-term storage of islet cells and to increase the practicality of clinical islet transplantation. Fetal bovine serum (FBS) supplemented with 10% dimethyl sulfoxide (DMSO) is generally used as a freezing medium for islet cells. However, FBS should ideally be…
In this study, gallium nitride (GaN)-based metal-insulator-semiconductor (MIS) ultraviolet (UV) photodetectors (PDs) with a gallium oxide (GaO(x)) gate layer formed by alternating current bias-assisted photoelectrochemical oxidation of n-GaN are presented. By introducing the GaO(x) gate layer to the GaN MIS UV PDs, th…
Pulsed laser ablation (wavelength 532 nm; fluence 18 J/cm2; pulse width 7 ns; repetition rate 10 Hz) of highly oriented pyrolytic graphite was conducted in adamantane-dissolved supercritical CO2 with and without cyclohexane as a cosolvent. Micro-Raman spectroscopy of the products revealed the presence of hydrocarbons…
Ultrathin ZnSe nanorods in the cubic phase have been synthesized by the reaction of selenium and zinc oleate for 30 min at 240 °C. These nanorods showed an average diameter of 2.4 nm, which is much smaller than the Bohr size of bulk ZnSe. Thus, they exhibited a remarkable quantum size effect in terms of their optical…
Pure titania (TiO2) polycrystalline thin films in rutile, anatase and mixed phase have been grown on amorphous glass substrates by pulsed laser deposition method at various oxygen gas pressure. Wettability investigations have been carried out on these films. Consistent with our previous report [J. Phys. D: Appl. Phys.…
The impact of ternary additions of Ni (1.6–21.5 at. %) and Cu (1.3–17.3 at. %) on the A1 (face centered cubic, fcc) to L10 phase transformation in FePt films has been re-evaluated based on compositions obtained using energy dispersive x-ray spectrometry (EDS). The data presented here serve as corrections to results re…
Atomic layer deposition was employed to deposit relatively thick (∼30 nm) aluminum oxide (Al2O3) using trimethylaluminum and triply-distilled H2O precursors onto epitaxial graphene grown on the Si-face of silicon carbide. Ex situ surface conditioning by a simple wet chemistry treatment was used to render the otherwise…
We fabricate and study the ammonia sensing properties of graphitic nanoribbon films consisting of multi-layer graphene nanoribbons. These films show very good sensitivity to parts-per-million (ppm) level concentrations of ammonia, which is further enhanced by platinum functionalization, resulting in a relative resista…
Local fluctuations in the distribution of dopant atoms are thought to cause the nanoscale electronic disorder or phase separation in pnictide superconductors. Atom probe tomography has enabled the first direct observations of dopant species clustering in a K-doped 122-phase pnictide. First-principles calculations sugg…
The effect of various carbon and nitrogen sources on cellulose production byAcetobacter lovaniensis HBB5 was examined. In this study, glucose, fructose, sucrose and ethanol as carbon source and yeast extract, casein hydrolysate and ammonium sulphate as nitrogen source were used. Among the carbon sources, glucose gave…
“Immortal” ring-opening polymerization (iROP) of rac -4-methyl-1,3-dioxan-2-one (α-methyl trimethylene carbonate, α-MeTMC) has been carried out using various catalysts combined with an alcohol acting as a co-initiator and a chain transfer agent. The Lewis acid Al(OTf) 3, the metallo-organic β-diiminate [(BDI)Zn(N(SiMe…
A new group of "breathing" crystals has been synthesized. These are aromatic solvates of the copper(II) hexafluoroacetylacetonate complex with spin-labeled pyrazole Cu(hfac)(2)L·0.5Solv, where L is 2-(1-butyl-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl and Solv is benzene, toluene, eth…
Highly porous ceramics are critical components of Solid Oxide Fuel Cells. Nevertheless, their mechanical properties are poor and not fully understood. Herein, Discrete Element simulations are used to quantitatively assess the relation between the particulate microstructure of highly porous ceramics and their mechanica…