Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Helix formation is an elementary process in protein folding, influencing both the rate and mechanism of the global folding reaction. Yet, because helix formation is less cooperative than protein folding, the kinetics are often multiexponential, and the observed relaxation times are not straightforwardly related to the…
The separation of empty and water-filled laser ablation and electric arc synthesized nanotubes is reported. Centrifugation of these large-diameter nanotubes dispersed with sodium deoxycholate using specific conditions produces isolated bands of empty and water-filled nanotubes without significant diameter selection. T…
Several new electride compounds M@pyrrole (M = Li, Na, and K), Li@AR (AR = indole, thiophene, and benzene), Li@tryptophan and Li@serotonin were designed and investigated, which exhibit considerably large first hyperpolarizabilities (β(0)) (6705, 1116, 11399, 5781, 4808, 1536, 8106, and 9389 au, respectively) by compar…
Stem cell function is regulated by intrinsic as well as microenvironmental factors, including chemical and mechanical signals. Conducting polymer-based cell culture substrates provide a powerful tool to control both chemical and physical stimuli sensed by stem cells. Here we show that polypyrrole (PPy), a commonly use…
A significant progress has recently been made in the synthesis of monodisperse silica nanoparticles less than 30 nm in diameter by using basic amino acids (e.g., lysine) as a base catalyst for hydrolysis of silicon alkoxide. Alternatively, a more versatile and economical amino acid-free method has been developed to sy…
We computed the Raman spectrum of cubic and amorphous Ge${}_{2}$Sb${}_{2}$Te${}_{5}$ (GST) by ab initio phonons and an empirical bond polarizability model. Models of the amorphous phase were generated by quenching from the melt by means of ab initio molecular dynamics simulations. The calculated spectra are in good ag…
Abstract Polylactide (PLA)/poly(butylenes adipate‐ co ‐terephthalate) (PBAT) blends with various composition ratios were prepared via melt compounding using a twin‐screw extruder. The dynamic rheological behavior and morphology of the blends were studied using a parallel‐plate rheometer and a scanning electron microsc…
Novel poly(phenylacetylene)s bearing a β-cyclodextrin (CyD) residue connected to the phenyl ring through an ester (poly- 2 β ) and an ether linkage (poly- 3 β ) as well as an amide linkage (poly- 1 β ) were synthesized and their chiroptical properties were investigated with circular dichroism (CD) and absorption spect…
This study theoretically and experimentally investigates the transmission properties of a metamaterial slab comprised of two layers of metallic fish-scale structure arrays and a sandwiched dielectric layer. Calculations show that the asymmetric transmission can be tuned by varying the slab thickness, due to near-field…
Hollow La(2)O(3):Ln (Ln = Yb/Er, Yb/Ho) microspheres with up-conversion (UC) luminescence properties were successfully synthesized via a facile sacrificial template method by employing carbon spheres as hard templates followed by a subsequent heating process. The structure, morphology, formation process, and fluoresce…
Abstract Poly( L lactide) (PLA) was blended with polypropylene (PP) at various ratios (PLA:PP = 90 : 10, 80 : 20, 70 : 30, and 50 : 50) with a melt‐blending technique in an attempt to improve the melt processability of PLA. Maleic anhydride (MAH)‐grafted PP and glycidyl methacrylate were used as the reactive compatibi…
We examine the possibility of observing Bose condensation of a confined two-dimensional polariton gas in an organic quantum well. We deduce a suitable parameterization of a model Hamiltonian based upon the cavity geometry, the biexciton binding energy, and similar spectroscopic and structural data. By converting the s…
Even the most regular stick-slip frictional sliding is always stochastic, with irregularity in both the intervals between slip events and the sizes of the associated stress drops. Applying small-amplitude oscillations to the shear force, we show, experimentally and theoretically, that the stick-slip periods synchroniz…
Capillarity approximation is used to study the free-energy landscape of nucleation when an intermediate metastable phase exists. The critical nucleus that corresponds to the saddle point of the free-energy landscape as well as the whole free-energy landscape can be studied using this capillarity approximation, and var…
Thermodynamics of the short-range model of spin ice magnets in a field is considered in the Bethe - Peierls approximation. The results obtained for [111], [100] and [011] fields agrees reasonably well with the existing Monte-Carlo simulations and some experiments. In this approximation all extremely sharp field-induce…
Using a newly developed highly spin-polarized Heusler alloy, Co2Fe(Ga0.5Ge0.5) (CFGG), as ferromagnetic layers, we have fabricated a current-perpendicular-to-plane pseudospin valve with large resistance change-area product (ΔRA) of 9.5 mΩ μm2 and magnetoresistance (MR) ratio (100×ΔR/R) of 41.7% at 300 K. These values…
In order to investigate the orientational ordering of molecular dipoles and the associated electronic properties, we studied the adsorption of chlorogallium phthalocyanine molecules (GaClPc, Pc=C_32N_8H_16) on Cu(111) using the X-ray standing wave technique, photoelectron spectroscopy, and quantum chemical calculation…
Atomic force microscopy and grazing incidence x-ray diffraction measurements have revealed the presence of ripples, aligned along the [11¯0] direction on the surface of (Ga,Mn)As layers grown on GaAs(001) substrates and buffer layers, with periodicity of about 50 nm in all samples that have been studied. These samples…
We investigate the index sensing characteristics of plasmonic arrays based on square lattice slablike gold nanorings (NRs) with different ring widths. The gold NR arrays exhibit two extinction peaks in the visible and near-infrared corresponding to antibonding and bonding modes. Redshift and blueshift in antibonding a…
Graphene has attracted much attention as one of promising candidates of future high-speed transistor materials because of its high carrier mobility of more than 10,000 cm2 V-1 s-1. Up to this point, we have focused on the contact properties as performance killers, as a very small density of states in graphene might su…