Materials Literature
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By partial exchange of surface protons of a polyoxometalate (POM; H 5 PO 40 V 2 Mo 10 ) by an ionic liquid (IL; butylmethylimidazolium, bmim + ), a protonic IL-POM ([bmim] 4 HPO 40 V 2 Mo 10 ) was obtained. Further exchange of this material with Pd 2+ yields a final solid that HRTEM and EXAFS-XANES techniques show to…
We evaluated the cytotoxicity of various morphological classes of TiO(2) nanostructures (including 0-D nanoparticles, 1-D nanorods, and 3-D assemblies) toward living cells. These TiO(2) nanostructures were modified with fluorescent dye molecules, mediated via a dopamine linkage, in order to facilitate a confocal study…
This paper explores the influence of textile, physiological, and sensorial parameters on sock comfort. Comfort parameters of sport socks were evaluated in two different sport exercises by a non-trained panel. The criteria of the sensory evaluation were perceived foot temperature, fabric dampness, and pain. No rating s…
The interaction between water-soluble Keplerate polyoxometalate {Mo(72)Fe(30)} macroions and small countercations is explored by laser light scattering, anomalous small-angle X-ray scattering (ASAXS), and isothermal titration calorimetry (ITC) techniques. The macroions are found to be able to select the type of associ…
The preparation by the deposition-precipitation method (using Na(2)PdCl(4) as a palladium precursor and Na(2)CO(3) as a basic agent) of Pd catalysts supported on gamma-Al(2)O(3) and on two different types of active carbons has been followed by several techniques (UV-vis, EXAFS, XRPD, and TPR). This work consists of fo…
In this work, we report on our studies on the multiferroic properties of two rare earth chromates, GdCrO3 and YCrO3. Polycrystalline bulks and thin films have been fabricated using conventional solid state reaction and pulsed laser deposition. Magnetic measurements have revealed that both compounds show weak ferromagn…
The twisted lateral tetraalkyloxy ortho-terphenyl units in dibenzo[18]crown-6 ethers 1a-f were readily converted into the flat tetraalkyloxytriphenylene systems 2a-f by oxidative cyclization with FeCl(3) in nitromethane. Reactions of the latter with potassium salts gave complexes KX.2, which displayed mesomorphic prop…
Abstract A new type of outstandingly active gold catalysts has been developed for the aerobic oxidation of amines to imines. The gold nanoparticles are generated in situ in an organic medium prior to the oxidation reaction. Various gold salts, preferably AuCl 3 and HAuCl 4 ⋅3 H 2 O, can be applied in the presence of n…
Synthesis and characterization of bulk NaxCoO2 samples substituted by K and Rb is reported. Phase formation studies revealed a narrow stable region for Na-alkali metal-Co system. Whisker and platelike single crystalline structures have been found to form on the surface of the pellets in case of K doping. All samples w…
Fully biodegradable, green composites were fabricated with ramie fibers and modified soy flour (MSF) resin. Defatted soy flour (SF) was modified by a lab-scale filtration system to improve its mechanical, interfacial, and thermal properties through increasing the protein content. The protein content of SF was increase…
Monolithic materials have become very popular because of various applications, especially within chromatography and catalysis. Large surface areas and multimodal porosities are great advantages for these applications. New sol-gel preparation methods utilizing phase separation or nanocasting have opened the possibility…
Aluminum toxicity is one of the major soil factors limiting root growth in acidic soils. Because of the increase in organic matter content in the upper few centimeters of soils under no‐till systems (NTS), most Al in soil solution may be complexed to dissolved organic C (DOC), thus decreasing its bioavailability. The…
Here, we report the remarkable oxygen intake/release capability of a double perovskite BaYMn 2 O 5+δ . This oxide rapidly stores/releases a large amount of oxygen (>3.7 wt %) at moderate temperatures in a perfectly reversible manner. The oxygen intake/release behaviors of BaYMn 2 O 5+δ are clearly beyond those of any…
We argue that salient experimental features of the magnetic excitations in the spin-density-wave phase of iron-based superconductors can be understood within an itinerant model. We identify a minimal model and use a multiband random-phase approximation treatment of the dynamical spin susceptibility. Weakly damped spin…
Automotive exhaust emission is a major cause of air pollution. Three-way catalyst (TWC) which can eliminate CO, HC (hydrocarbons), and NO(x) simultaneously has been used to control exhaust emissions. Ceria-zirconia is a key component in TWC and most researchers pay attention to Ceria-Zirconia (Ce-rich) solid solution.…
To fully exploit the potential advantages of ideal quantum dots (QDs) (i.e. full 3D carrier confinement), elimination of the wetting layer and a uniform monomodal QD size distribution is needed. Nanopatterning with selective metalorganic chemical vapour deposition (MOCVD) QD growth has potential for achieving a higher…
The large-scale integration of devices consisting of individual single-walled carbon nanotubes (SWCNT), all of the same chirality, is a critical step toward their electronic, optoelectronic, and electromechanical application. Here, the authors realize two related goals, the first of which is the fabrication of high-de…
Semiconductor nanocrystal colloids are most striking for the ease with which their color, determined by electronic absorption frequencies, can be controlled by size. The investigations of intraband (also called inter-sub-band) transitions started in 1984 with studies of semiconductor quantum wells. Interest in the int…
We investigate the possibility of using the protease thermolysin to drive the synthesis and gelation of ionic-complementary peptides from nongelling precursors. In this system, short peptide fragments are continuously interconverted to form a dynamic peptide library, which eventually favors synthesis of peptides that…
A series of eight derivatives based on tetraphenylethylene were prepared, and two of these, i.e., 1,1-bis(4-phenylcarbonyl)-2,2-diphenylethylene (2), 1,1,2,2-tetrakis(4-phenylcarbonyl)phenylethylene (4), were characterized crystallographically. Because the rigidity and steric hindrance in the molecular structure enhan…