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Size-controlled synthesis of silver nanoparticles on Ti-containing mesoporous silica thin film and photoluminescence enhancement of rhodamine 6G dyes by surface plasmon resonance

Yu Horiuchi、Makoto Shimada、Takashi Kamegawa 等 5 位作者2009-01-01Journal of Materials Chemistry

Silver nanoparticles having a narrow size distribution were synthesized on Ti-containing mesoporous silica thin film (Ti-MSTF) using a simple photo-assisted deposition (PAD) method. Their particle sizes were successfully controlled by changing the photo-irradiation time during the deposition and average particle sizes…

Advanced Photocatalysis TechniquesGold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And Properties

Two different types of shear-deformation behaviour in Au–Cu multilayers

Y.P. Li、Xiaofei Zhu、Jun Tan 等 5 位作者2009-01-01Philosophical Magazine Letters

Localised shear deformation of a material is usually identified as a particular feature of deformation inhomogeneity. Here, we show two different types of shear deformation-behaviour that occurred in Au–Cu multilayers subjected to microindentation load, namely, a cooperative-layer-buckling-induced shear banding in a n…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesAdvanced materials and composites

Enhanced Red Phosphorescence in MgGeO[sub 3]:Mn[sup 2+] by Addition of Yb[sup 3+] Ions

Cong Yan、Bin Li、Shumei Yue 等 6 位作者2009-01-01Journal of The Electrochemical Society

Enhancement of the red emission of with addition of is reported. The initial phosphorescence in the codoped sample is an order of magnitude stronger than that of the -free sample. Thermoluminescence spectra indicate that the introduction of into the host produces traps with a suitable depth, resulting in the enhanced…

Luminescence Properties of Advanced MaterialsFerroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear Optics

Structural characterization of α-lactalbumin nanotubes

Johanna F. Graveland‐Bikker、Roman I. Koning、Henk K. Koerten 等 6 位作者2009-01-01Soft Matter

Nanotubes are formed by self-assembly of the milk protein α-lactalbumin, after partial hydrolysis by a protease from Bacillus licheniformis. These unique nanotubes are formed only in the presence of an appropriate cation at neutral pH. The α-lactalbumin nanotube is a heterogeneous self-assembled structure comprising d…

Proteins in Food SystemsInfant Nutrition and HealthSupramolecular Self-Assembly in Materials

A conducting metallopolymer featuring valence tautomerism

T.J. O'Sullivan、Brandon Djukic、Paul A. Dube 等 4 位作者2009-01-01Chemical Communications

A new cobalt bis(semiquinone) valence tautomer is reported featuring a terthienyl substituent, which undergoes electropolymerization to produce a valence tautomeric conducting metallopolymer.

Magnetism in coordination complexesConducting polymers and applicationsPolyoxometalates: Synthesis and Applications

Structural control of anodized tantalum oxide nanotubes

Jeremy Barton、Christopher L. Stender、Phoebe Li 等 4 位作者2009-01-01Journal of Materials Chemistry

Ta2O5nanotube length, diameter, and wall thickness are controlled by varying the ratio of HF to H2O in the electrolyte solution.

Semiconductor materials and devicesAnodic Oxide Films and NanostructuresGa2O3 and related materials

Stabilization of organic field-effect transistors in hexamethylenetetrathiafulvalene derivatives substituted by bulky alkyl groups

Masato Kanno、Yoshimasa Bando、Takashi Shirahata 等 6 位作者2009-01-01Journal of Materials Chemistry

Hexamethylenetetrathiafulvalene (HMTTF) derivatives substituted by tert-butyl, n-pentyl, and 1,1-dimethylpropyl groups are prepared, and the transistor properties are investigated. The compounds substituted by bulky tertiary groups exhibit high mobilities up to 0.98 cm2/Vs in the thin-film transistors and 2.3 cm2/Vs i…

Perovskite Materials and ApplicationsNonlinear Dynamics and Pattern FormationOrganic and Molecular Conductors Research

Zero thermal expansion in (1−x)PbTiO3–xBi(Mg,Ti)1/2O3 piezoceramics

Penghao Hu、Jun Chen、Xueyi Sun 等 8 位作者2009-01-01Journal of Materials Chemistry

The compounds (1−x)PbTiO3–xBi(Mg,Ti)1/2O3 (x = 0–0.7) were prepared in order to hunt for low thermal expansion piezoceramics, in particular for zero thermal expansion over a wide temperature range. The negative thermal expansion of PbTiO3 was much weakened by forming a solid solution with Bi(Mg,Ti)1/2O3. Solutions of…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisThermal Expansion and Ionic Conductivity

Encapsulation of Diclofenac Molecules into Poly(ε‐Caprolactone) Electrospun Fibers for Delivery Protection

Loredana Tammaro、Giuseppina Russo、Vittoria Vittoria2009-01-01Journal of Nanomaterials

Mg‐Al Hydrotalcite‐like clay (LDH) intercalated with diclofenac anions (HTlc‐DIC) was introduced into poly( ε ‐caprolactone) (PCL) in different concentrations by the electrospinning technique, and mats of nonwoven fibers were obtained and compared to the pristine pure electrospun PCL. The fibers, characterized by X‐ra…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

A DFT comparative study of carbon adsorption and diffusion on the surface and subsurface of Ni and Ni3Pd alloy

Fabrizio Cinquini、Françoise Delbecq、Philippe Sautet2009-01-01Physical Chemistry Chemical Physics

Carbon diffusion in transition metal nanoparticles is assumed to be a key factor in the catalyzed growth of carbon nanotubes (CNT). Aiming at designing more efficient catalysts, we have compared this carbon diffusion process in the near surface and in the bulk of Ni and Ni(3)Pd by means of density functional theory (D…

Carbon Nanotubes in CompositesGraphene research and applicationsCatalytic Processes in Materials Science

A tailored spirooxazine dimer as a photoswitchable binding tool

Satish Kumar、Davita L. Watkins、Tomoko Fujiwara2009-01-01Chemical Communications

A uniquely angled spirooxazine dimer was synthesized as a smart photoswitch for sensing and delivery applications; the dimer showed reversible binding and release ability towards a palladium catalyst.

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Kinetic Approach for Growth and Coalescence of Nano-Size Oxide Particles in 9Cr-ODS Steel Using High-Energy Synchrotron Radiation X-rays in SPring-8

Sa-Woong Kim、Takahisa Shobu、Satoshi Ohtsuka 等 6 位作者2009-01-01MATERIALS TRANSACTIONS

Nanometer size oxide particles in 9Cr-ODS steel are dispersed finely and densely in a matrix by the hot-solidification process. The size and density distribution of dispersed oxide particles is recognized as one of the main issues for ensuring good microstructural stability and high temperature strength in a high temp…

Metal and Thin Film MechanicsFusion materials and technologiesIon-surface interactions and analysis

Electronic Structure and Luminescence Properties of Yellow-Emitting Ca[sub 2]GeO[sub 4]:Ce[sup 3+],Li[sup +] Phosphor for White Light-Emitting Diodes

Ziqiang Jiang、Yuhua Wang、Zhipeng Ci 等 4 位作者2009-01-01Journal of The Electrochemical Society

The electronic structure of was calculated using the CASTEP code. shows an indirect optical bandgap with a bandgap energy of about 4.0 eV. -activated phosphors were synthesized by a solid-state reaction method, and their photoluminescence properties were characterized. The excitation band of ranges from 380 to 520 nm…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsPerovskite Materials and Applications

Comparison of abrasion resistance of selected constructional materials

Marcin Adamiak、Jacek Górka、Tomasz Kik2009-01-01Journal of Achievements of Materials and Manufacturing Engineering

Purpose: The aim of this work was to define and compare abrasion resistance of selected constructional materials widely used in the industry. Chromium cast iron wear resistant plates were compared with typically used wear resistant plates made from Hardox 400 steel and two different, wear resistant, materials cladded…

Advanced materials and compositesTribology and Wear AnalysisMetal Alloys Wear and Properties

Effects of Eu[sup 2+] Co-Doping on VUV Photoluminescence Properties of BaMgAl[sub 10]O[sub 17]:Mn[sup 2+] Phosphors for Plasma Display Panels

Taeho Moon、Gun Young Hong、Hong-Cheol Lee 等 8 位作者2009-01-01Electrochemical and Solid-State Letters

Effects of Eu2 + Co-Doping on VUV Photoluminescence Properties of BaMgAl10O17 : Mn2 + Phosphors for Plasma Display Panels, Moon, Taeho, Hong, Gun Young, Lee, Hong-Cheol, Moon, Eun-A, Jeoung, Byung Woo, Hwang, Sun-Tae, Kim, Je Seok, Ryu, Byung-Gil

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsLuminescence and Fluorescent Materials

Parallel ultrafast E–C ring closure and E–Z isomerisation in a photochromic furylfulgide studied by femtosecond time-resolved spectroscopy

Ron Siewertsen、Falk Renth、F. Temps 等 4 位作者2009-01-01Physical Chemistry Chemical Physics

The photo-induced parallel E-->C ring closure and E-->Z isomerisation reactions of the (E) isomer of the photochromic furylfulgide 2-[1-(2,5-dimethyl-3-furyl)-ethylidene]-3-isopropylidene succinic anhydride () in n-hexane have been studied using femtosecond time-resolved spectroscopy. Broadband transient absorption da…

Radical Photochemical ReactionsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Preparation of gold nanoparticles supported on glassy carbon by direct spray pyrolysis

María A. Montero、María R. Gennero de Chialvo、Abel C. Chialvo2009-01-01Journal of Materials Chemistry

A method for the preparation of gold nanoparticles supported on glassy carbon by direct spray pyrolysis in air at low temperature is presented. The procedure is based on the property of some gold salts which, unlike many other metal salts, decompose by heating at low temperature to produce metallic gold and gaseous sp…

Gold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and ApplicationsElectrohydrodynamics and Fluid Dynamics

A proposed protocol for nomenclaturally effective DNA barcoding of microalgae

Katharine Evans、David G. Mann2009-01-01Phycologia

K.M. Evans and D.G. Mann. 2009. A proposed protocol for nomenclaturally effective DNA barcoding of microalgae. Phycologia 48: 70–74. DOI: 10.2216/08-70.1.A mechanism for giving DNA barcodes nomenclatural status in microalgae via culture-derived epitypes is demonstrated with reference to four species of the freshwater…

Diatoms and Algae ResearchAquatic Invertebrate Ecology and BehaviorIdentification and Quantification in Food

Characterization of the Corrosion Products of Crevice Corroded Alloy 22

Xi Shan、Joe H. Payer2009-01-01Journal of The Electrochemical Society

The crevice corrosion performance of Alloy 22 was tested under potentiostatic polarization more positive than the repassivation potential in 4 M NaCl solution at . Under this aggressive condition, crevice corrosion initiated under the crevice contacts and four stages of corrosion behavior were observed: initiation, pr…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsHydrogen embrittlement and corrosion behaviors in metals