Materials Literature
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Computer modeling and simulation reveals a bridging domain mechanism that explains the phase coexistence commonly observed around the morphotropic phase boundaries of ferroelectric solid solutions. The simulation takes into account the important role of coupled ferroelectric and ferroelastic domain microstructures in…
Abstract A method for the manipulation of crystal shape by using cycles of growth and dissolution is presented, representing a unique process‐based solution to an important product quality concern. Using 3‐D shape evolution models for faceted crystal growth and dissolution, results are reported for cycling both an ill…
Molecular dynamics simulations of tensile testing have been performed on nc-SiC. Reduction of grain size promotes simultaneous enhancement of ductility, toughness, and strength. nc-SiC fails by intergranular fracture preceded by atomic level necking. Conventionally, high strain-rate deformations of ceramics are limite…
Here we report a normal-mode-based protocol for modeling anisotropic thermal motions of proteins in x-ray crystallographic refinement. The foundation for this protocol is a recently developed elastic normal mode analysis that produces much more accurate eigenvectors without the tip effect. The effectiveness of the pro…
Parallel spin alignment under moderate magnetic fields has been reported in numerous magnetically dilute oxides at temperatures above 300K. It is proposed that magnetoelastic effects from 3dn series ions with Jahn-Teller orbital occupancy cause lattice-assisted paramagnetism. Theoretical models are offered for the mag…
UNLABELLED: Monosodium titanate (MST) particles effectively bind specific metals and are therefore promising compounds for delivery or sequestration of metals in biological contexts. Yet, the biological properties of MST are largely unexplored. Our previous study showed that the cytotoxicity of these compounds was mil…
Under stress: A high level of crystallinity in polymers does not impair ductility and elastic performance if a stress-induced martensitic crystal–crystal phase transition takes place (see picture; c: unit cell axis, h: helical form, t: trans-planar form). This type of elasticity is not merely entropic but also partly…
Nanocrystalline Tm3+-doped LaGaO3 phosphors were prepared through a Pechini-type sol-gel process [M. P. Pechini, U.S. Patent No. 3,330,697 (11 July 1967)]. X-ray diffraction, field emission scanning electron microscopy, photoluminescence, and cathodoluminescence (CL) spectra were utilized to characterize the synthesiz…
Lead-free (Bi0.5Na0.5)0.93Ba0.07TiO3–xwt%In2O3 ceramics synthesized by direct reaction sintering have been studied. X-ray diffraction reveals that all (Bi0.5Na0.5)0.93Ba0.07TiO3–xwt%In2O3 ceramics are of a perovskite structure with coexistence of rhombohedral and tetragonal phases. It is found that the direct reaction…
Micro-Raman measurements were performed to study the nitrogen-related modes in ZnO samples implanted with N+. The two stable N isotopes, N14 and N15, were implanted. Distinct peaks at 277 and 512cm−1 are observed irrespective of the implanted isotope, both before and after rapid thermal annealing. The insensitivity of…
Abstract Superparamagnetic hybrid nanoparticles (ca. 80 nm) are obtained. They consist of an inner iron oxide core coated by a silica shell, which is in turn functionalized with amine or carboxyl groups and covalently coupled to a monoclonal antibody (anti‐hCG; hCG = human chorionic gonadotropin). The prepared nanopar…
Low-dimensional phase-change nanostructures provide a valuable research platform for understanding the phase-transition behavior and thermal properties at nanoscale and their potential in achieving superdense data storage. Ge2Sb2Te5 nanowires have been grown using a vapor-liquid-solid technique and shown to exhibit di…
We report exceptional ductile behavior in individual double-walled and triple-walled carbon nanotubes at temperatures above 2000 degrees C, with tensile elongation of 190% and diameter reduction of 90%, during in situ tensile-loading experiments conducted inside a high-resolution transmission electron microscope. Conc…
A systemic study was performed on bismuth strontium titanate (Sr1−1.5xBixTiO3, 0.04⩽x⩽0.25) ceramics. Dielectric properties were measured from 83to373K at different frequencies. A transformation from relaxor ferroelectrics to relaxor behavior was observed when x>0.10. Both diffuseness and relaxation degree incr…
The authors demonstrate the use of electrostatic force microscopy (EFM) as a noninvasive tool for mapping individual single wall carbon nanotubes (SWCNTs) in spin cast polymer/SWCNT composites. The authors obtain the distribution of lengths and orientations of nanotubes in a poly-(methylmethacrylate)/SWCNT composite.…
Abstract This work seeks to optimize the twin‐screw compounding of polymer‐clay nanocomposites (PCNs). Proportional amounts (3:1) of maleic anhydride functionalized polypropylene compatibilizer (PP‐ g ‐MA) and organically modified montmorillonite clay at clay loadings of 1, 3, and 5 wt% were melt‐blended with a polypr…
Materials showing reversible resistance switching between high-resistance state and low-resistance state at room temperature are attractive for today’s semiconductor technology. In this letter, the improvement of reproducible hysteresis and resistive switching characteristics of metal-La0.7Ca0.3MnO3-metal (M-LCMO-M) h…
A Si metal-oxide-semiconductor electroluminescent device structure is reported which emits two colors, while being doped with a single rare-earth element. Thermally grown SiO2 oxide layers were implanted with Eu and subseqently annealed. Depending on the electrical excitation current, the luminescence is red or blue,…
Magnetoelectrically chiral media are studied in this paper as potential materials to realize double negative materials and negative refractive characteristics. The behaviors of the negative refractive index, the backward eigenwaves, and the impedance of these eigenmodes of this particular type of chiral media are exam…
Abstract High Density Polyethylene (HDPE) was melt extruded with different amounts of expanded graphite (EG) based masterbatches. Conductive composites were obtained by diluting PE and PS masterbatches with 60 wt% content of expanded graphite. These masterbatches were readily dispersed into the molten HDPE matrix yiel…