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Synthesis and Photoluminescence Properties of Truncated Octahedral Eu-Doped YF3 Submicrocrystals or Nanocrystals

Feng Tao、Zhijun Wang、Lianzeng Yao 等 5 位作者2007-02-06The Journal of Physical Chemistry C

Highly uniform and monodisperse Eu:YF 3 nanosized and submicrosized truncated octahedra are successfully prepared in large quantities using a facile hydrothermal approach assisted by a capping reagent, ethylenediaminetetraacetic acid disodium salt (Na 2 H 2 EDTA). X-ray diffraction, field emission scanning microscopy,…

Microwave Dielectric Ceramics SynthesisLuminescence Properties of Advanced MaterialsInorganic Fluorides and Related Compounds

Brownian Molecular Dynamics Simulation on Self-Assembly Behavior of Rod−Coil Diblock Copolymers

Shaoliang Lin、Naoko Numasawa、Takuhei Nose 等 4 位作者2007-02-06Macromolecules

Brownian molecular dynamics simulations are carried out on the self-assembly behavior of rod−coil diblock copolymers. The copolymer molecule is represented by a linear chain consisting of definite beads connecting by harmonic bond stretching potential. The rigidity of the rod block is introduced by harmonic potential…

Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-AssemblySurfactants and Colloidal Systems

Enhancement of Superconductivity and Evidence of Structural Instability in Intercalated GraphiteCaC6under High Pressure

Andrea Gauzzi、Shinya Takashima、Nao Takeshita 等 9 位作者2007-02-06Physical Review Letters

We measured the temperature dependent resistivity, $\ensuremath{\varrho}(T)$, of the intercalated graphite superconductor ${\mathrm{CaC}}_{6}$ as a function of pressure up to 16 GPa. We found a large linear increase of critical temperature, ${T}_{c}$, from the ambient pressure value 11.5 K up to 15.1 K, the largest va…

Boron and Carbon Nanomaterials ResearchHigh-pressure geophysics and materialsSuperconductivity in MgB2 and Alloys

Highly Luminescent Cd1−xZnxSe/ZnS Core/Shell Nanocrystals Emitting in the Blue–Green Spectral Range

Myriam Protière、Peter Reiß2007-02-06Small

Getting the green light: ZnS-coated Cd1−xZnxSe alloy nanocrystals are stable and efficient emitters, whose color can easily be tuned in the blue–green spectral range by changing the ratio of the metal precursors applied during synthesis. Incorporated into a polymer matrix, they can be used for the conversion of blue (…

Quantum Dots Synthesis And PropertiesNanocluster Synthesis and ApplicationsChalcogenide Semiconductor Thin Films

Kinetics and Mechanistic Model for Hydrogen Spillover on Bridged Metal−Organic Frameworks

Yingwei Li、Frances H. Yang、Ralph T. Yang2007-02-06The Journal of Physical Chemistry C

The kinetics of hydrogen adsorption on IRMOF-8 by hydrogen spillover from a Pt/AC catalyst (activated carbon support) was studied at various pressures (0−100 atm) and temperatures (273−348 K). The sorbent studied was a mixture of IRMOF-8 and Pt/AC with added carbon bridges. The overall isosteric heats of adsorption (−…

Hydrogen Storage and MaterialsMetal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials Science

Microstructure‐properties correlations in dynamically vulcanized nanocomposite thermoplastic elastomers based on PP/EPDM

Ghasem Naderi、Pierre G. Lafleur、Charles Dubois2007-02-06Polymer Engineering and Science

Abstract Thermoplastic vulcanized (TPV) nanocomposites were prepared in a laboratory mixer using EPDM, polypropylene of different viscosities, maleic anhydride modified polypropylene, an organo‐clay, and a sulfur‐based curing system. Based on the obtained results from X‐ray diffraction, transmission electron microscop…

Dielectric materials and actuatorsPolymer Nanocomposites and PropertiesPolymer crystallization and properties

Highly Sensitive Optical Detection of Humidity on Polymer/Metal Nanoparticle Hybrid Films

Norman A. Luechinger、Stefan Loher、Evagelos K. Athanassiou 等 5 位作者2007-02-06Langmuir

Porous metal films for optical humidity sensing were prepared from copper nanoparticles protected by a 2-3 nm carbon coating, a silicon tenside, and a polymeric wetting agent. Exposure to water or solvent vapor revealed an exceptional sensitivity with optical shifts in the visible light range of up to 50 nm for a chan…

Biosensors and Analytical DetectionGas Sensing Nanomaterials and SensorsGold and Silver Nanoparticles Synthesis and Applications

Alginate-Mediated Growth of Co, Ni, and CoNi Nanoparticles: Influence of the Biopolymer Structure

Roberta Brayner、Marie-Josèphe Vaulay、Fernand Fiévet 等 4 位作者2007-02-06Chemistry of Materials

Biopolymers have already been widely used to control the growth of inorganic particles. However, some of these natural macromolecules present an intrinsic chemical and structural variability that may influence their templating efficiency. We have therefore compared the ability of three different sources of alginate to…

Pickering emulsions and particle stabilizationAlgal biology and biofuel productionPolymer Surface Interaction Studies

Magnetic structure and phase diagram in a spin-chain system: Ca$_3$Co$_2$O$_6$

Yuri B. Kudasov2007-02-06arXiv

The low-temperature structure of the frustrated spin-chain compound Ca$_3$Co$_2$O$_6$ is determined by the ground state of the 2D Ising model on the triangular lattice. At high-temperatures it transforms to the honeycomb magnetic structure. It is shown that the crossover between the two magnetic structures at 12 K ari…

cond-mat.stat-mechMaterials Science

Chain motion and viscoelasticity in highly entangled solutions of semiflexible rods

Shriram Ramanathan、David C Morse2007-02-06arXiv

Brownian dynamics simulations are used to study highly entangled solutions of semiflexible polymers. Bending fluctuations of semiflexible rods are signficantly affected by entanglement only above a concentration $c^{**}$, where $c^{**}\sim 10^{3}L^{-3}$ for chains of similar length $L$ and persistence length. For $c >…

Soft Condensed MatterMaterials Science

Growth Kinetics of 0.5 cm Vertically Aligned Single-Walled Carbon Nanotubes

Guofang Zhong、Takayuki Iwasaki、John Robertson 等 4 位作者2007-02-06The Journal of Physical Chemistry B

Half-centimeter-high mats of vertically aligned single-walled carbon nanotubes were grown at 600 degrees C by point-arc microwave plasma chemical vapor deposition. The mats were produced from 0.5 nm of an Fe catalyst layer, thus showing one of the highest catalytic yields of approximately 105 times. The growth process…

Fullerene Chemistry and ApplicationsGraphene research and applicationsCarbon Nanotubes in Composites

Spin relaxation time, spin dephasing time and ensemble spin dephasing time in $n$-type GaAs quantum wells

C. Lü、J. L. Cheng、M. W. Wu 等 4 位作者2007-02-06arXiv

We investigate the spin relaxation and spin dephasing of $n$-type GaAs quantum wells. We obtain the spin relaxation time $T_1$, the spin dephasing time $T_2$ and the ensemble spin dephasing time $T_2^{\ast}$ by solving the full microscopic kinetic spin Bloch equations, and we show that, analogous to the common sense i…

cond-mat.otherMaterials Science

MBE Growth of Cubic InN

J. Schoermann、D. J. As、K. Lischka2007-02-06arXiv

Cubic InN films were grown on top of a c-GaN buffer layer by rf-plasma assisted MBE at different growth temperatures. X-Ray diffraction investigations show that the c-InN layers consist of a nearly phase-pure zinc blende (cubic) structure with a small fraction of the wurtzite (hexagonal) phase grown on the (111) facet…

Materials Science

Mechanism of nucleation and growth near the gas-liquid spinodal

Prabhakar Bhimalapuram、Suman Chakrabarty、Biman Bagchi2007-02-06arXiv

Understanding the mechanism of nucleation of the stable phase inside the metastable parent phase during a first order phase transition has been a subject of outstanding interest in natural science. The problem becomes even more challenging as the spinodal is approached. In this work, we have undertaken extensive compu…

Materials ScienceSoft Condensed Matter

19 F magnetic resonance imaging for stem/progenitor cell tracking with multiple unique perfluorocarbon nanobeacons

Kathryn C. Partlow、Junjie Chen、Jason A. Brant 等 10 位作者2007-02-06OpenAlex

ABSTRACT MRI has been employed to elucidate the migratory behavior of stem/progenitor cells noninva‐sively in vivo with traditional proton ( 1 H) imaging of iron oxide nanoparticle‐labeled cells. Alternatively, we demonstrate that fluorine ( 19 F) MRI of cells labeled with different types of liquid perfluorocarbon (PF…

Advanced MRI Techniques and ApplicationsCancer, Hypoxia, and MetabolismLanthanide and Transition Metal Complexes

Biological Designer Self-Assembling Peptide Nanofiber Scaffolds Significantly Enhance Osteoblast Proliferation, Differentiation and 3-D Migration

Akihiro Horii、Xiumei Wang、Fabrizio Gelain 等 4 位作者2007-02-06OpenAlex

A class of self-assembling peptide nanofiber scaffolds has been shown to be an excellent biological material for 3-dimension cell culture and stimulating cell migration into the scaffold, as well as for repairing tissue defects in animals. We report here the development of several peptide nanofiber scaffolds designed…

RNA Interference and Gene DeliverySupramolecular Self-Assembly in MaterialsAntimicrobial Peptides and Activities

Magnetic Confinement of Massless Dirac Fermions in Graphene

Alessandro De Martino、Luca Dell’Anna、Reinhold Egger2007-02-06OpenAlex

Because of Klein tunneling, electrostatic potentials are unable to confine Dirac electrons. We show that it is possible to confine massless Dirac fermions in a monolayer graphene sheet by inhomogeneous magnetic fields. This allows one to design mesoscopic structures in graphene by magnetic barriers, e.g., quantum dots…

Topological Materials and PhenomenaQuantum and electron transport phenomenaGraphene research and applications

Biomedical applications of diamond‐like carbon coatings: A review

Ritwik Kumar Roy、Kwang‐Ryeol Lee2007-02-06OpenAlex

Owing to its superior tribological and mechanical properties with corrosion resistance, biocompatibility, and hemocompatibility, diamond-like carbon (DLC) has emerged as a promising material for biomedical applications. DLC films with various atomic bond structures and compositions are finding places in orthopedic, ca…

Diamond and Carbon-based Materials ResearchMetal and Thin Film MechanicsLubricants and Their Additives