Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInduced dynamic nuclear spin polarization in photoreductions of benzophenone by toluene and ethylbenzeneGerhard L. Closs and Liselotte E. ClossCite this: J. Am. Chem. Soc. 1969, 91, 16, 4550–4552Publication Date (Print):July 1, 1969Publication History Published online1 May 2…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTADIABATIC GAS ABSORPTION AND STRIPPING IN PACKED TOWERSRobert E. TreybalCite this: Ind. Eng. Chem. 1969, 61, 7, 36–41Publication Date (Print):July 1, 1969Publication History Published online1 May 2002Published inissue 1 July 1969https://pubs.acs.org/doi/10.1021/ie50715a009ht…
UCRL-18456 Cs 2 BkC1 6 and Cs 2 NaBkC1 6 have been FreFared from aqueous solution on the scale of a few micrograms using the isotoFe 249Bk.The crystal structures of these comFounds have been determined.Cs 2 BkC1 6 is not isomorFhous with Cs 2 PuC1 6 or CS2CeC16' which exhibi ttrigonal symmetry, but rather is hexagonal…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDonor-acceptor complexes of the inorganic .pi. acceptor, bis-cis-(1,2-perfluoromethylethene-1,2-dithiolato)nickelRichard D. Schmitt, Richard M. Wing, and August H. MakiCite this: J. Am. Chem. Soc. 1969, 91, 16, 4394–4401Publication Date (Print):July 1, 1969Publication Histor…
Single crystal thin films of titanium have been epitaxially grown on NaCl substrates of three different orientations [(001), (110), (111)]. At thicknesses above 500 Å, the normal hexagonal close-packed structure is obtained. Below approximately 350 Å, the metal is seen to grow in a previously unreported face-centered…
The 719–730-cm−1 doublet in the infrared spectrum of polyethylene (PE) is known to shift to higher frequencies with decreasing temperature. In this work we have measured these peak positions as a function of temperature down to 10°K for three bulk polyethylene samples of three different degrees of crystallinity, as we…
The condition for metallic or non-metallic behaviour in compounds of transition metals is examined, with particular reference to titanates, vanadium and titanium oxides, and to Fe3O4
Abstract The effects of temperature and penetrant activity on the sorption kinetics and equilibria of a series of alkanes in glassy, biaxially oriented polystyrene were studied. Normal isomers of pentane, hexane, and heptane cause crazing of polystyrene film samples at high penetrant activities (> 0.85). Crazing ki…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation W. Buckel; Internal Stresses. J. Vac. Sci. Technol. 1 July 1969; 6 (4): 606–609. https://doi.org/…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolid solution of aluminum oxide in rutile titanium dioxideRichard A. Slepetys and Philip A. VaughanCite this: J. Phys. Chem. 1969, 73, 7, 2157–2162Publication Date (Print):July 1, 1969Publication History Published online1 May 2002Published inissue 1 July 1969https://pubs.ac…
From a critical evaluation of the available data on the system Na 2 O‐Al 2 O 2 and particularly on β‐Al 2 O 3 some of the discrepancies in the literature were resolved, and plausible phase diagrams for the system were constructed. The diagrams define needed equilibrium data and are useful in putting into perspective t…
Abstract A modus operandi is developed for determining the molecular structure of hydroxypropylcellulose (HPC), and characterizing, in quantitative terms, the morphological changes occurring when a water‐cast film of the polymer is deformed. This involves the application of the following eleven different physical meas…
We develop an analytical framework for the theory of plasticity in which the constitutive equations are single valued and which at the same time represents the proper physical concepts. A Coleman-Gurtintype thermodynamics which utilizes internal state variables is used for the study of an elastic-plastic substance. Qu…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSteric parameters in drug design. Monoamine oxidase inhibitors and antihistaminesEberhard Kutter and Corwin HanschCite this: J. Med. Chem. 1969, 12, 4, 647–652Publication Date (Print):July 1, 1969Publication History Published online1 May 2002Published inissue 1 July 1969http…
A multistep kinetic process is postulated to describe the pyrolysis of nylon 6–6, phenolic CTL-91LD (a phenolic novalac resin), and their composites. Kinetic coefficients are derived from thermogravimetric analysis data (TGA) at heating rates varying from 3–60°C/min for each component. Three correlation techniques are…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure of aquomagnesium tetraphenylporphyrinRussell Timkovich and A. TulinskyCite this: J. Am. Chem. Soc. 1969, 91, 16, 4430–4432Publication Date (Print):July 1, 1969Publication History Published online1 May 2002Published inissue 1 July 1969https://pubs.acs.org/doi/10.102…
Abstract The kinetics of dehydration and decarboxylation as well as the glass transition temperature as a function of anhydride content were measured for poly(acry1ic acid). It was found that the glass transition of PAA is of the order of 103°C and increases with increasing anhydride content, reaching an extrapolated…
Abstract Antiplasticizers are considered to be diluents which when added to polymers result in mechanical property behavior opposite to that of plasticization. The addition of antiplasticizers to certain polymers such as Bisphenol A polycarbonate, polysulfone, and polyvinyl chloride results in the elimination of the s…
Abstract Isotactic polypropylene was decomposed under vacuum at 360, 380, and 400°C, and the volatile products from C 1 to C 12 hydrocarbons were analyzed by gas chromatography. The formation of the main products is discussed on the basis of a free‐radical mechanism in which intramolecular radical transfer is assumed…
Abstract The effects of shear stress on the crystallization kinetics and morphology of linear polyethylene and polybutene‐1 were studied with the aid of a specially designed apparatus. With this equipment, it was possible to heat a thin polymer sample between glass slides to a melt temperature, quench the sample to a…