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Double Molybdates and Tungstates of the Rare Earth and Alkali Metals

A. A. Maier、M.V. Provotorov、V. A. Balashov1973-10-31Russian Chemical Reviews

Data on the preparation, structure, and various properties of the double tungstates and molybdates (EO4) of the alkali (M) and rare earth (R) metals with the composition RM(EO4)2 have been summarised and systematised. The regular features of the change in the symmetry, polymorphism, and nature of the fusion with chang…

Luminescence Properties of Advanced MaterialsCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Intrinsic photoconduction and photoemission in polyethylene

K J Less、E. G. Wilson1973-10-30Journal of Physics C Solid State Physics

Intrinsic photoemission and photoconduction of polyethylene in the photon energy range 7<E<14 eV have been experimentally investigated. Both phenomena are parabolic in E with the same threshold energy E G =8.8 eV. The main features of a model that accounts for the observations are: (a) E G is the intrinsic electron-ho…

Force Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Polysulfur Nitride—a One-Dimensional Chain with a Metallic Ground State

Vernon Walatka、M. M. Labes、Jerome H. Perlstein1973-10-29OpenAlex

The temperature dependence of the electrical conductivity and Seebeck coefficient for the polymer chain system ${(\mathrm{SN})}_{x}$ has been measured along the chain axis from 4.2 to 300\ifmmode^\circ\else\textdegree\fi{}K. The data show the system to be metallic over the entire temperature range studied, with a smal…

Magnetism in coordination complexesConducting polymers and applicationsOrganic and Molecular Conductors Research

Growth of color centres and hardening of CaF2 by heavy dose of γ-irradiation

S. R. Sashital、K. Vedam1973-10-16physica status solidi (a)

The growth of color centers and the accompanying changes in the mechanical properties (flow stress, Vicker's microhardness and dislocation mobilities) of CaF2 single crystals due to γ-ray irradiation has been studied in the dosage range of 104 to 5 × 108 R at room temperature. Of the four absorption band spectra with…

Luminescence Properties of Advanced MaterialsNuclear Materials and PropertiesIon-surface interactions and analysis

Mobility of dislocations in Fe-3% Si

H. Saka、T. Imura1973-10-16physica status solidi (a)

The mobilities of edge and screw dislocations in Fe-3% Si weremeasured directly by using an etch-pitting method in the temperature range of 298 to 198 °K. It was also examined whether or not there is asymmetry in the mobility of screw dislocations with respect to a reversal ofthe sign of the applied shear stress. From…

Microstructure and Mechanical Properties of SteelsAluminum Alloy Microstructure PropertiesMagnetic Properties and Applications

Exciton-phonon interaction in crystalline phenanthrene

K. Tomioka、Hiroyuki Amimoto、Tosiro Tomotika 等 4 位作者1973-10-15The Journal of Chemical Physics

The polarized optical absorption spectrum of the first exciton band (the first progression member of 1A1 exciton band) of crystalline phenanthrene has been measured in the temperature range 81 to 293 °K. The exciton-phonon interaction is discussed using Toyozawa's theory. The lower energy tail of the first exciton abs…

Spectroscopy and Quantum Chemical StudiesPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Temperature Dependence of the EPR Spectra of Niobium-Doped TiO2

P. Zimmermann1973-10-15Physical review. B, Solid state

Detailed measurements of the temperature dependence of the EPR spectrum and Hall coefficient of niobium-doped rutile have been made. At 4.2 \ifmmode^\circ\else\textdegree\fi{}K and 34 GHz, the EPR spectrum consists of a set of well-resolved hyperfine lines which coalesce and then shift with increasing temperature. Com…

Advancements in Battery MaterialsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Dislocation Mobility in Pure Copper at 4.2 °K

K. M. Jassby、T. Vreeland1973-10-15Physical review. B, Solid state

Torsional stress pulses of several microseconds duration were applied at 4.2 \ifmmode^\circ\else\textdegree\fi{}K to cylindrical single crystals of copper containing freshly introduced dislocations. Dislocation displacements were measured by means of a double-etch technique, and subsequently the dislocation damping co…

Microstructure and mechanical propertiesSemiconductor materials and interfacesSurface and Thin Film Phenomena

Percolation View of Transport Properties inNaxWO3

P. A. Lightsey1973-10-15Physical review. B, Solid state

New measurements of electrical conductivity and Hall constants have been performed on single crystals of ${\mathrm{Na}}_{x}\mathrm{W}{\mathrm{O}}_{3}$ for $0.22&lt;x&lt;0.63$ and temperatures from 1.2 to 300 K. The conductivity varies with $x$ according to the relation, $\ensuremath{\sigma}\ensuremath{\propto}{(x\ensu…

Transition Metal Oxide NanomaterialsAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Comment on the Theory of Extended X-Ray-Absorption Fine Structure

W. L. Schaich1973-10-15Physical review. B, Solid state

The two theoretical approaches to extended x-ray-absorption fine structure, based on either "long-range order" or "short-range order" are critically examined within a muffin-tin-scatterer model. It is argued that the two apparently dissimilar theories will in practice yield essentially the same results. The argument i…

X-ray Spectroscopy and Fluorescence AnalysisX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

Vibrational Excitation ofO2by Electron Impact above 4 eV

S. F. Wong、M. J. W. Boness、G. J. Schulz1973-10-15Physical Review Letters

Vibrational excitation of ${\mathrm{O}}_{2}$ by electrons in the energy range 4-15 eV is studied with a crossed-beam double electrostatic analyzer. The differential vibrational cross sections for $v=1\ensuremath{-}4$ at 25\ifmmode^\circ\else\textdegree\fi{} show a bell-shaped energy dependence peaked near 9.5 eV. The…

Advanced Chemical Physics StudiesElectrochemical Analysis and ApplicationsElectron and X-Ray Spectroscopy Techniques

Optical storage in VO2 films

Anders Smith1973-10-15Applied Physics Letters

The use of VO2 films for direct-bit optical storage with near-infrared lasers is demonstrated. The VO2 response is fast (&amp;lt; 10 ns), and large read signals are obtained with unpolarized light. A writing threshold of 0.03 nJ/μm2 is observed.

Photonic and Optical DevicesTransition Metal Oxide NanomaterialsPhase-change materials and chalcogenides

Thermochromism and Electrical Conductivity in Doped SrTiO3

R. L. Wild、Evelyn M. Rockar、Jana C. Smith1973-10-15Physical review. B, Solid state

Large reversible thermochromic changes in pure and transition-metal-doped SrTi${\mathrm{O}}_{3}$ were observed which depend markedly on impurity concentration, anealing temperature, and especially on the rapidity of the quench. The material also changes its electrical properties from insulator to semimetallic, and for…

Chalcogenide Semiconductor Thin FilmsTransition Metal Oxide NanomaterialsElectronic and Structural Properties of Oxides

X-Ray Band Spectra and Electronic Structure of TiS2

David W. Fischer1973-10-15Physical review. B, Solid state

An electronic structure, in terms of molecular orbitals, is suggested for the layered compound Ti${\mathrm{S}}_{2}$. This structure is based on the combined $\mathrm{Ti}{L}_{\mathrm{III}}$, $\mathrm{Ti}K$, $\mathrm{S}{L}_{\mathrm{II},\mathrm{III}}$, and $\mathrm{S}K$ x-ray-emission and -absorption band spectra. The x-…

2D Materials and ApplicationsTransition Metal Oxide NanomaterialsSemiconductor materials and interfaces

On the Weak Ferromagnetism of Orthorhombic CuFe2S3

M. G. Townsend、J. L. Horwood、J. R. Gosselin1973-10-15Canadian Journal of Physics

Orthorhombic CuFe 2 S 3 is weakly ferromagnetic. The magnetic susceptibilities of single-crystal and polycrystalline specimens have been determined at temperatures between 78 and 500 °K. A model is presented to explain the weak ferromagnetism.

Magnetic and transport properties of perovskites and related materialsMagnetic Properties and Synthesis of FerritesAdvanced Condensed Matter Physics

X-Ray Photoemission from Sodium and Lithium

S. P. Kowalczyk、L. Ley、F. R. McFeely 等 5 位作者1973-10-15Physical review. B, Solid state

X-ray photoelectron spectra of Na and Li metals were obtained in ultrahigh vacuum. Rich plasmon structures were observed on all peaks. Both the photoemission and Auger peaks showed large extra-atomic relaxation energies. A simple "equivalent-cores" screening model predicts extra-atomic relaxation energies in good agre…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Liquid crystal phase transitions in mixtures of rodlike and platelike molecules

R. Alben1973-10-15The Journal of Chemical Physics

Model calculations are presented which indicate that the character of the nematic-isotropic phase transition can be continuously changed from first to second order and that a new biaxial liquid crystal phase can be obtained by mixing suitable platelike and rodlike molecules. Precursors of the predicted behavior should…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Study of the sensitivity of coupled reaction systems to uncertainties in rate coefficients. II Applications

John H. Schaibly、Kurt E. Shuler1973-10-15The Journal of Chemical Physics

The Fourier amplitude method developed in Paper I as a diagnostic tool for determining the sensitivity of the results of complex calculations to the parameters which enter these calculations has been applied to two chemical reaction systems involving sets of coupled, nonlinear rate equations. These were: (a) a five re…

Machine Learning in Materials ScienceThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Band Structures of Transition-Metal-Dichalcogenide Layer Compounds

L. F. Mattheiss1973-10-15OpenAlex

The nonrelativistic augmented-plane-wave (APW) method is applied to calculate the electronic band structures of several transition-metal-dichalcogenide ($T{X}_{2}$) layer compounds, including materials with the $C6(1T\ensuremath{-}\mathrm{Hf}{\mathrm{S}}_{2},1T\ensuremath{-}\mathrm{Ta}{\mathrm{S}}_{2})$, $C27(2H\ensur…

2D Materials and ApplicationsIron-based superconductors researchInorganic Chemistry and Materials