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Dissociation Constants and Solubilities of Dalbergin and Nordalbergin in Different Solvents

Wanjun Kong、Rui Sun、Yanjuan Gao 等 6 位作者2015-08-05Journal of Chemical & Engineering Data

The dissociation constants (p K a ) of dalbergin and nordalbergin were measured at 298.2 K using ultraviolet (UV) spectroscopy method. The solubilities of dalbergin and nordalbergin in water, methanol, propanone, ethyl ethanoate, trichloromethane, and hexane have been determined by the UV spectrophotometric method fro…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesPharmacological Effects of Natural Compounds

Preparation and Characterization of Tin Tungstate Thin Films

Alexei Kuzmin、Ma̅rtiņš Zubkins、R. Kalendarev2015-08-05Ferroelectrics

Tin tungstate thin films were prepared by dc magnetron sputtering method and studied by x-ray diffraction, confocal microscopy and Raman spectroscopy. It is shown that the films are composed mainly of nanocrystalline α-SnWO4 phase. The possibility to use these films as write-once optical recording media is demonstrate…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Space Charge Behavior in Paper Insulation Induced by Copper Sulfide in High-Voltage Direct Current Power Transformers

Ruijin Liao、Ende Hu、Lijun Yang 等 4 位作者2015-08-05Energies

The main insulation system in high-voltage direct current (HVDC) transformer consists of oil-paper insulation. The formation of space charge in insulation paper is crucial for the dielectric strength. Unfortunately, space charge behavior changes because of the corrosive sulfur substance in oil. This paper presents the…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Porous PZT Films Prepared by PVP Assisted Sol-Gel Process

Д. С. Серегин、К. А. Воротилов、А. С. Сигов 等 4 位作者2015-08-05Ferroelectrics

Sol-gel process of porous PbZr0.48Ti0.52O3 film preparation on Pt/TiO2/SiO2/Si substrates is studied. Polyvinylpyrrolidone (PVP) with molecular weight of 29000 is used as a porogen agent destroyed after annealing. The volume film porosity reaches ˜33 % at 20 wt.% PVP content that permits twice to increase the film thi…

Ferroelectric and Piezoelectric MaterialsSilicone and Siloxane ChemistryElectrophoretic Deposition in Materials Science

The Incommensurate Phase Transformation in TlInS2Ferroelectric

A. Salnik、Yu. P. Gololobov、N. A. Borovoy2015-08-05Ferroelectrics

The features of the crystal structure of c and 2c TlInS2 polytypes have been studied by single-crystal X-ray diffraction method in the temperature range 180 K–300 K. In the c polytype the appearance of the incommensurate phase with modulation vector was observed at the temperature of 238 K (on cooling). The active pha…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Oxygen Exchange in La0.6Sr0.4Co0.2Fe0.8O3−δ Thin-Film Heterostructures under Applied Electric Potential

E. Mitchell Hopper、Edith Perret、Brian J. Ingram 等 8 位作者2015-08-05The Journal of Physical Chemistry C

In situ synchrotron X-ray diffraction was used to investigate oxygen surface exchange behavior in La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3−δ /Gd 2 O 3 -doped CeO 2 /Y 2 O 3 -stabilized ZrO 2 (LSCF/GDC/YSZ) epitaxial thin-film heterostructures. Applying electrical potentials across the heterostructure under high temperature and…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Drug Release Mechanism of Slightly Soluble Drug from Nanocomposite Matrix Formulated with Zeolite/ Hydrotalcite as Drug Carrier

Ahmad Ainurofiq、Syaiful Choiri2015-08-05Tropical Journal of Pharmaceutical Research

Purpose: To evaluate the mechanism of drug release of a slightly soluble drug (theophylline) from nanocomposite of zeolite (ZLT) or hydrotalcite (HTC) used as drug carrier.Methods: Nanocomposite was prepared with dispersion of either ZLT or HTC as drug carrier and theophylline (THP) as drug in drug to clay ratios of 1…

Mesoporous Materials and CatalysisClay minerals and soil interactionsLayered Double Hydroxides Synthesis and Applications

Molecular mobility on graphene nanoroads

Mehdi Jafary‐Zadeh、Yong‐Wei Zhang2015-08-05Scientific Reports

We study molecular mobility on a graphene nanoroad (GNRD), a pristine graphene strip embedded in between two hydrogenated graphene domains serving as a nanoscale pathway for transporting admolecules. Our molecular dynamics simulations using a prototype physisorbed C60 admolecule demonstrate that the proposed GNRD is a…

Graphene research and applicationsMolecular Junctions and NanostructuresNanopore and Nanochannel Transport Studies

Effects of filament cross section on the performance of automotive upholstery fabrics

Serpil Koral Koç、Diren Mecit、Bekir Boyacı 等 5 位作者2015-08-05Journal of Industrial Textiles

Aim of this study was to investigate the effects of filament cross section on the performance of automotive upholstery fabrics. Thirty-six yarns were produced by changing the cross section of poly(ethylene terephthalate) fibers (round, octolobal and W-channel) and the air-jet texturing parameters (overfeed and number…

Mechanical Behavior of CompositesTextile materials and evaluationsMaterial Properties and Processing

Effects of M2+ (M = Ca, Sr, and Ba) Addition on Crystallization and Microstructure of SiO2-MgO-Al2O3-B2O3-K2O-F Glass

Mrinmoy Garai、Nibedita Sasmal、Basudeb Karmakar2015-08-05Indian Journal of Materials Science

In understanding the effect of K + substitution by M 2+ (M = Ca, Sr, and Ba) on crystallization and microstructural properties of boroaluminosilicate glass system, the SiO 2 -MgO-Al 2 O 3 -B 2 O 3 -MgF 2 -K 2 O-Li 2 O-AlPO 4 glasses were prepared by single-step melt-quenching at 1500°C. Density of base glass (2.64 g·c…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsNuclear materials and radiation effects

Anomalous Hall effect in epitaxial ferrimagnetic anti-perovskite Mn4−xDyxN films

Miao Meng、Shuxiang Wu、Wenqi Zhou 等 7 位作者2015-08-05Journal of Applied Physics

Anomalous Hall effect (AHE) has been studied for ferrimagnetic antiperovskite Mn4−xDyxN films grown by molecular-beam epitaxy. The introduction of Dy changes the AHE dramatically, even changes its sign, while the variations in magnetization are negligible. Two sign reversals of the AHE (negative-positive-negative) are…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

On the orientation of N2and CO2molecules adsorbed in slit pore models with oxidised graphitic surface

Anastasios Gotzias、Georgia Charalambopoulou、Theodore Steriotis2015-08-05Molecular Simulation

We report grand canonical Monte Carlo studies of nitrogen (77 K) and carbon dioxide (253 K) adsorbed in graphitic slit pores with surface oxygen functionalities. The analysis is focused on the molecular orientation within the adsorption layers and the influence of surface heterogeneity on molecular density distributio…

Catalytic Processes in Materials SciencePhase Equilibria and ThermodynamicsCatalysis and Oxidation Reactions

Dynamics of dissipative self-assembly of particles interacting through oscillatory forces

M. Tagliazucchi、Igal Szleifer2015-08-05Faraday Discussions

Dissipative self-assembly is the formation of ordered structures far from equilibrium, which continuously uptake energy and dissipate it into the environment. Due to its dynamical nature, dissipative self-assembly can lead to new phenomena and possibilities of self-organization that are unavailable to equilibrium syst…

Proteins in Food SystemsMicro and Nano RoboticsPickering emulsions and particle stabilization

Electrochemical deposition of silver nanoparticle and polymerization of pyrrole on fabrics via conducting multiwall carbon nanotubes

Tomasz Makowski、Dorota Kowalczyk、Witold Fortuniak 等 5 位作者2015-08-05Cellulose

The paper presents results of tests on the possibility of utilising fabric with a deposited spatial network of multiwall carbon nanotubes (MWCNTs) as electrodes in processes of their functionalization by electrochemical methods enabling deposition of metal nanoparticles, as well as—by electropolymerization—of conducti…

Carbon Nanotubes in CompositesNanoparticles: synthesis and applicationsConducting polymers and applications

Firsthand in situ observation of active fine laser tuning by combining a temperature gradient and a CLC wedge cell structure

Mi‐Yun Jeong、Jihun Cha2015-08-05Optics Express

In situ direct observation of the lasing process in a cholesteric liquid crystal (CLC) laser array using a CMOS camera was used to investigate discontinuous laser tuning in a parallel CLC cell. In accordance with the discontinuous pitch change by thermal energy transfer, at the same time the laser wavelength undergoes…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Pseudo-planar conjugated swastikas metamaterial with giant circular dichroism and negative refraction at near-infrared region

Fang Fang、Lin Gao、Honghua Liao2015-08-05Journal of Modern Optics

In this paper, a pseudo-planar conjugated swastikas metamaterial (MM) was proposed and investigated numerically at near-infrared region. Numerical results show that the circular dichroism (CD) is more than 25 dB at resonance frequencies. Owing to the stronger chirality, the refractive indices for right-handed and left…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Corrosion Inhibition of Mild Steel by Various Plant Extracts in Acid Media

O. O. Obiukwu、Ignatius Opara、Lawan U. Grema2015-08-05Research Journal of Applied Sciences Engineering and Technology

The aim of this study is to investigate the corrosion inhibition of some plant extracts on mild steel in selected media. The plant extracts investigated are Okazi leaf (<em>Gnetum africanum</em>), Utazi leaf (<em>Gongronema latifolium</em>) and Elizabeth leaf (<em>Chromolena odaratum</em>). The selected media are 1M H…

Corrosion Behavior and Inhibition

Porphyrin Nanowires with Epitaxially Locked Uniaxial Orientation

Marcello Campione、Giancarlo Capitani、Luisa Raimondo 等 4 位作者2015-08-05The Journal of Physical Chemistry C

The ability to drive the growth of nano-objects of functional materials with desired shape, size, and orientation is necessary for exploiting the potentiality of organic-based nanoelectronics. Here, we present a methodology for growing by vacuum sublimation low-dimensional structures of a free-base porphyrin, in parti…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

A comprehensive study on the thermo-mechanical properties of multi-walled carbon nanotube/epoxy nanocomposites

Mohammad Hossein Yas、Samira Mohammadi、Bandar Astinchap 等 4 位作者2015-08-05Journal of Composite Materials

In this study, the mechanical, thermal and viscoelastic properties of multi-walled carbon nanotube/epoxy nanocomposite at low-weight percentages of nanotubes are evaluated and discussed. In order to provide better interfacial interactions of constituent materials, the multi-walled carbon nanotubes are functionalized w…

Carbon Nanotubes in CompositesNatural Fiber Reinforced CompositesNanotechnology research and applications

Depolarizing field in ultrathin electrocalorics

Е. А. Глазкова、C.-M. Chang、S. Lisenkov 等 5 位作者2015-08-05Physical Review B

Ferroelectric thin films are considered to be among the top candidates for room-temperature electrocaloric materials as they exhibit excellent electric properties and allow application of record high electric fields. At the same time, downsizing of ferroelectric electrocalorics brings about an unwanted but unavoidable…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsFerroelectric and Negative Capacitance Devices