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Creating a Nanospace under an h-BN Cover for Adlayer Growth on Nickel(111)

Yang Yang、Qiang Fu、Haobo Li 等 7 位作者2015-10-08ACS Nano

Heterostructures of two-dimensional (2D) atomic crystals have attracted increasing attention, while fabrication of the 2D stacking structures remains a challenge. In this work, we present a route toward formation of 2D heterostructures via confined growth of a 2D adlayer underneath the other 2D overlayer. Taking a hex…

Graphene research and applications2D Materials and ApplicationsQuantum and electron transport phenomena

Cuboid-like Bi2Fe4O9/Ag with Graphene-Wrapping Tribrid Composite with Superior Capability for Environmental Decontamination: Nanoscaled Material Design and Visible-Light-Driven Multifunctional Catalyst

Zhong-Ting Hu、Shun Kuang Lua、Teik‐Thye Lim2015-10-08ACS Sustainable Chemistry & Engineering

A cuboid-like Bi 2 Fe 4 O 9 /Ag with graphene-wrapping tribrid nanoarchitecture was fabricated using a delicate multistep synthesis process. It is designed to effectively enhance the performance of the pristine Bi 2 Fe 4 O 9 in the removal of organic pollutants [up to 97% of methylene blue (MB) removal in 30 min under…

Advanced Photocatalysis TechniquesMultiferroics and related materials

Multiwalled Carbon Nanotube Oxygen Sensor: Enhanced Oxygen Sensitivity at Room Temperature and Mechanism of Sensing

Krishnamoorthy Rajavel、Murugan Lalitha、Joghee Kullan Radhakrishnan 等 5 位作者2015-10-08ACS Applied Materials & Interfaces

A pyrolysis assisted method was applied for the synthesis of defect controlled carbon nanotubes (CNTs) by varying different growth temperatures. The fabricated resistive devices containing a random network of CNTs were tested for oxygen sensing under standard room-temperature and pressure conditions. Nanotubes grown a…

Carbon Nanotubes in CompositesGas Sensing Nanomaterials and SensorsAnalytical Chemistry and Sensors

Half-Metallic Behavior in Doped Sr2CrOsO6 Double Perovskite with High Transition Temperature

Kartik Samanta、Prabuddha Sanyal、Tanusri Saha‐Dasgupta2015-10-08Scientific Reports

Half-metallic magnets with metallic behavior in one spin channel and insulating in the other, have attracted considerable attention due to their potential application possibility. The spin-dependent nature of the carrier scattering due to half-metallic nature of these materials, allows for the resistance to be strongl…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Spectroscopic Visualization of Grain Boundaries of Monolayer Molybdenum Disulfide by Stacking Bilayers

Seki Park、Min Su Kim、Jaemin Kim 等 7 位作者2015-10-08ACS Nano

Polycrystalline growth of molybdenum disulfide (MoS2) using chemical vapor deposition (CVD) methods is subject to the formation of grain boundaries (GBs), which have a large effect on the electrical and optical properties of MoS2-based optoelectronic devices. The identification of grains and GBs of CVD-grown monolayer…

Perovskite Materials and Applications2D Materials and ApplicationsChalcogenide Semiconductor Thin Films

[{Ni4(OH)3AsO4}4(B‐α‐PW9O34)4]28−: A New Polyoxometalate Structural Family with Catalytic Hydrogen Evolution Activity

Hongjin Lv、Yingnan Chi、Jan van Leusen 等 10 位作者2015-10-08Chemistry - A European Journal

A new structural polyoxometalate motif, [{Ni4 (OH)3 AsO4 }4 (B-α-PW9 O34 )4 ](28-) , which contains the highest nuclearity structurally characterized multi-nickel-containing polyanion to date, has been synthesized and characterized by single-crystal X-ray diffraction, temperature-dependent magnetism and several other…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

The Use of Shape Memory Polymers for MEMS Assembly

Jeffrey D. Eisenhaure、S. Rhee、Ala'a M. Al‐Okaily 等 6 位作者2015-10-08Journal of Microelectromechanical Systems

The advantages of utilizing the polymeric shape memory effect for deterministic assembly of microscale objects are explored in this paper. Assembly of building blocks, referred to as inks, by transfer printing is performed using a polymeric stamp with reversible adhesion as a manipulator. The dynamic rigidity control…

Advanced Sensor and Energy Harvesting MaterialsPolymer composites and self-healingAdvanced Materials and Mechanics

Mechanical Tuning of Thermal Transport in a Molecular Junction

Qian Li、Ivan Duchemin、Shiyun Xiong 等 5 位作者2015-10-08The Journal of Physical Chemistry C

Understanding and controlling heat transport in molecular junctions would provide new routes to design nanoscale coupled electronic and phononic devices. Using first-principles full quantum calculations, we tune thermal conductance of a molecular junction by mechanically compressing and extending a short alkane chain…

Graphene research and applicationsAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Evidence in Support of Exciton to Ligand Vibrational Coupling in Colloidal Quantum Dots

Efrat Lifshitz2015-10-08The Journal of Physical Chemistry Letters

The Perspective focuses on the investigation of an unresolved conflict in semiconductor colloidal quantum dots (CQDs) research, concerning the influence of the immediate surrounding on the optical properties of the materials. Today's advanced synthetic colloidal procedures offer formation of a high-quality inorganic c…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Pore characteristics for improving luminous efficacy of phosphor-in-glass

Sunil Kim、H. Yie、Seunggon Choi 等 5 位作者2015-10-08Optics Express

) on the viscosity and pore properties at different sintering temperatures. This study found that PIGs sintered within a given viscosity range exhibit different optical properties depending on their pore size and overall porosity; a higher luminous efficacy observed in the case of intermediate scattering length values…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsGas Sensing Nanomaterials and Sensors

Membrane assisted cooling crystallization: Process model, nucleation, metastable zone, and crystal size distribution

Xiaobin Jiang、Dapeng Lu、Wu Xiao 等 6 位作者2015-10-08AIChE Journal

The membrane assisted cooling crystallization was proposed and investigated by the simulation and experiments. The developed process model concerned the supersaturation evolution on the membrane interface, the combined nucleation rate in the crystallizer. The impact of different membrane on reducing the nucleation bar…

Process Optimization and IntegrationCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

Ceria–Zirconia Particles Wrapped in a 2D Carbon Envelope: Improved Low‐Temperature Oxygen Transfer and Oxidation Activity

Eleonora Aneggi、Verónica Rico-Pérez、Carla de Leitenburg 等 7 位作者2015-10-08Angewandte Chemie International Edition

Engineering the interface between different components of heterogeneous catalysts at nanometer level can radically alter their performances. This is particularly true for ceria-based catalysts where the interactions are critical for obtaining materials with enhanced properties. Here we show that mechanical contact ach…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Realisation and advanced engineering of true optical rugate filters based on nanoporous anodic alumina by sinusoidal pulse anodisation

Abel Santos、Jeong Ha Yoo、Charu Vashisth Rohatgi 等 6 位作者2015-10-08Nanoscale

This study is the first realisation of true optical rugate filters (RFs) based on nanoporous anodic alumina (NAA) by sinusoidal waves. An innovative and rationally designed sinusoidal pulse anodisation (SPA) approach in galvanostatic mode is used with the aim of engineering the effective medium of NAA in a sinusoidal…

Photonic Crystals and ApplicationsOptical Coatings and GratingsAnodic Oxide Films and Nanostructures

The concentration-dependent behaviour of nanoparticles

Mohammed Baalousha、Mithun Sikder、Ashwini Prasad 等 6 位作者2015-10-08Environmental Chemistry

Environmental context Studies of manufactured nanoparticles (NPs) in the environment have been performed almost exclusively at high NP concentrations. These data lead to misunderstandings related to NP fate and effects at relevant environmental concentrations, which are expected to be low. A better understanding of th…

Nanoparticles: synthesis and applicationsAir Quality and Health ImpactsMicroplastics and Plastic Pollution

Original Synthetic Route To Obtain a SrAl2O4 Phosphor by the Molten Salt Method: Insights into the Reaction Mechanism and Enhancement of the Persistent Luminescence

Rocío Estefanía Rojas-Hernández、Fernando Rubio‐Marcos、Ricardo H. Gonçalves 等 8 位作者2015-10-08Inorganic Chemistry

SrAl2O4:Eu(2+), Dy(3+) has been extensively studied for industrial applications in the luminescent materials field, because of its excellent persistent luminescence properties and chemical stability. Traditionally, this strontium aluminate material is synthesized in bulk form and/or fine powder by the classic solid-st…

Luminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Polarization induced self-doping in epitaxial Pb(Zr0.20Ti0.80)O3 thin films

L. Pintilie、Corneliu Ghica、Cristian M. Teodorescu 等 14 位作者2015-10-08Scientific Reports

The compensation of the depolarization field in ferroelectric layers requires the presence of a suitable amount of charges able to follow any variation of the ferroelectric polarization. These can be free carriers or charged defects located in the ferroelectric material or free carriers coming from the electrodes. Her…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Intracellular Temperature Sensing: An Ultra-bright Luminescent Nanothermometer with Non-sensitivity to pH and Ionic Strength

Helin Liu、Yanyan Fan、Jianhai Wang 等 8 位作者2015-10-08Scientific Reports

Luminescence thermometry usually suffer from cellular complexity of the biochemical environment (such as pH and ionic strength), and thus the accuracy and reliability of the determined intracellular temperature are directly affected. Herein, a photoluminescent nanothermometer composed of polymer encapsulated quantum d…

Quantum Dots Synthesis And PropertiesNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Single-Layer Graphene as a Barrier Layer for Intense UV Laser-Induced Damages for Silver Nanowire Network

Suprem R. Das、Qiong Nian、Mojib Saei 等 9 位作者2015-10-08ACS Nano

Single-layer graphene (SLG) has been proposed as the thinnest protective/barrier layer for wide applications involving resistance to oxidation, corrosion, atomic/molecular diffusion, electromagnetic interference, and bacterial contamination. Functional metallic nanostructures have lower thermal stability than their bu…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchLaser-Ablation Synthesis of Nanoparticles

The effect of order–disorder phase transitions and band gap evolution on the thermoelectric properties of AgCuS nanocrystals

Satya N. Guin、Dirtha Sanyal、Kanishka Biswas2015-10-08Chemical Science

Copper and silver based chalcogenides, chalco-halides, and halides form a unique class of semiconductors, as they display mixed ionic and electronic conduction in their superionic phase. These compounds are composed of softly coupled cationic and anionic substructures, and undergo a transition to a superionic phase di…

Quantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

Direct Writing of Three-Dimensional Macroporous Photonic Crystals on Pressure-Responsive Shape Memory Polymers

Yin Fang、Yongliang Ni、Sin‐Yen Leo 等 7 位作者2015-10-08ACS Applied Materials & Interfaces

Here we report a single-step direct writing technology for making three-dimensional (3D) macroporous photonic crystal patterns on a new type of pressure-responsive shape memory polymer (SMP). This approach integrates two disparate fields that do not typically intersect: the well-established templating nanofabrication…

Photonic Crystals and ApplicationsPolymer composites and self-healingAdvanced Materials and Mechanics