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Bis[pyrrolyl Ru( ii )] triads: a new class of photosensitizers for metal–organic photodynamic therapy

Deborah A. Smithen、Susan Monro、Mitch Pinto 等 9 位作者2020-01-01Chemical Science

Ten dinuclear Ru( ii ) complexes based on the bis[pyrrolyl Ru( ii )] triad scaffold were prepared to evaluate the influence of the central organic linker on the spectroscopic and in vitro photodynamic therapy (PDT) properties of the compounds.

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Oxygen-atom vacancy formation and reactivity in polyoxovanadate clusters

Brittney E. Petel、Ellen M. Matson2020-01-01Chemical Communications

Overview of recent work detailing oxygen-deficient polyoxovanadate clusters as models for reducible metal oxides: toward gaining a fundamental understanding the consequences of vacancy formation on metal oxide surfaces during catalysis.

Catalytic Processes in Materials SciencePolyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation Reactions

In situ synthesis of copper nanoparticles encapsulated by nitrogen-doped graphene at room temperature via solution plasma

Phu Quoc Phan、Sangwoo Chae、Phuwadej Pornaroontham 等 7 位作者2020-01-01RSC Advances

Metal-carbon core-shell nanostructures have gained research interest due to their better performances in not only stability but also other properties, such as catalytic, optical, and electrical properties. However, they are limited by complicated synthesis approaches. Therefore, the development of a simple method for…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Theoretical search for high-performance thermoelectric donor–acceptor copolymers: the role of super-exchange couplings

Xue Yong、Gang Wu、Wen Shi 等 10 位作者2020-01-01Journal of Materials Chemistry A

First-principles calculations of a series of representing D–A copolymers demonstrated the strong Super-Exchange couplings induce not only small hole effective mass but also weak electron-phonon couplings, and eventually high thermoelectric power factor.

Advanced Thermoelectric Materials and DevicesConducting polymers and applicationsThermal properties of materials

CdS crown growth on CdSe nanoplatelets: core shape matters

Anja Schlosser、Rebecca T. Graf、Nadja C. Bigall2020-01-01Nanoscale Advances

The influence of tri- n -octylphosphine on the synthesis of CdS crowns around various types of CdSe core nanoplatelets is investigated.

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

An overview of conventional and non-conventional techniques for machining of titanium alloys

Samuel Ranti Oke、Gabriel Seun Ogunwande、Moshood Onifade 等 10 位作者2020-01-01Manufacturing Review

Machining is one of the major contributors to the high cost of titanium-based components. This is as a result of severe tool wear and high volume of waste generated from the workpiece. Research efforts seeking to reduce the cost of titanium alloys have explored the possibility of either eliminating machining as a proc…

Advanced machining processes and optimizationTitanium Alloys Microstructure and PropertiesAdvanced Machining and Optimization Techniques

High performance in situ annealed partially pressurized pulsed laser deposited WO 3 & V 2 O 5 thin film electrodes for use as flexible all solid state supercapbatteries

Ramasamy Velmurugan、Palaniappan Alagammai、Mani Ulaganathan 等 4 位作者2020-01-01Journal of Materials Chemistry A

Flexible all solid-state hybrid supercapacitors (HSCs) are considered to be significant energy storage devices and are used as major power sources in various real-time applications.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Two-dimensional silicon bismotide (SiBi) monolayer with a honeycomb-like lattice: first-principles study of tuning the electronic properties

A. Bafekry、Fazel Shojaei、Mohammed M. Obeid 等 6 位作者2020-01-01RSC Advances

molecular dynamic simulations and phonon dispersion calculations suggest its good thermal and dynamical stability. The SiBi monolayer is a semiconductor with a narrow indirect bandgap of 0.4 eV. Our results show that the indirect bandgap decreases as the number of layers increases, and when the number of layers is mor…

2D Materials and ApplicationsThermal properties of materialsMXene and MAX Phase Materials

Responsive Trimodal Probes for In Vivo Imaging of Liver Inflammation by Coassembly and GSH-Driven Disassembly

Yuxuan Hu、Yuqi Wang、Xidan Wen 等 9 位作者2020-01-01Research

Noninvasive in vivo imaging of hepatic glutathione (GSH) levels is essential to early diagnosis and prognosis of acute hepatitis. Although GSH-responsive fluorescence imaging probes have been reported for evaluation of hepatitis conditions, the low penetration depth of light in liver tissue has impeded reliable GSH vi…

Advanced biosensing and bioanalysis techniquesNanoplatforms for cancer theranosticsSupramolecular Self-Assembly in Materials

Interplay between local distortion at lattice sites with optical and electrical properties of Eu 3+ -doped MNbO 3 (M = Na and K) compounds

Nimai Pathak、Sumanta Mukherjee、Balaji P. Mandal 等 6 位作者2020-01-01Materials Advances

An effort was made to understand the correlation between local distortion at the lattice site with optical and electrical properties of Eu 3+ -doped MNbO 3 (M = Na and K) compounds for their potential application in piezophotonic devices.

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Microfibers synthesized by wet-spinning of chitin nanomaterials: mechanical, structural and cell proliferation properties

Ling Wang、Nazanin Zanjanizadeh Ezazi、Liang Liu 等 8 位作者2020-01-01RSC Advances

), while being stable in the wet state (50% of dry strength), which warrants consideration as biobased absorbent systems. In addition, according to cell proliferation and viability of rat cardiac myoblast H9c2 and mouse bone osteoblast K7M2, the wet-spun ChNF microfibers showed excellent results and can be considered…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Green approach in fabrication of photocatalytic, antimicrobial, and antioxidant zinc oxide nanoparticles – hydrothermal synthesis using clove hydroalcoholic extract and optimization of the process

Mahvash Anvarinezhad、Afshin Javadi、Hoda Jafarizadeh‐Malmiri2020-01-01Green Processing and Synthesis

Abstract Zinc oxide nanoparticles (ZnO NPs) were hydrothermally fabricated, using hydroalcoholic clove extract. GC-MS analysis demonstrated that Eugenol is the main bioactive compound of the prepared extract. Experiments were designed, based on the central composite design. The effects of different amounts of zinc nit…

Nanoparticles: synthesis and applicationsAdvanced Nanomaterials in CatalysisMoringa oleifera research and applications

Negative and zero thermal expansion in α-(Cu 2−x Zn x )V 2 O 7 solid solutions

Naike Shi、Andrea Sanson、Alessandro Venier 等 7 位作者2020-01-01Chemical Communications

Negative or zero thermal expansion (NTE or ZTE) of materials is intriguing for controllable thermal expansion. We report a series of orthorhombic α-Cu2-xZnxV2O7 (x = 0, 0.1, 0.2), in which the volumetric coefficients of thermal expansion are successfully tuned from -10.19 × 10-6 K-1 to -1.58 × 10-6 K-1 in the temperat…

Advanced Battery Materials and TechnologiesMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

Interplay between engineered nanomaterials and microbiota

Yirong Zhang、Monika Mortimer、Liang‐Hong Guo2020-01-01Environmental Science Nano

Engineered nanomaterials (ENM) have a potential to modulate microbiota and induce harmful or beneficial effects in the host. However, the causal factors of ENM-induced dysbiosis remain unknown.

Nanoparticles: synthesis and applicationsBacterial biofilms and quorum sensingMedical and Biological Ozone Research

Fe–Ni metal–organic frameworks with prominent peroxidase-like activity for the colorimetric detection of Sn 2+ ions

Ye Hu、Chaochao Yue、Jing Wang 等 9 位作者2020-01-01The Analyst

Fe-Ni-MOFs with different amounts of Fe are synthesized through a two-step template etching method. Kinetic analysis indicates that Fe-Ni-MOF exhibits prominent intrinsic peroxidase-like activity, which could catalytically oxidize 3,3',5,5'-tetramethylbenzidine (TMB) to produce oxidized TMB (oxTMB) with a blue color.…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

Functionalization of pristine graphene for the synthesis of covalent graphene–polyaniline nanocomposite

Jaehyeung Park、Xiaojian Yang、Dhanushka Wickramasinghe 等 7 位作者2020-01-01RSC Advances

polymerization of aniline gave polyaniline covalently grafted on the FLG surface. Characterization by FTIR, TEM, SEM, XPS, XRD and electrochemistry confirmed the successful conjugation of PANI to FLG. The grafting density of PANI was estimated by thermal analysis to be ∼26%. As the PFPA-mediated coupling chemistry is…

Graphene research and applicationsSupercapacitor Materials and FabricationConducting polymers and applications