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Conformation and segmental motion of native and denatured ribonuclease A in solution. Application of natural-abundance carbon-13 partially relaxed Fourier transform nuclear magnetic resonance

Adam Allerhand、David M. Doddrell、Victor Glushko 等 7 位作者1971-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConformation and segmental motion of native and denatured ribonuclease A in solution. Application of natural-abundance carbon-13 partially relaxed Fourier transform nuclear magnetic resonanceAdam Allerhand, David Doddrell, Victor Glushko, David W. Cochran, Ernest Wenkert, Pe…

Protein Structure and DynamicsEnzyme Structure and FunctionMolecular spectroscopy and chirality

The Ballistic Damage Characteristics and Damage Tolerance of Wing Structural Elements

J. A. Jensen1971-01-01OpenAlex

The damage and residual strength of 7075-T6 aluminum panels exposed to caliber 0.50 AP M2 gunfire was found to vary with projectile velocity, impact angle, and target thickness. Maximum damage occurred at low velocities and high impact angles. The strength of thin panels agreed closely with fracture theory because of…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsElectromagnetic Launch and Propulsion Technology

Interactions and residence times in aqueous alkali metal nitrite solutions from Raman spectral measurements

D. E. Irish、M. H. Brooker1971-01-01Transactions of the Faraday Society

Aqueous solutions of LiNO2, NaNO2, KNO2 and CsNO2 generate only three Raman lines even though extremely high concentrations are attainable. The relative integrated intensities are proportional to concentration and show no specific cation dependence. The frequencies approach those of the corresponding solid. The halfwi…

Solid-state spectroscopy and crystallography

Vibrational spectrum of trimethylsulfonium bromide

J. W. Ypenburg、E. van Der Leij‐Van Wirdum、H. Gerding1971-01-01Recueil des Travaux Chimiques des Pays-Bas

Abstract Trimethylsulfonium bromide (CH 3 ) 3 SBr has been prepared; melting range 183‐186°C. Infrared absorption and Raman spectra have been recorded and assigned.

Inorganic and Organometallic ChemistrySolid-state spectroscopy and crystallographyThermal and Kinetic Analysis

Studies of the charge-transfer complexes of 1,4-naphthoquinone acceptors

Suprabhat Chatterjee1971-01-01Journal of the Chemical Society B Physical Organic

The naphthoquinone acceptors form stable charge-transfer complexes in solutions of aprotic solvents with aromatic hydrocarbons as donors. From the charge-transfer transition energies of the complexes as well as from the polarographic half-wave reduction potentials of the acceptors relative electron affinities of the a…

Nonlinear Optical Materials ResearchPhotochemistry and Electron Transfer StudiesBioactive Compounds and Antitumor Agents

Thermal Stresses of the Elastic Plane with a Circular Hole, Including One Heat Source

Kiyoshi Fukui、Tsuyoshi Fukui、Hiroyoshi KAIBORI1971-01-01Bulletin of JSME

The thermo-elastic solutions for the case of one heat source near a circular hole in an infinite elastic plate are given in the steady-state condition using the thermal expansion displacement for "zero stresses". It is assumed that the temperature along the edge of this hole is held at zero degree always. Numerical ca…

Engineering and Agricultural InnovationsContact Mechanics and Variational InequalitiesStructural mechanics and materials

Polycyclic fluoroaromatic compounds. Part V. Some reactions of 1,2,3,4-tetrafluoronaphthalene

Paul L. Coe、G. M. Pearl、J. C. Tatlow1971-01-01Journal of the Chemical Society C Organic

1,2,3,4-Tetrafluoronaphthalene undergoes nucleophilic and electrophilic substitutions in the fluorocarbon and in the hydrocarbon ring respectively. On treatment with sodium methoxide, hydrazine, and lithium aluminium hydride, the 2-fluorine atom is displaced predominantly. Bromination and nitration yield mixtures of c…

Fluorine in Organic ChemistrySynthesis and properties of polymersSilicone and Siloxane Chemistry

Factors Affecting the Growth Rate of Plasma A nodi zed Al[sub 2]O[sub 3]

John F. O’Hanlon1971-01-01Journal of The Electrochemical Society

This paper discusses the affects of anodization parameters on the growth rate of plasma anodized . Variations in growth rate were inferred by observing the variations in the anodic current decay while anodizing at a constant bias potential. The following effects have been observed: (a) Sputtered cathode oxide was foun…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesAnodic Oxide Films and Nanostructures

Solid-state vibrational spectroscopy. Part II. The vibrational spectra of some chromates and dichromates

J. Eric D. Davies、D. A. Long1971-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

The solid-state (powder) i.r. (1000–40 cm–1) and Raman (1000–130 cm–1) spectra of sodium, potassium, and ammonium chromate(VI) and dichromate(VI) are reported and compared with the previously reported solution Raman spectra. Considerable splittings of the degenerate modes are observed and an attempt is made to account…

Crystal Structures and PropertiesCrystallization and Solubility StudiesX-ray Diffraction in Crystallography

Linear Sweep Voltammetry of Ni(II), Co(II), Cd(II), and Pb(II) at Glassy Carbon Electrodes in Molten Lithium Chloride-Potassium Chloride Eutectic

Wishvender K. Behl1971-01-01Journal of The Electrochemical Society

The reduction of Ni(II), Co(II), Cd(II), and Pb(II) was studied at glassy carbon electrodes in molten lithium chloride‐potassium chloride eutectic at 450°C using the technique of linear sweep voltammetry. Peak‐shaped voltammograms were obtained at scan rates of 10 mV to 1 V / sec . Linear dependence of peak currents o…

Solid-state spectroscopy and crystallographyMolten salt chemistry and electrochemical processes

Infrared and Mössbauer spectra of tetracarbonylcadmioiron and related complexes

A. T. T. Hsieh、M. J. Mays、R. H. Platt1971-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

The i.r. and Mössbauer spetra of CdFe(CO)4 and of several complexes of the type L2MFe(CO)4(M = Zn or Cd; L = nitrogen donor ligand) have been recorded. The Mössbauer spectra indicate the presence of octahedrally co-ordinated iron atoms and, on this basis, possible structures for the complexes are discussed. The comple…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Redetermination of the crystal structure of [NH4]2[SbCl5]

M. Webster、S. Keats1971-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

The structure of the title compound has been redetermined from three-dimensional X-ray data and shown to be in good agreement with the previous study. The structure consists of ammonium ions and approximately square pyramidal [SbCl5]2– ions with antimony–chlorine distances of 2·36, 2·58 (two) and 2·69 (two)Å.

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Oxidative reactions of cellulose initiated by free radicals

Jett C. Arthur、Oscar Hinojosa1971-01-01Journal of Polymer Science Part C Polymer Symposia

Abstract Oxidative reactions in cellulose are commonly initiated by thermal, ultraviolet, and high‐energy radiations and by chemical oxidation. Long‐lived free radicals, formed in cellulose on the localization of energy from thermal, ultraviolet, and high‐energy radiations, and short‐lived free radicals, formed in cel…

Advanced Cellulose Research StudiesEnzyme-mediated dye degradationLignin and Wood Chemistry

Optical Spectrum of Triply Ionized Erbium in Calcium Tungstate

D. E. Wortman1971-01-01The Journal of Chemical Physics

The energy levels of the I4 ground term of Er3+ in single crystals of CaWO4 were established by absorption and fluorescence spectra measurements. The measurements were made using crystals at temperatures of 2, 20, and 85°K. The energy level scheme allows an interpretation of the 1.612-μ four-level CaWO4:Er3+ laser tra…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Predicting storage stability from time-temperature data

W.F. Kwolek、G.N. Bookwalter1971-01-01Food technology

Methods are given to assist in choosing an appropriate equation relating product quality to storage time and temp. and for determining the constants of the equation. Figures prepared from these equations show contours of constant product quality as related to time and temp. From the plotted contours, storage condition…

Crystallization and Solubility StudiesScientific Measurement and Uncertainty EvaluationThermal and Kinetic Analysis

Phase Equilibria in the Sr[sub 3](PO[sub 4])[sub 2]-Cd[sub 3](PO[sub 4])[sub 2] System and Eu2+-Activated Luminescence of Sr[sub 3](PO[sub 4])[sub 2] and Related Phases

James R. Looney、Jesse J. Brown1971-01-01Journal of The Electrochemical Society

The phase equilibria relationships in the Sr 3 ( PO 4 ) 2 ‐ Cd 3 ( PO 4 ) 2 system were established in air using DTA and melting point data obtained from compositions previously equilibrated by solid‐state reactions. In addition to the previously reported rapid, reversible α ⇄ β ‐ Sr 3 ( PO 4 ) 2 polymorphic inversion…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsNuclear materials and radiation effects

Heats of immersion of pure and doped magnesia in cyclohexane. Effects of micropores

R. Sh. Mikhail、S. Νashed、A.M. Khalil1971-01-01Discussions of the Faraday Society

Heats of immersion of pure and doped magnesia in cyclohexane were measured at 35°C for samples heated at different temperatures in vacuo. For the pure samples, rise in temperature of thermal treatment leads to a gradual decrease in the heats of immersion normalized per unit area (h1, ergs cm–2), till a certain limitin…

Mesoporous Materials and CatalysisSolid-state spectroscopy and crystallographyAerogels and thermal insulation

The sign of the 57Fe quadrupole splittings in iron(II) low-spin compounds: partial quadrupole splittings and bonding properties of ligands

G. M. Bancroft、R. E. B. Garrod、A. G. Maddock1971-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

The signs of Vzz(and e2qQ) at the 57Fe nucleus for the following compounds have been measured by use of the Mössbauer magnetic field technique: trans-FeCl2(p-MeO·C6H4·NC)4, trans-FeCl2(depe)2[depe = 1,2-bis(diethylphosphino)ethane]. Na3[Fe(CN)5NH3],H2O, K3[Fe(CN)5H2O],7H2O, all positive; cis-FeCl2(p-MeO·C6H4·NC)4 and…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesMagnetism in coordination complexes

Crystal structure of piperidinium hexathiotetra-arsenate

Editor-Roger Porter、George M. Sheldrick1971-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

Crystals of [C5H12N]+2[As4S6]2– are orthorhombic, space group Imm2, with a= 10·25, b= 19·61, c= 5·97 Å, Z= 2. The anion possesses a ‘basket’ structure in which the four arsenic atoms, and two of the sulphur atoms, lie on crystallographic mirror planes; the bond lengths are: As–As 2·579(12), As–S(terminal) 2·183(10), A…

Crystal structures of chemical compoundsCrystal Structures and PropertiesOrganometallic Compounds Synthesis and Characterization

The substructure of crystalline cellulose and chitin microfibrils

K. H. Gardner、John Blackwell1971-01-01Journal of Polymer Science Part C Polymer Symposia

Abstract The fine structures of the highly crystalline cellulose microfibrils from the cell walls of the marine algae Valonia ventricosa, and the extra cellular chitin spines of the euryhaline diatoms Thalassiosira fluviatilis , have been investigated by observation of deformed and un‐deformed specimens in the electro…

Surface Modification and SuperhydrophobicityAdvanced Cellulose Research StudiesDiatoms and Algae Research