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Solvent effects on polymer surface structure

Jiaxing Chen、Hengzhong Zhuang、Jinshi Zhao 等 4 位作者2001-08-01Surface and Interface Analysis

Abstract The surface modification of polymeric materials has been of great research interest in the last few years because of its importance in applications such as biomaterials and coatings. The bulk composition of polymeric materials often cannot provide the desired surface properties in these applications. For exam…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Dielectric Properties of BaTiO3 Codoped with Er2O3 and MgO

Jin Hyun Hwang、Sang Keun Choi、Young Ho Han2001-08-01Japanese Journal of Applied Physics

The effect of Er 2 O 3 and MgO addition on the dielectric properties of BaTiO 3 ceramics was studied in a reduced atmosphere. MgO effectively prevented the material from being reduced and suppressed grain growth. An X7R material with moderate temperature dependence was developed by the addition of MgO with higher than…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Experimental studies on the B7phase of a banana-shaped achiral mesogen

D. S. Shankar Rao、Geetha G. Nair、S. Krishna Prasad 等 5 位作者2001-08-01Liquid Crystals

We report optical, X-ray, polarization and response time measurements on a new 'bananas-haped' mesogen. The material has a salicylaldimine segment in the linear part of the core, but is otherwise structurally similar to the mesogen first reported to show a banana mesophase. Textural and X-ray studies show that this me…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsPlant Reproductive Biology

DYNAMIC MODELING AND OPERATION OF A SEEDED BATCH COOLING CRYSTALLIZER

Wei Xie、Sohrab Rohani、A. PHOENlX2001-08-01Chemical Engineering Communications

In this study, a dynamic model of a batch cooling crystallizer is developed. The seeded crystallization of potash alum from aqueous solutions. Four different cooling policies namely natural cooling, linear cooling, optimal cooling, and controlled cooling (nonlinear geometric control (NGC) cooling) are presented. The s…

Process Optimization and IntegrationCrystallization and Solubility StudiesFreezing and Crystallization Processes

Design of efficient lightpipes for illumination by an analytical approach

Anurag Gupta、Junwon Lee、R. John Koshel2001-08-01Applied Optics

We present the concept of principal sections of a lightpipe to analyze the propagation of light through the lightpipe by total internal reflection. Only the principal sections determine the acceptance angle and thus help in the identification of regions where the leakage occurs first. Use of principal sections for ana…

Advanced optical system designColor Science and ApplicationsOptical Coatings and Gratings

Sensory Attributes of Whey Protein Isolate and Candelilla Wax Emulsion Edible Films

Su-Jeong Kim、Z. Ustunol2001-08-01Journal of Food Science

ABSTRACT: Whey protein isolate (5% w/v) films were plasticized with sorbitol or glycerol, and candelilla wax (0.8% w/ v) was added to produce whey protein isolate and candelilla wax emulsion edible films. The films were cut into 7.62 cm × 2.54 cm strips and evaluated by a 15‐member trained sensory panel for milk odor,…

Meat and Animal Product QualityNanocomposite Films for Food PackagingFood Chemistry and Fat Analysis

Lattice model for ferroelectric thin film materials including surface effects: Investigation on the “depolarizing” field properties

L. Baudry、Jacques‐Donald Tournier2001-08-01Journal of Applied Physics

Ferroelectric properties of thin film materials like lead zirconate titanate differ from those observed for bulk material. It is well known that the surface can strongly influence phase transition phenomena. By the use of a thermodynamical approach, very similar to those generally used to describe phase transitions, w…

Ferroelectric and Piezoelectric MaterialsMaterial Dynamics and PropertiesSolid-state spectroscopy and crystallography

Mechanical and Biochemical Characterisation of Wheat Gluten Films as a Function of pH and Co-solvent

Betül Ş. Kayserilioğlu、W.M. Stevels、Wim J. Mulder 等 4 位作者2001-08-01Starch - Stärke

Dispersions of wheat gluten were prepared at different pHs (4, 6 and 11) in the presence or absence of ethanol. Films were obtained after casting suspensions followed by evaporation of the solvent. Films prepared at pH 11 were significantly stronger than the films prepared at pH 4 and 6 with tensile strengths of appro…

Nanocomposite Films for Food PackagingPolymer Surface Interaction StudiesSurgical Sutures and Adhesives

DBAli: a database of protein structure alignments

Marc A. Martı́-Renom、Valentin Ilyin、Andrej Šali2001-08-01Bioinformatics

SUMMARY: The DBAli database includes approximately 35000 alignments of pairs of protein structures from SCOP (Lo Conte et al., Nucleic Acids Res., 28, 257-259, 2000) and CE (Shindyalov and Bourne, Protein Eng., 11, 739-747, 1998). DBAli is linked to several resources, including Compare3D (Shindyalov and Bourne, http:/…

Protein Structure and DynamicsChemical Synthesis and AnalysisEnzyme Structure and Function

Formation of Amorphous Carbon and Graphite in CVD Diamond upon Annealing: A HREM, EELS, Raman and Optical Study

L. C. Nistor、Victor Ralchenko、И. И. Власов 等 7 位作者2001-08-01physica status solidi (a)

Polycrystalline diamond thick films were subjected to annealing in vacuum at temperatures of 1350–1450 °C. The films were examined by optical absorption, Raman spectroscopy, transmission electron microscopy and electron energy loss spectroscopy. The formation of amorphous carbon and/or of well-crystallized graphite la…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

HOMSTRAD: adding sequence information to structure-based alignments of homologous protein families

Paul I. W. de Bakker、Alex Bateman、David F. Burke 等 8 位作者2001-08-01Bioinformatics

summary: We describe an extension to the Homologous Structure Alignment Database (HOMSTRAD; Mizuguchi et al., Protein Sci., 7, 2469-2471, 1998a) to include homologous sequences derived from the protein families database Pfam (Bateman et al., Nucleic Acids Res., 28, 263-266, 2000). HOMSTRAD is integrated with the serve…

Genomics and Phylogenetic StudiesProtein Structure and DynamicsEnzyme Structure and Function

Preparation and characterization of polyaniline blends with polyvinyl acetate, polystyrene and polyvinyl chloride for toxic gas sensors

Seyed Hossein Hosseini、Ali Akbar Entezami2001-08-01Polymers for Advanced Technologies

Abstract The conditions of processing and gas sensing of ­polyaniline (PANi) blends with polyvinyl acetate (PVAc), polystyrene (PS) and polyvinyl chloride (PVC) were investigated. Flexible, free‐standing and stretchable films of various blends compositions were obtained by casting. The mechanisms of the conducting ble…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Sintering Behavior and Electrical Properties of Nanosized Doped‐ZnO Powders Produced by Metallorganic Polymeric Processing

P. Durän、F. Capel、J. Tartaj 等 4 位作者2001-08-01Journal of the American Ceramic Society

Homogeneous and nanosized (28 nm crystallite size) doped‐ZnO ceramic powders were obtained by a metallorganic polymeric method. Calcining and granulating resulted in green compacts with uniform powder packing and a narrow pore‐size distribution (pore size 19 nm). Dense ceramic bodies (>99% of theoretical) were fabr…

ZnO doping and propertiesDielectric materials and actuatorsAerogels and thermal insulation

Effects of thickness on the electrical properties of metalorganic chemical vapor deposited Pb(Zr, Ti)O3 (25–100 nm) thin films on LaNiO3 buffered Si

Chien-Cheng Lin、Philip A. Friddle、C. H. Ma 等 5 位作者2001-08-01Journal of Applied Physics

Pb(Zr, Ti)O 3 (PZT) thin films with (100) preferred orientation were prepared using metalorganic chemical vapor deposition on LaNiO3 (LNO) buffered platinized Si with thickness varying from 25–100 nm. The dependence of electrical properties of PZT films on thickness was studied using several techniques, including pola…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

Quantitative AES IX and quantitative XPS II: Auger and x‐ray photoelectron intensities and sensitivity factors from spectral digital databases reanalysed using a REELS database

M. P. Seah、Ian S. Gilmore、Steven J. Spencer2001-08-01Surface and Interface Analysis

Abstract An extension has been made of previous analyses of peak area intensities for elemental spectra in digital Auger and x‐ray photoelectron databases. The intensities, instead of being analysed after removal of a background derived from the Tougaard Universal cross‐section, are now analysed after removal of the e…

Advancements in Photolithography TechniquesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Synthesis and Excited-State Photodynamics in Perylene-Porphyrin Dyads 2. Effects of Porphyrin Metalation State on the Energy-Transfer, Charge-Transfer, and Deactivation Channels

Sung Ik Yang、Sreedharan Prathapan、Mark A. Miller 等 7 位作者2001-08-01The Journal of Physical Chemistry B

The photophysical properties of two perylene−porphyrin dyads have been examined in detail with the aim of expanding the functional utility of these constructs for molecular optoelectronics applications. The dyads consist of a perylene-bis(imide) dye (PDI) connected to either a magnesium porphyrin (Mg) or a free base p…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

Synthesis of a Novel Optically Tunable Amphiphilic Poly(p-phenylene): Influence of Hydrogen Bonding and Metal Complexation on Optical Properties

Chinnappan Baskar、Yee‐Hing Lai、Suresh Valiyaveettil2001-08-01Macromolecules

A series of optically tunable amphiphilic conjugated polymers, poly(2-hydroxy-5-alkoxy- p -phenylene) ( 1 ) containing long alkyl chains, were prepared by Suzuki polycondensation using 2,5-dibromo-1-benzyloxy-4-alkoxybenzene and bis(boronic ester) monomers. All polymers showed good solubility in common organic solvent…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsLuminescence and Fluorescent Materials

Physicochemical and Biological Evaluation of P792, a Rapid-Clearance Blood-Pool Agent for Magnetic Resonance Imaging

Marc Port、Claire Corot、Isabelle Raynal 等 9 位作者2001-08-01Investigative Radiology

RATIONALE AND OBJECTIVES: To summarize the physicochemical characterization, pharmacokinetic behavior, and biological evaluation of P792, a new monogadolinated MRI blood-pool agent. METHODS: The molecular modeling of P792 was described. The r1 relaxivity properties of P792 were measured in water and 4% human serum alb…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Toughening of Brittle Materials by Dislocation Cells

H. Saka、W-J Moon、Shin Horiuchi 等 4 位作者2001-08-01Microscopy and Microanalysis

Abstract Many attempts have been made to improve the fracture toughness of brittle materials such as ceramics. Most of the methods developed so far make use of metallurgical processes, for example, phase transformation, refining of grains, formation of composite materials. However, these methods can not be applied uni…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Pressure Raman spectra of LiK0.8(NH4)0.2SO4

Alexandre Magno Rodrigues Teixeira、Paulo Freire、J. M. Sasaki 等 6 位作者2001-08-01Journal of Raman Spectroscopy

Abstract Raman spectra of LiK 0.8 (NH 4 ) 0.2 SO 4 were obtained as a function of applied pressure. The measurements were carried out using a microscope to focus the light into a spot size of 2 µm, in order to avoid probing a multi‐domain sample. With increasing pressure, many of the Raman peaks are shifted towards hi…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography