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The Measurement of Surface Charge

Cornelis W. Reedyk、Martin M. Perlman1968-01-01Journal of The Electrochemical Society

A new method of measuring the charge density on a dielectric surface has been developed. An electrode is vibrated in the surface field to produce a signal that is displayed on an oscilloscope, or measured with a VTVM. A bias is then applied across the vibrating and fixed electrodes sufficient to produce zero output si…

High voltage insulation and dielectric phenomena

The Nucleation, Growth, and Structure of Thin Ni-P Films

J. Márton、M. Schlesinger1968-01-01Journal of The Electrochemical Society

The nucleation, early growth, and structure of Ni‐P on SnCl 2 ‐ PdCl 2 activated dielectric substrates were studied. The SnCl 2 ‐ PdCl 2 treatment was found to provide small catalytic sites on the substrate, serving as the nuclei for Ni‐P growth. The average diameter of catalytic sites was estimated to be less than 10…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

cis-Dioxo- and trioxo-complexes

William P. Griffith、T. D. Wickins1968-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

Raman and infrared spectra have been measured of a number of transition-metal complexes of the form [MO2X4]n–(M = MoVI, WVI, or VV; X = F, Cl, or ½ Ox), and a cis configuration of the oxygen ligands has been found for these d0-species. The results are compared with those obtained for trans-dioxo-complexes and the díff…

Magnetism in coordination complexesPolyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation Reactions

Metastable Immiscibility in the B2O3–SiO2 System

R. J. Charles、F. E. Wagstaff1968-01-01Journal of the American Ceramic Society

Using the phase diagram and a simple solution model, a subliquidus miscibility gap was estimated for the B 2 O 3 ‐SiO 2 system. The predicted coexistence boundary, showing a consolute temperature of 520°C, was flat and symmetrical and extended across the complete binary. Gradient furnace heat treatments of selected co…

Advanced ceramic materials synthesisSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics

Characterization of Chloramphenicol Acetyltransferase from Chloramphenicol-resistant Staphylococcus aureus

William V. Shaw、R. F. Brodsky1968-01-01Journal of Bacteriology

Chloramphenicol-resistant strains of Staphylococcus aureus contain an inducible enzyme which inactivates chloramphenicol by acetylation in the presence of acetyl coenzyme A. The products of acetylation are chromatographically indistinguishable from those obtained with chloramphenicol-resistant Escherichia coli harbori…

Bacterial Genetics and BiotechnologyRNA and protein synthesis mechanismsEnzyme Structure and Function

ESR Studies of Cupric Ion in Various Oxide Glasses

Hiroshi Imagawa1968-01-01physica status solidi (b)

Abstract ESR spectra of cupric ions in borate, silicate, and phosphate glasses were analyzed by the LCAO MO method of Maki and McGarvey. The covalency of the B 2g π‐orbital was found to change with the bond strength of the network‐former. Particularly it reflected clearly the weakening of BO bonds in alkali borate gl…

Glass properties and applicationsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

A Study of Radiation Effects on SiO2 and Al2O3 Layers Using Thermoluminescence Glow Curve Techniques

J.P. Mitchell1968-01-01IEEE Transactions on Nuclear Science

Trap levels in thin layers (500 to 6000Å) of Al2O3 and various types of SiO2, all on Si substrates, were investigated using thermoluminescence glow curves in a temperature range from 30° to 300°C. Layers were studied which had been exposed to doses of Co60-gamma radiation up to several Mrads. Previously unirradiated S…

Luminescence Properties of Advanced MaterialsGaN-based semiconductor devices and materialsRadiation Detection and Scintillator Technologies

The Low‐Temperature Thermoelectric Power and Thermal Conductivity of GeTe and of Some GeTe‐MnTe Alloys

John E. Lewis、H. Rodot、P. Haen1968-01-01physica status solidi (b)

Abstract A method of preparation has been developed which allows the growth of large homogeneous single phase ingots of such alloy systems as GeTe‐MnTe, GeTe‐SnTe, etc. … We have measured the thermoelectric power and the thermal conductivity of both GeTe and two alloys of the system Ge 1− x Mn x Te, in the temperature…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Copper and Copper Alloys

Einar Mattsson、Rolf Holm1968-01-01OpenAlex

In 1958 exposure tests were started in Sweden to gain knowledge of the natural patination and the corrosion behavior of copper and copper alloys when used outdoors. The investigation covered 36 alloys in sheet or rod form: 5 coppers, 20 brasses, 5 phosphor bronzes, 1 silicon bronze, 1 aluminum bronze, 1 cadmium bronze…

Materials Engineering and ProcessingMetallurgy and Material Science

Stacking Faults on {110} Planes in the B.C.C. Lattice

B. Pegel1968-01-01physica status solidi (b)

Abstract Maximum stacking fault energies for α‐type stacking faults in the b.c.c. lattice are estimated for the group Va and VIa transition metals and iron. The half widths of glissile type split screw dislocations should be in all cases at least one total Burgers vector.

Microstructure and mechanical propertiesTitanium Alloys Microstructure and PropertiesAdvanced materials and composites

Complex halides of the transition metals. Part III. Electronic spectra and ligand field parameters of octahedral and tetrahedral halogeno-complexes of manganese(II)

John James Foster、Naida S. Gill1968-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

The electronic spectra of a number of compounds of manganese(II) in which the metal is surrounded by an octahedral arrangement of halogen atoms have been analysed, and values for the Racah parameters, B and C, and the ligand-field parameters, Δ, calculated. The compounds include MnX2(X = F, Cl, Br, I), (MeNH3)2MnCl4,…

Crystal structures of chemical compoundsLanthanide and Transition Metal ComplexesInorganic and Organometallic Chemistry

Magnetic Properties of ZrFe2 and TiFe2 within Their Homogeneity Range

W. Brückner、R. Perthel、K. Kleinstück 等 4 位作者1968-01-01physica status solidi (b)

Abstract The magnetic properties of TiFe 2 and ZrFe 2 are investigated within their homogeneity range in dependence on the concentration. TiFe 2 is antiferromagnetic at titanium excess and at stoichiometric composition and it is ferromagnetic at iron excess. ZrFe 2 is ferromagnetic throughout the whole homogeneity ran…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

ZnO field-effect transistor

G.F. Boesen、John E. Jacobs1968-01-01Proceedings of the IEEE

Fabrication of experimental insulated-gate field-effect transistors on single crystal ZnO is described. Measured transconductance of 10 µmhos is two orders of magnitude smaller than that predicted for this structure by the Hall mobility of 220 cm2/V ċ s. Threshold voltage indicates relatively large values of surface s…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesQuantum and electron transport phenomena

FINITE ELEMENT ANALYSES OF PAVEMENTS

Julie Duncan、C L Monismith、Edward L. Wilson1968-01-01Highway Research Record

AN APPLICATION IS DESCRIBED OF THE FINITE ELEMENT TECHNIQUE TO THE ANALYSIS OF SYSTEMS REPRESENTATIVE OF PAVEMENT STRUCTURES. USE IS MADE OF A DIGITAL COMPUTER PROGRAM WHICH GENERATES SUITABLE FINITE ELEMENT CONFIGURATIONS FOR AXISYMMETRIC STRUCTURES AND ACCOMMODATES APPROXIMATIONS OF NONLINEARITY WHICH APPEAR APPROPR…

Industrial Engineering and TechnologiesMaterial Properties and Applications

Thermal degradation of polycarbonate

A. Davis、J. H. Golden1968-01-01Journal of the Chemical Society B Physical Organic

A comparison is drawn between the thermal behaviour of poly-[2,2-propane-bis-(4-phenyl carbonate)] and the model compound diphenyl carbonate. On this basis a rearrangement mechanism is suggested to account for the main chemical and physical features of the degradation of the polymer between 300 and 389°.

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Spectra of Some Rare Earth Vanadates

R.C. Ropp1968-01-01Journal of The Electrochemical Society

Spectra of some rare earth activated phosphors, where may be Y, Gd, or La, are presented. The most efficient phosphors, particularly in the matrix, are those activated by Sm +3 , Eu +3 , and Dy +3 . It is shown that has an output efficiency comparable to commercial phosphors. , when properly prepared, has an output in…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesCatalysis and Oxidation Reactions

Thermal dissociation of Ca(OH)2 at elevated pressures

J. A. C. Samms、B. E. Evans1968-01-01Journal of Applied Chemistry

Abstract The equilibrium Ca(OH) 2 ⇌ CaO+H 2 O has been studied at pressures of steam up to 50 bars and at temperatures of up to 800° C. The dissociation pressures determined are in agreement with the data derived by some previous workers at pressures of less than one bar but they conflict with data published for highe…

Metallurgical Processes and ThermodynamicsCombustion and Detonation ProcessesThermal and Kinetic Analysis

Determination of Vapor-Liquid Equilibrium from Boiling Point Curve

Kazuo Kojima、Katsumi Tochigi、Haruo Seki 等 4 位作者1968-01-01Chemical engineering

沸点曲線にもとずく気液平衡の決定を検討するために沸点計を作製し, メタノールー水系.エタノールー水系, ノープロパノールー水系, i-プロバノールー水系. アセトンー水系, メタノールーループロバノール系の760mmHgにおける沸点を実測した。Taoの式を基礎式として気液平衡を決定したところ. 計算値と文献値は良好な精度で一致した. 沸点測定は比較的簡単であり, また正確に行ないうるので気液平衡実測値の検討にも役立つものと思う.

Crystallization and Solubility StudiesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

The Measurement of Ionic Mobilities in the Anodic Oxides of Tantalum and Zirconium by a Precision Sectioning Technique

J. L. Whitton1968-01-01Journal of The Electrochemical Society

The technique of removing thin sections of anodic oxides by vibratory polishing has been used in conjunction with implantation of anion, cation, and inert gas radiotracers to measure the mode of anodic oxide formation on Zr and Ta. The measured transport number for metal during the growth of (0.28) is in good agreemen…

Hydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Cathodic Reduction Mechanism of MnOOH to Mn(OH)[sub 2] in Alkaline Electrolyte

Akiya Kozawa、J. F. Yeager1968-01-01Journal of The Electrochemical Society

The cathodic reduction process of MnOOH , which is produced from γ ‐ MnO 2 or β ‐ MnO 2 by electrochemical reduction, was studied in 9 M KOH with various particle sizes of the original γ ‐ MnO 2 and various depths of discharge. The polarization of MnOOH produced from electrolytic γ ‐ MnO 2 is small, less than 60 mv, u…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationElectrochemical Analysis and Applications