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Tubular Conjugated Polymer for Chemosensory Applications

Anat Molad、Israel Goldberg、Arkadi Vigalok2012-04-23Journal of the American Chemical Society

In this paper, we present the concept of a soluble tubular conjugated polymer (TCP). We report on a fluorescent 5,5'-Bicalixarene-based polymer where the calixarene units are seamlessly incorporated in the conjugated polymeric chain that can respond to a small molecule complexation inside the hydrophobic cavity. In pa…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Synthesis, Characterization, and Optical Properties of 4H-Pyran-4-ylidene Donor-Based Chromophores: The Relevance of the Location of a Thiophene Ring in the Spacer

Natalia Martínez de Baroja、Javier Garı́n、J. Orduna 等 8 位作者2012-04-23The Journal of Organic Chemistry

A series of new 4H-pyran-4-ylidene donor-based chromophores with a thiophene ring in the spacer has been synthesized. The linear and nonlinear optical (NLO) properties of these compounds have been determined and compared with the results of computational calculations. The position of the thiophene ring proved essentia…

Nonlinear Optical Materials ResearchSynthesis and Properties of Aromatic CompoundsChemical synthesis and pharmacological studies

Large-area nanostructured substrates for surface enhanced Raman spectroscopy

Andriy Shevchenko、Victor Ovchinnikov、Anna Shevchenko2012-04-23Applied Physics Letters

We demonstrate substantial enhancement of Raman transitions of organic molecules by nanostructured gold-coated substrates at the excitation wavelength of 785 nm and experimentally study the factors that influence the enhancement. The substrates are fabricated by using a robust and cost-effective nanopatterning techniq…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchBiosensors and Analytical Detection

Influence of work-function of top electrodes on the photovoltaic characteristics of Pb0.95La0.05Zr0.54Ti0.46O3 thin film capacitors

V. N. Harshan、Sushma Kotru2012-04-23Applied Physics Letters

Photovoltaic properties of Pb0.95La0.05Zr0.54Ti0.46O3 thin film capacitors prepared using solution based method with metal top electrodes having different work functions are investigated in this work. It is shown that by using aluminum, a low work-function metal, as top electrode, the magnitude of photo voltage as wel…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Planar PbS quantum dot/C60 heterojunction photovoltaic devices with 5.2% power conversion efficiency

Ethan J. D. Klem、Chris Gregory、G. Cunningham 等 6 位作者2012-04-23Applied Physics Letters

Of interest for both photovoltaic and photodetector applications is the ability of colloidal quantum dot (CQD) devices to provide response further into the infrared than is typical for other solution-processable materials. Here, we present a simple heterojunction diode structure that utilizes the extended infrared abs…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsMolecular Junctions and Nanostructures

Investigation on flame retardancy and thermal degradation of flame retardant poly(butylene succinate)/bamboo fiber biocomposites

Shibin Nie、Xueli Liu、Guanglong Dai 等 7 位作者2012-04-23Journal of Applied Polymer Science

Abstract Poly(butylene succinate)/bamboo fiber (BBF) biocomposites were prepared by melt blending method. Microencapsulated ammonium polyphosphate (MCAPP) was used as flame retardants to prepare flame retardant BBF biocomposites. The thermal degradation and flame retardant properties of BBF biocomposites were investig…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesFlame retardant materials and properties

Thermal stability of magnetoelectric sensors

Ying Shen、Junqi Gao、Yaojin Wang 等 5 位作者2012-04-23Applied Physics Letters

The effect of temperature on the equivalent magnetic noise floor of Metglas-Pb(Zr,Ti)O3 (PZT) laminate magnetoelectric (ME) sensors has been investigated in the temperature range of −50 °C to 50 °C. In detail, the parameters that control the noise floor of ME sensors, such as capacitance, tan δ, and ME charge coeffici…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Spatial displacement correlations in polymeric systems

F. Puosi、D. Leporini2012-04-23The Journal of Chemical Physics

The spatial correlations of the monomer displacements are studied via molecular-dynamics simulations of a melt of fully flexible, unentangled polymer chains with different length, interacting potential, density, and temperature. Both the scalar and the vector characters of the correlations are considered and their ext…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesNMR spectroscopy and applications

Interface state density distribution in Au/n-ZnO nanorods Schottky diodes

Sadia Muniza Faraz、M. Willander、Q. Wahab2012-04-23IOP Conference Series Materials Science and Engineering

Interface states density (N SS ) distribution is extracted in Au/ ZnO Schottky diodes. Nanorods of ZnO are grown on silver (Ag) using aqueous chemical growth (ACG) technique. Well aligned hexagonal–shaped vertical nanorods of a mean diameter of 300 - 450 nm and 1.3 -1.9 μm high are revealed in SEM. Gold (Au) Schottky…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsSemiconductor materials and interfaces

Metal-insulator transition with multiple micro-scaled avalanches in VO2 thin film on TiO2(001) substrates

Kenichi Kawatani、Hidefumi Takami、Teruo Kanki 等 4 位作者2012-04-23Applied Physics Letters

We observed micro-scale phase separation in VO2 thin films on TiO2(001) substrates and investigated the relationship between the appearance of metallic domains and the abrupt resistive changes around the phase transition. The resistive changes are interpreted using a combined resistance model of the two phases, and th…

Gas Sensing Nanomaterials and SensorsAdvanced Memory and Neural ComputingTransition Metal Oxide Nanomaterials

Thermal stability and flammability of banana‐fiber‐reinforced polypropylene nanocomposites

Manoranjan Biswal、Smita Mohanty、Sanjay K. Nayak2012-04-23Journal of Applied Polymer Science

Abstract Banana‐fiber‐reinforced polypropylene nanocomposites were prepared with a melt‐blending technique followed by compression molding. The thermal stability and fire retardancy of the fiber‐reinforced nanocomposites was studied as a function of the variable weight percentages of fibers and nanoclays with both the…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesFlame retardant materials and properties

Effect of the Strain Rate and Drawing Temperature on the Mechanical Behavior of EVOH and EVOH Composites

Edgar Adrián Franco Urquiza、José Gámez‐Pérez、Julio Cesar Velázquez Infante 等 6 位作者2012-04-23Advances in Polymer Technology

Abstract The effect of the strain rate and draw temperature on the mechanical behavior of ethylene vinyl alcohol (EVOH) and EVOH composites was analyzed. When EVOH is stretched at moderate strain rates, evidence of strain‐induced crystallization and recrystallization was observed. Higher strain rates produced less str…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesDielectric materials and actuators

Effect of a TiO 2 Nucleating Agent on the Nucleation and Crystallization Behavior of MgO – B 2 O 3 – SiO 2 Glass

Marjeta Maček Kržmanc、Urban Došler、Danilo Suvorov2012-04-23Journal of the American Ceramic Society

The nucleation and crystallization of MgO – B 2 O 3 – SiO 2 ( MBS ) glasses with various TiO 2 additions (0–15 wt%) were studied by means of a nonisothermal, thermal analysis technique, X ‐ray diffraction, and electron microscopy. The effect of the TiO 2 on the nucleation rate was determined from the dependence of the…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisGlass properties and applications

Plasma-Enabled Growth of Single-Crystalline SiC/AlSiC Core–Shell Nanowires on Porous Alumina Templates

Jinghua Fang、Igor Aharonovich、Igor Levchenko 等 7 位作者2012-04-23Crystal Growth & Design

We report the catalyst-free synthesis of the arrays of core–shell, ultrathin, size-uniform SiC/AlSiC nanowires on the top of a periodic anodic aluminum oxide template. The nanowires were grown using an environmentally friendly, silane-free process by exposing the silicon supported porous alumina template to CH 4 + H 2…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceAnodic Oxide Films and Nanostructures

Evolution of the Morphologies of Zinc Oxide Mesocrystals Under the Influence of Natural Polysaccharides

Florian Waltz、Gesa Wißmann、Jann Lippke 等 8 位作者2012-04-23Crystal Growth & Design

In the present investigation, we have analyzed the influence of naturally occurring negatively charged polysaccharides on the morphology of zinc oxide obtained in low-temperature precipitation experiments. Performing detailed analyses of scanning electron microscopy (SEM) micrographs, we inferred the morphology of ind…

ZnO doping and propertiesPolymer Surface Interaction StudiesCalcium Carbonate Crystallization and Inhibition

Behavior of Thermoset Shape Memory Polymer-Based Syntactic Foam Sealant Trained by Hybrid Two-Stage Programming

Guoqiang Li、Abe King、Tao Xu 等 4 位作者2012-04-23Journal of Materials in Civil Engineering

Recently, a shape memory polymer-based self-healing syntactic foam was proposed and tested as a sealant for expansion joints. The key for success is to train the foam by using a two-dimensional (2D) stress condition (compression in the horizontal or traffic direction and tension in the vertical direction) at a tempera…

Polymer composites and self-healingSynthetic Organic Chemistry MethodsSilicone and Siloxane Chemistry

Selective Enhancement of Photoluminescence in Filled Single‐Walled Carbon Nanotubes

Xianjie Liu、H. Kuzmany、Paola Ayala 等 6 位作者2012-04-23Advanced Functional Materials

Abstract The insertion of organometallic molecules into the hollow core of single‐walled carbon nanotubes can drastically change their properties. Using biocompatible standardized suspensions of pristine, opened, and filled nanotubes, a very selective enhancement of the photoluminescence and optical absorption is obse…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

A review of fire blocking technologies for soft furnishings

Shonali Nazaré、Rick D. Davis2012-04-23Fire Science Reviews

Abstract Fire barrier fabrics are expected to play an increasingly important role in complying with existing and proposed soft furnishing flammability regulations in the US. The number of commercial fire blocking technologies is large in order to accommodate the vast requirements of the consumers, manufacturers, and r…

Fire dynamics and safety researchFlame retardant materials and propertiesFiber-reinforced polymer composites

Nano-sized cationic polymeric magnetic liposomes significantly improves drug delivery to the brain in rats

Ming Zhao、Jin Chang、Xiangping Fu 等 7 位作者2012-04-23Journal of drug targeting

In recent years, cationic polymeric magnetic liposomes have shown greater stability and prolonged circulation half-life over traditional liposomes. Here, we examined the capability of cationic polymeric magnetic liposomes in delivering drugs into the brain under magnetic targeting with paclitaxel as the loaded agent.…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryCharacterization and Applications of Magnetic Nanoparticles

Deaging and Asymmetric Energy Landscapes in Electrically Biased Ferroelectrics

Goknur Tutuncu、Dragan Damjanović、Jun Chen 等 4 位作者2012-04-23Physical Review Letters

In ferroic materials, the dielectric, piezoelectric, magnetic, and elastic coefficients are significantly affected by the motion of domain walls. This motion can be described as the propagation of a wall across various types and strengths of pinning centers that collectively constitute a force profile or energetic lan…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies