Materials Literature
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Hydrophobized plant polyphenols can be easily prepared by rational and controlled etherification of highly abundant aromatic hydroxyls with linear alkyl chains. The resultant organo-soluble polyphenols spontaneously formed fibrous structures and unravelled to be potential adhesive, anticorrosion, and antibacterial coa…
The recently discovered twist-bend nematic phase of achiral bent-shaped molecules, NTB, has a doubly degenerate ground-state with a periodically modulated heliconical structure and unusual distortion elasticity, the theoretical description of which is still debated. We show that the NTB phase has the same macroscopic…
Abstract Active food packaging films based on chitosan and honeysuckle flower extract ( HFE ) were developed. The effects of the HFE incorporation at different levels on physical and mechanical properties (density, moisture content, opacity, color, water solubility, water vapor permeability, tensile strength and elong…
Metal oxide nanoparticles supported on graphene exhibit high catalytic activity for oxidation, reduction and coupling reactions. Here we show that pyrolysis at 900 °C under inert atmosphere of copper(II) nitrate embedded in chitosan films affords 1.1.1 facet-oriented copper nanoplatelets supported on few-layered graph…
Shape-controlled synthesis of uniform noble metal nanoparticles (NPs) is crucial for the development of future plasmonic devices. The use of nanocrystals with well-defined morphologies and crystallinity as seed particles is expected to provide excellent shape control and monodispersity. We report the aqueous-based see…
Nanomedicine aims to find novel solutions for urgent biomedical needs. Despite this, one of the most challenging hurdles that nanomedicine faces is to successfully target therapeutic nanoparticles to cells of interest in vivo. As for any biomaterials, once in vivo, nanoparticles can interact with plasma biomolecules,…
Zn2Al/-layered double hydroxide (LDH) with intercalated MoO4(2-) was investigated as a potential source of soluble molybdate inhibitor in anticorrosion coatings for hot dip galvanized steel (HDG). The effect of solution pH, soluble chlorides, and carbonates on the release kinetics of the interleaved MoO4(2-) ions from…
ABSTRACT Multiwall carbon nanotubes (MWCNTs) reinforced composites for electromagnetic (EM) absorption are reviewed. Here, four types of nanostructured radar absorbing materials (RAMs) were discussed including MWCNTs polymer composites, magnetic nanostructures decorated MWCNTs polymer composites, nonmagnetic nanostruc…
The results of spin-polarized density functional theory calculations find that band gap engineering can be achieved by site-specific interactions in a composite consisting of polyaniline and TiO2 nanoparticles. Interactions in the composite matrix are found to be mediated by Ti atoms inducing dependency of location of…
Recent radio frequency scanning tunneling spectroscopy (rf-STS) experiments have demonstrated nuclear and electron spin excitations up to $\pm12\hbar$ in a single molecular spin quantum dot (qudot). Despite the profound experimental evidence, the observed independence of the well-established dipole selection rules is…
The search for new quantum spin Hall (QSH) phase and effective manipulations of their edge states are very important for both fundamental sciences and practical applications. Here, we use first-principles calculations to study the strain-driven topological phase transition of two-dimensional (2D) arsenene monolayer. W…
Ultrasound velocity measurements were performed on a single crystal of spin-frustrated ferrite spinel ZnFe$_2$O$_4$ from 300 K down to 2 K. In this cubic crystal, all the symmetrically-independent elastic moduli exhibit softening with a characteristic minimum with decreasing temperature below $\sim$100 K. This elastic…
The wave function of Dirac fermions is a two-component spinor. In graphene, a one-atom-thick film showing two-dimensional Dirac-like electronic excitations, the two-component representation, reflects the amplitude of the electron wave function on the $A$ and $B$ sublattices. This unique property provides unprecedented…
Our purpose is to study role of ionic radii of non-magnetic dopants; Li+ (0.68 Å), Mg2+ (0.72 Å) and K+ (1.38 Å) on the magnetic property of rutile TiO2 compound. The Ti0.94A0.06O2 (A=Li, Mg, K) compounds have been synthesized via solid state route method at equilibrium. The structural analyses of X-ray diffraction pa…
We use time- and angle-resolved photoemission to measure quasiparticle relaxation dynamics across a laser-induced superconducting phase transition in Bi2Sr2CaCu2O8+delta. Whereas low-fluence measurements reveal picosecond dynamics, sharp femtosecond dynamics emerge at higher fluence. Analyses of data as a function of…
We have studied the magnetic layer thickness dependence of the orbital magnetic moment in magnetic heterostructures to identify contributions from interfaces. Three different heterostructures, Ta/CoFeB/MgO, Pt/Co/AlO$_x$ and Pt/Co/Pt, which possess significant interface contribution to the perpendicular magnetic aniso…
Understanding the metal-insulator transition in disordered many-fermion systems, both with and without interactions, is one of the most challenging and consequential problems in condensed matter physics. In this paper we address this issue from the perspective of the modern theory of the insulating state (MTIS), which…
The saga of the primary photoexcitations in $π$-conjugated polymers has been a source of extraordinary scientific curiosity that has lasted for more than three decades. From soliton excitations in trans-polyacetylene, to singlet and triplet excitons and polarons in other polymers, to charge transfer excitons in blends…
Using classical equilibrium molecular dynamics simulations and applying the original Tersoff interatomic potential, we study the thermal transport property of the latest two dimensional carbon allotrope, penta-graphene. It is predicted that its room-temperature thermal conductivity is about 167 W/mK, which is much low…
Graphitic ( g )-C x N y H z has become a popular element in photocatalytic water splitting cells. Recently, the crystal structures of completely polymerized g -C 3 N 4 and incompletely polymerized g -C 6 N 9 H 3 crystals based on the triazine and heptazine monomers have been characterized. In this manuscript we evalua…