681. Studies in co-ordination chemistry. Part XIII. Magnetic moments and bond types of transition-metal complexes
F. H. Burstall and R. S. Nyholm, J. Chem. Soc., 1952, 3570 DOI: 10.1039/JR9520003570
Materials Literature
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F. H. Burstall and R. S. Nyholm, J. Chem. Soc., 1952, 3570 DOI: 10.1039/JR9520003570
New experiments of Molenaar and Aarts, Blewitt and others seem to confirm the view of the author, previously based only on the experiments of Gyulai and Hartly and Stepanow on sodium chloride, that vacant lattice sites, and possibly interstitial atoms, are generated during plastic flow in ductile crystals, particularl…
The discontinuous phenomena in plasticity of metals, such as the yielding, the state of ultimate strength and the brittle fracture, were regarded as a kind of Markoff process, and studied from the standpoint of nucleation theory. The fundamental features of these types of failures, namely, (1) the relation between str…
We consider a volume of material, divided into two regions 1 and 2. each of density ρ, by a moving surface S. On S a change of phase occurs, at a definite temperature (which we may take to be zero) and with absorption or liberation of a latent heat L per unit mass. If θ l , k l , K 1 are the temperature, thermal condu…
With d.c. electrical resistivities several orders of magnitude greater than those of the ferromagnetic metals, and magnetic saturation intensities in some cases less than one order of magnitude smaller, the ferrites gave promise of greater `effective permeability' and lower `eddy-current' loss in high-frequency magnet…
The specific heat and thermal expansion of high purity BaTiO 3 ceramics have been measured at temperatures from -120° to 150°C with the following results:
The phase transition and the crystal structures of cuprous iodide (CuI) have been studied by the X-ray and calorimetric measurement Two phase transitions at 369°C and 407°C were found and the corresponding energy and entropy changes were estimated from the specific heattemperature curve. The crystal lattice of γ, β an…
R. P. Linstead and M. Whalley, J. Chem. Soc., 1952, 4839 DOI: 10.1039/JR9520004839
The phase diagram of the whole range of the PbZrO 3 -PbTiO 3 system was determined by the dielectric and dilatometric measurements. According to the reason shown in part I, this phase diagram can be divided into three regiors; paraelectric, ferroelectric and antiferroelectric phases. The crystal structure of this syst…
D. H. Everett and W. I. Whitton, Trans. Faraday Soc., 1952, 48, 749 DOI: 10.1039/TF9524800749
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