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Using the dusty gas diffusion equation in catalyst pores smaller than 50 Å radius

Hirokazu Omata、Lee F. Brown1972-09-01AIChE Journal

Abstract When the dusty gas diffusion equation is applied to materials containing pores with radii below 50 Å, the observed diffusion behavior in these smaller pore systems can be quite different from that predicted by the equation. Higher temperatures and in some cases higher pressures tend to lessen the deviations b…

Catalytic Processes in Materials ScienceGas Dynamics and Kinetic TheoryCatalysis and Oxidation Reactions

Electrical Breakdown and the Similarity Law in SF6 at Extra-High-Voltages

I. M. Bortnik、C. M. Cooke1972-09-01IEEE Transactions on Power Apparatus and Systems

The DC electrical breakdown of SF6 gas at extra-high- voltages was studied experimentally in coaxial systems of moderate size. The results were compared to a similarity relationship of electric stress for breakdown based on ionization of the gas. For laboratory-clean systems, theory and experiment agree when the macro…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationNon-Destructive Testing Techniques

The self heating of commercial powdered activated carbons

Angus E. Cameron、J. D. Macdowall1972-09-01Journal of Applied Chemistry and Biotechnology

Abstract The self heating characteristics of a series of activated carbon samples have been studied in relation to their chemical/physical properties. It appears that ease of self heating is related to the oxygen content of the carbon on a dry ash free basis, and from this it can be shown that all carbons manufactured…

Thermal and Kinetic Analysis

Umströmung kugelförmiger Blasen mit innerer Zirkulation

Udo Haas、H. Schmidt‐Traub、Heinz Brauer1972-09-01Chemie Ingenieur Technik

Abstract Die Umströmung von einzelnen Kugelblasen mit innerer Zirkulation wurde theoretisch untersucht. Die Differentialgleichungen, die das Geschwindigkeits‐ und Druckfeld in der Umgebung der Blase beschreiben, berücksichtigen die vollständigen Trägheitsglieder. Die Rechnungen haben ergeben, daszlig; sich die Strömun…

Surface Modification and SuperhydrophobicityPlant Surface Properties and TreatmentsPhysics and Engineering Research Articles

Spin Fluctuations of Fe3+ Ions in Cobalt–Zinc Ferrites Using the Mössbauer Effect

S. C. Bhargava、P.K. Iyengar1972-09-01physica status solidi (b)

Abstract Resonance absorption spectra of Fe 57 in Co x Zn 1− x Fe 2 O 4 (for x = 0.3, 0.5, and 0.75), in the temperature range from 80 to 700 °K, are discussed. The modulated lineshapes of the magnetic hyperfine spectra show features which are characteristic of relaxation effects. The theoretical line shapes, computed…

Magnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsMagneto-Optical Properties and Applications

Influence of structural effects of halogen and phosphorus polyol mixtures on flame retardancy of flexible polyurethane foams

Anthony J. Papa、William R. Proops1972-09-01Journal of Applied Polymer Science

Abstract The role of mixtures of reactive bromine and phosphorus flame‐retardant polyol intermediates as well as the individual bromine and phosphorus reagents in suppressing combustion of flexible polyurethane foams was investigated by means of the oxygen index flame test and charring techniques. Bromine alone appear…

Fire dynamics and safety researchFlame retardant materials and propertiesEnvironmental and Industrial Safety

Microfibers within fibers: A review

Paul A. Tucker、Waller George1972-09-01Polymer Engineering and Science

Abstract Literature relating to the fundamental nature of the fibrous state is reviewed with the goal of illustrating evidence for the existence of a possibly fundamental morphological unit, the elemental microfiber or fibril. Following a short summary of the rather well documented situation in natural fibers, the pro…

Natural Fiber Reinforced CompositesTextile materials and evaluationsFiber-reinforced polymer composites

A review of microwave relaxation in polycrystalline ferrites

Carl E. Patton1972-09-01IEEE Transactions on Magnetics

The microwave losses in polycrystalline ferrites can be separated into two parts: those associated with resonance (inhomogeneous linebroadening and two magnon processes) and intrinsic losses. In recent years, both types have been studied in great detail. The near-resonance relaxation can be quantitatively explained by…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsSemiconductor materials and interfaces

Stress Generation and Adhesion in Growing Oxide Scales

J. Stringer1972-09-01Materials and Corrosion

Abstract The experimental evidence for stress generation in growing oxide scales is briefly summarised, and the origin of these stresses is discussed. The limited experimental data related to oxide adhesion is discussed, and it is concluded that the adhesion between metal and oxide probably involves chemical interacti…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

High‐pressure phase of polytetrafluoroethylene

H. D. Flack1972-09-01Journal of Polymer Science Part A-2 Polymer Physics

Abstract The effect of hydrostatic pressure on the crystal structure of PTFE has been studied up to pressures of ca. 25 kbar by x‐ray diffraction. The experimental method uses opposed diamond anvils of small surface area as transmitters of pressure with MoKα x‐radiation propagating through these anvils. A small specim…

Metal and Thin Film MechanicsTribology and Wear AnalysisPolymer Nanocomposite Synthesis and Irradiation

Kinetic investigation of the synthesis of a polyethersulphone

T.E. Attwood、A.B. Newton、J. Bruce Ralphin Rose1972-09-01British Polymer Journal

Abstract This paper summarises results obtained from a kinetic investigation of the processes occuring during the synthesis of polyethersulphones by reactions such as: magnified image The factors determining the variations in functional group reactivities due to ‘bridge’ effects are described with reference to the rea…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

The effects of elastic anisotropy on dislocation line tension in metals

D. M. Barnett、R.J. Asaro、S.D. Gavazza 等 5 位作者1972-09-01Journal of Physics F Metal Physics

Formulae for the energy, its first derivative with respect to orientation and the line tension of straight dislocations in elastic media of arbitrary anisotropy are developed. The formulae may be evaluated rapidly and precisely by numerical integration, thus avoiding the need for solving a sextic algebraic equation co…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesMetal Forming Simulation Techniques

Critical Review of Synthesis and Occurrence of Plagioclase Feldspars and a Possible Phase Diagram

J. V. Smith1972-09-01The Journal of Geology

Attainment of equilibrium in plagioclase feldspars is severely hampered by the charge linkage between Ca and Al on the one hand and Na and Si on the other hand (Goldsmith): exsolution is governed therefore by the activation energy for migration of tetrahedrally bonded atoms. Fine-scale intergrowths with structural con…

Soil and Unsaturated FlowCO2 Sequestration and Geologic InteractionsClay minerals and soil interactions

Factors Affecting the Interactions of Collagen Molecules as Observed by in Vitro Fibril Formation

Toshihiko Hayashi、Yutaka Nagai1972-09-01The Journal of Biochemistry

Mono, di-, and tri-saccharides were found to inhibit collagen fibril formation in vitro without denaturing collagen molecules. Polyalcohols such as ethylene glycol, glycerol, and mannitol also inhibited the fibril formation at higher concentrations than those of sugars. Urea and dioxane also inhibited the fibril forma…

Osteoarthritis Treatment and MechanismsProteoglycans and glycosaminoglycans researchCollagen: Extraction and Characterization

Electron paramagnetic resonance study of copper(II)-ammonia complexes in Y-type zeolites

E. F. Vansant、Jack H. Lunsford1972-09-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron paramagnetic resonance study of copper(II)-ammonia complexes in Y-type zeolitesE. F. Vansant and J. H. LunsfordCite this: J. Phys. Chem. 1972, 76, 20, 2860–2865Publication Date (Print):September 1, 1972Publication History Published online1 May 2002Published inissue…

Magnetism in coordination complexesAdvanced NMR Techniques and ApplicationsElectron Spin Resonance Studies

Elastic Constants and Soft Optical Modes in Gadolinium Molybdate

U. T. Höchli1972-09-01Physical review. B, Solid state

The complete set of elastic constants in single-crystal gadolinium molybdate (GMO) is presented in a temperature range from 20 to 200 \ifmmode^\circ\else\textdegree\fi{}C. This covers the structural phase transition at 159 \ifmmode^\circ\else\textdegree\fi{}C, below which GMO is both ferroelastic and ferroelectric. El…

High-pressure geophysics and materialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Thermal stability of thin PtSi films on silicon substrates

A. K. Sinha、Robert B. Marcus、T. T. Sheng 等 4 位作者1972-09-01Journal of Applied Physics

The thermal stability of PtSi is an important parameter in large-scale integration processing schemes which involve postmetallization high-temperature operations. For this reason, the effect of annealing on various properties of PtSi has been studied over the temperature range 800–900°C, for 200- and 900-Å-thick PtSi…

Semiconductor materials and devicesCopper Interconnects and ReliabilitySemiconductor materials and interfaces