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Glass transitions of topologically interpenetrating polymer networks

H. L. Frisch、Kurt C. Frisch、D. Klempner1974-09-01Polymer Engineering and Science

Abstract Two component topologically‐interpenetrating polymer networks were made of the SIN type (simultaneous interpenetrating network) composed of two polyurethanes (a polyether‐based and a polyester‐based) in combination with an epoxy resin, a polyacrylate and two unsaturated polyesters. The linear polymers and/or…

Computational Drug Discovery MethodsPolymer composites and self-healingCatalysis and Oxidation Reactions

Pseudoelasticity in Au-Cu-Zn thermoelastic martensite

Seiji Miura、Shunsuke Maeda、Norihiko Nakanishi1974-09-01Philosophical magazine

Pseudoelaatioity in quasibinary Au-Cu-Zn alloys (e/a = 1·45, 1·46, 1·47 and 1·48) was studied by an analysis of stress-strain curves, and explained on the basis of lattice softening. The growth morphology of stress-induced martensite was observed, and its crystal structure and axial ratio were found to be an orthorhom…

Microstructure and mechanical propertiesShape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties

Spatial distribution of backscattered electrons in the scanning electron microscope and electron microprobe

Kenji Murata1974-09-01Journal of Applied Physics

Monte Carlo calculations have been applied to the electron scattering theory in scanning electron microscopy. These calculations are based on a single-scattering model in which the screened Rutherford expression for single-scattering cross section and the continuous energy-loss equation of Bethe are used. The surface…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Ionization dilatation effects in fused silica from 2 to 18-keV electron irradiation

C. B. Norris、E.P. EerNisse1974-09-01Journal of Applied Physics

We have used low-energy electron irradiations in conjunction with a bending-cantilever-plate technique to investigate the volume dilatations produced by ionization effects in fused silica. Our irradiations generally cause compaction in agreement with previous data from high-energy electron irradiations, but we consist…

Glass properties and applicationsIon-surface interactions and analysisNuclear materials and radiation effects

Magnetic anisotropy and hyperfine interactions in CeFe2, GdFe2, and LuFe2

U. Atzmony、M.P. Dariel1974-09-01Physical review. B, Solid state

M\"ossbauer-effect measurements on $^{57}\mathrm{Fe}$ have been carried out on the cubic Laves compounds Ce${\mathrm{Fe}}_{2}$, Gd${\mathrm{Fe}}_{2}$, and Lu${\mathrm{Fe}}_{2}$ between 80 and 300 K. The analysis of the M\"ossbauer spectra allowed the determination of the easy axes of magnetization $\stackrel{\ensurema…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Elastic Constants of Fe-Pt Alloys. I. Single Crystalline Elastic Constants of Fe72Pt28

G. Hausch1974-09-01Journal of the Physical Society of Japan

The elastic constants of a disordered Fe 72 Pt 28 single crystal have been measured as a function of temperature. All elastic constants behave highly anomalously below T c due to the Invar properties of this alloy. The magnetic contribution to the shear modes C '=( C 11 - C 12 )/2 and C = C 44 can be described by the…

Magnetic properties of thin filmsMicrostructure and Mechanical Properties of SteelsMagnetic Properties and Applications

Adsorption of proteins onto hydrophobic polymer surfaces: Adsorption isotherms and kinetics

Randy G. Lee、Sung‐Wan Kim1974-09-01Journal of Biomedical Materials Research

Abstract Adsorption of albumin, γ‐globulin, and fibrinogen from solution, under both static and flow conditions, onto several hydrophobic polymers was studied using internal reflection infrared spectroscopy. Isotherm curves experimentally found were consistant with Langmuir type adsorption. The rate and amount of prot…

Polymer Surface Interaction StudiesProtein purification and stabilityBlood properties and coagulation

Domain structure in YIG films subjected to magnetic fields and stresses

E. Duda、B. Désormière、G. Volluet1974-09-01IEEE Transactions on Magnetics

Magnetic domain structure in epitaxial YIG films was investigated using Faraday effect and Bitter method. These experiments have shown complex structures of closure domains. The influence of in-plane magnetic fields and stresses on the magnetization position was measured. The observed variation was interpreted in the…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications

Knudsen Effusion Study of the Vaporization of CdO(s)

R. Tom Jun. Coyle、G. Lewis1974-09-01Journal of the American Ceramic Society

Knudsen effusion studies were conducted on CdO(s) in fused‐SiO 2 Knudsen cells from 889 to 1110 K. The orifice size was varied; the largest cell orifice yielded a calculated pressure significantly lower than could be accounted for by experimental error. Average‐slope‐ and average‐free‐energy‐function‐based values of Δ…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceSemiconductor materials and devices

Lennard-Jones interaction for hexagonal layered crystals

J. F. Green、T. K. Bolland、J. W. Bolland1974-09-01The Journal of Chemical Physics

A very wide range of extremely high precision single-plane hexagonal lattice sums were calculated by computer. These sums are necessary to the Lennard-Jones interaction potential theory for hexagonal layered crystals. As an application, interplanar spacing, c-axis lattice energy, c-axis elastic moduli, and their chang…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchGraphite, nuclear technology, radiation studies

ANODIC OXIDATION OF TRIALKYLBORANES USING GRAPHITE AS THE ANODE. NOVEL REACTION OF ORGANOBORANES PROCEEDING THROUGH A CARBONIUM ION MECHANISM

Toru Taguchi、Yuzuru Takahashi、Mitsuomi Itoh 等 4 位作者1974-09-01Chemistry Letters

Abstract Trialkylboranes are readily electrolyzed by using graphite as an anode in a sodium perchlorate-methanol solution containing sodium methoxide or a sodium acetate-acetic acid solution to give corresponding alkyl methyl ethers or alkyl acetates in good yields, respectively.

Radical Photochemical ReactionsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

A study of kinking and buckling in zinc single crystals

E. G. Tapetado、M. H. Loretto1974-09-01Philosophical magazine

Single crystals of zinc have been deformed in compression along directions close to 〈1·00〉 and 〈11·0〉. High-voltage electron microscopy has been used to identify the dislocations in the deformed crystals. Crystals which deform by kinking, without significant prior plastic deformation, contain dislocations of b = ⅓〈11·…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesHigh-Velocity Impact and Material Behavior

Calculation of Electron Transport in a Slab

O. B. Evdokimov、A. P. Yalovets1974-09-01Nuclear Science and Engineering

A new calculation method of electron transport in a medium with boundaries has been developed. The method is based on the solution of the kinetic equation, written for the segments model in the continuous slowing down approximation. The distribution function is represented in the Fourier-Legendre expansion and the equ…

Electron and X-Ray Spectroscopy Techniques

Contaminated Insulators-Chemical Dependence of Flashover Voltages and Salt Migration

L. J. Williams、Jung Ho Kim、Yun Kim 等 6 位作者1974-09-01IEEE Transactions on Power Apparatus and Systems

The results of carefully controlled laboratory experiments on contaminated flat plate insulators are presented. Flashover voltages and salt migration effects are shown for the following nine common salts: NaCl, NaNO3, Na2SO4, MgC12, Mg(NO3)2, MgSO4, CaCl2, Ca(NO3)2, and CaSO4. Our results show that the tendency for an…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

A Modification of the Almon Distributed Lag

Peter Schmidt1974-09-01Journal of the American Statistical Association

This article modifies the Almon polynomial distributed lag to allow for a lag of infinite length. Estimation of the model is considered, and an empirical example is given to illustrate the usefulness of the model

Stochastic processes and statistical mechanicsCrystallization and Solubility Studies

The effects of stress on some properties of MnZn ferrite

E. C. Snelling1974-09-01IEEE Transactions on Magnetics

The effects of tensile and compressive stresses applied parallel to the magnetic flux path were observed on specially shaped specimens cut from blocks of low-loss MnZn ferrous ferrite typical of those used for inductor cores. The permeability, losses and coercivity were observed as functions of temperature. Stress lev…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesInduction Heating and Inverter Technology

Electron interferometry with the Elmiskop 101 electron microscope

P. G. Merli、G.F. Missiroli、G. Pozzi1974-09-01Journal of Physics E Scientific Instruments

A simple and versatile electron biprism of the Mollenstedt type is presented, which allows the conversion of a Siemens Elmiskop 101 electron microscope for use as an interference microscope or as an electron interferometer. The microscope's performance with the biprism inserted at the level of the selector aperture pl…

Advanced X-ray Imaging TechniquesAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Dynamic Mechanical and Electrical Properties of Vulcanizates at Elongations up to Sample Rupture

Andries Voet、J. C. Morawski1974-09-01Rubber Chemistry and Technology

Abstract Dynamic properties of vulcanizates have been measured at small and large extensions, up to specimen rupture, by means of a modified Rheovibron. The influence of temperature, frequency, and amplitude on the dynamic moduli has been determined for a number of SBR samples, uncharged or charged with silica or carb…

Advanced Sensor and Energy Harvesting MaterialsPolymer Nanocomposites and PropertiesForce Microscopy Techniques and Applications

GENESIS OF RED AND BLACK SOILS ON BASALT ON THE DARLING DOWNS, QUEENSLAND, AUSTRALIA

G. G. Beckmann、C. H. Thompson、G. D. Hubble1974-09-01Journal of Soil Science

Summary Shallow friable red soils (euchrozems) and shallow cracking clays (black earths) occur in close proximity on basalt hills of the Darling Downs of Queensland. The euchrozems are mainly restricted to fiat hill crests and are associated with lithosols; the shallow black earths occur on upper pediment slopes, on s…

Soil and Unsaturated FlowClay minerals and soil interactionsGeochemistry and Geologic Mapping

Bisphenol a synthesis: Kinetics of the phenol‐acetone condensation reaction catalyzed by sulfonic acid resin

R. A. Reinicker、B. C. Gates1974-09-01AIChE Journal

Abstract The industrially important reaction of phenol and acetone to give bisphenol A and water was catalyzed by beads of ion‐exchange resin (sulfonated styrene‐divinylbenzene copolymer) suspended in a batch reactor containing liquid reactants. The data are summarized by a rate equation accounting for reaction in the…

Zeolite Catalysis and SynthesisSynthesis and properties of polymersMicrowave-Assisted Synthesis and Applications