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Chain Scission and Cross-Linking in the Radiation Degradation of Polymers: Limitations on the Utilization of Theoretical Expressions and Experimental Results in the Pregel Region

J. H. O'Donnell、Nazia Rahman、Craig A. Smith 等 4 位作者1979-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChain Scission and Cross-Linking in the Radiation Degradation of Polymers: Limitations on the Utilization of Theoretical Expressions and Experimental Results in the Pregel RegionJ. H. O'Donnell, N. P. Rahman, C. A. Smith, and D. J. WinzorCite this: Macromolecules 1979, 12, 1…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Beiträge zum thermischen Verhalten von Sulfaten. II. Zur thermischen Dehydratisierung des ZnSO4 · 7 H2O und zum Hochtemperaturverhalten von wasserfreiem ZnSO4

M. Spiess、R. Gruehn1979-01-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Mit kontinuierlichen Heizguinieraufnahmen wurde die Dehydratisierung von ZnSO 4 · 7 H 2 O und das Hochtemperaturverhalten von wasserfreiem ZnSO 4 untersucht. Der Abbau von ZnSO 4 · 7 H 2 O verläuft an der Luft über das 6‐Hydrat, eine unbekannte Hydratphase und das 1‐Hydrat zum N‐ZnSO 4 , der Normaltemperaturf…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsThermal and Kinetic Analysis

Effects of boron, titanium, and nitrogen on the hardenability of boron-treated steels for heavy machinery

F. Nakasato、Masatoshi Takahashi1979-01-01Metals Technology

The effects of boron, titanium, and nitrogen contents on the hardenability of boron-bearing steels have been studied. The boron hardenability factor was found to be a rapidly decreasing function of (total N – N as TiN). Thus, it was confirmed that titanium plays a very important role in retaining the excellent hardena…

Metal and Thin Film MechanicsAdvanced materials and compositesMetal Alloys Wear and Properties

Electron-microscope observation of structure domains in the ferroelastic phase of lead phosphate, Pb3(PO4)2

R. Ayroles、J. Torrès、J. Aubrée 等 5 位作者1979-01-01Applied Physics Letters

We have used for the first time the electron-microscopy technique to reveal the pure ferroelastic phase domain structure of lead phosphate, Pb3(PO4)2. The domain configuration confirms previous identifications of the symmetry elements lost at the transition. The domains are found separated by thin walls whose thicknes…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsSolid-state spectroscopy and crystallography

Biphasic photochemistry: micellar regioselectivity in enone dimerisation

Kong-Hung Lee、P. de Mayo1979-01-01Journal of the Chemical Society Chemical Communications

Irradiation of 3-alkylcylcopentenones in potassium dodecanoate micelles leads to greatly increased efficiency of dimerisation over that in homogeneous solution and regiospecific head-to-head control far beyond that possible by solvent variation.

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Synthesis of 1 - (4-Alkoxy or Alkyl- Benzoyloxy-Phenyl) - 2- (4′- Pentylphenyl) - Ethanes. Influence of the Central Group on the Mesomorphic Properties

Nguyễn Hữu Tình、A. Zann、Jean Dubois1979-01-01Molecular crystals and liquid crystals

An homologous series of mesomorphic compounds, the I-(4-alkoxy or alkyl-benzoyloxyphényl)-2-(4′-pentylphenyl)-ethanes, has been synthesized. The compounds with R = alkyl have low-melting points and wide mesomorphic ranges, for example from 33.5°C to 106.5C. The compounds with R = alkoxy exhibit a smectic polymorphism;…

Liquid Crystal Research AdvancementsSynthesis of Organic CompoundsAxial and Atropisomeric Chirality Synthesis

CaAgP und CaAgAs -Zwei Verbindungen mit Fe2P-Struktur/CaAgP and CaAgAs -Two Compounds with the Fe2P-Structure

Albrecht Mewis1979-01-01Zeitschrift für Naturforschung B

Abstract The compounds CaAgP and CaAgAs have been prepared and their structures have been determined. They are isotypic and crystallize in a modified Fe 2 P-structure (space group P6̄2m-D 3 3h ) with the lattice constants: CaAgP a = 704,5(1) pm, c = 417,4(1) pm, CaAgAs a = 720,4(1) pm, c = 427,0(1) pm.

Microstructure and Mechanical Properties of SteelsRare-earth and actinide compoundsIron-based superconductors research

Relationship between lead content of Cu–40Zn, machinability, and svvarf surface composition determined by Auger electron spectroscopy

C. T. H. Stoddart、C. H. Lea、W. A. Dench 等 5 位作者1979-01-01Metals Technology

The surface composition of swarfs from leaded Cu-40Zn has been determined by Auger electron spectroscopy and ion etching as a function of bulk-lead content and machining conditions. The lead additive is distributed at the swart surface as a continuous thinfilm of monatomic thickness and as varying proportions of thick…

Electrodeposition and Electroless CoatingsElectron and X-Ray Spectroscopy TechniquesIntegrated Circuits and Semiconductor Failure Analysis

Proton exchange and temperature studies of pyrazole in dimethyl-d6 sulfoxide by carbon-13 NMR

William M. Litchman1979-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProton exchange and temperature studies of pyrazole in dimethyl-d6 sulfoxide by carbon-13 NMRWilliam M. LitchmanCite this: J. Am. Chem. Soc. 1979, 101, 3, 545–547Publication Date (Print):January 1, 1979Publication History Published online1 May 2002Published inissue 1 January…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyElectron Spin Resonance Studies

HIGH TEMPERATURE CYCLIC DEFORMATION OF NICKEL

Shrikant P. Bhat、C. Laird1979-01-01Fatigue & Fracture of Engineering Materials & Structures

Abstract— High temperature cyclic deformation in nickel is investigated by comparing its cyclic hardening curves at constant strain amplitudes at four temperatures with the monotonic hardening curves and by detailed electron microscopic examination of the bulk. Just as at ambient temperature, there are broad similarit…

Microstructure and mechanical propertiesHigh Temperature Alloys and CreepMetallurgy and Material Forming

Molecular properties of some nematic liquids. II. Refractive index and order parameter

I. H. Ibrahim、W. Haase1979-01-01Journal de physique

The refractive indices and densities of a number of 4,4'-disubstituted phenyl benzoates and the Merck nematic phases ZLI 1052 and ZLI 389 are reported as functions of temperature in the nematic and isotropic phases. Also two isomers of 4,4'-disubstituted phenyl thiobenzoates are investigated. Comparison of Vuks model…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Behavior of dissolved silica in parent solution at the formation of calcium carbonate.

Yasushi Kitano、Minoru Okumura、Masatoshi Idogaki1979-01-01GEOCHEMICAL JOURNAL

The authors have studied experimentally on the coprecipitation of dissolved silica with calcium carbonate (calcite or aragonite) and on the influence of silica dissolved in a parent calcium bicarbonate solution on the crystal form of calcium carbonate precipitated from the parent solution. The coprecipitation of disso…

Calcium Carbonate Crystallization and Inhibition

Kinetic and topological limits on melt crystallisation in polyethylene

Jacob Klein、Robin Ball1979-01-01Faraday Discussions of the Chemical Society

The rates at which molecular sequences may deposit onto growing lamellae in a crystallising polyethylene melt are examined on the basis of the results of recent self-diffusion experiments in such melts, in conjunction with theories of molecular dynamics in polymer melts based on the reptation picture. The results are…

Polymer crystallization and propertiesMicroplastics and Plastic Pollution

Inconel Alloy 690-A New Corrosion Resistant Material

A. J. Sedriks、J. W. Schultz、M. A. Cordovi1979-01-01Corrosion engineering digest

INCONEL Alloy 690 (Ni-30Cr-9Fe-0.02C, wt. %), is a new high-chromium nickel-base alloy, designed to provide a stable austenitic structure combined with resistance to corrosion and oxidation in aggressive industrial environments at elevated temperatures. Extensive laboratory evaluation of Alloy 690 during the past 12 y…

Nuclear reactor physics and engineeringHigh-Temperature Coating BehaviorsNuclear Materials and Properties

The theory of blister formation

Yu. V. Martynenko1979-01-01Radiation Effects

Abstract The generation of blisters due to irradiation by helium ions is investigated theoretically. The possible pressure in helium bubbles in metals, the binding energy of helium atoms and vacancies to a bubble are calculated. The kinetics of bubble growth is studied. Using the known profiles of implanted ions and d…

Surface Modification and SuperhydrophobicityAdvanced Materials and MechanicsIon-surface interactions and analysis

Effect of pressure and temperature on some kinetic and thermodynamic parameters of non-ionic reactions. Volume changes on activation and reaction

B. S. EL'YANOV、Elena M. Gonikberg1979-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The formulae currently used to calculate volume changes on activation, ΔV≠0 and reaction, ΔV≠0, are shown to be unsuitable even at pressures of ≈ 1 kbar, and calculations are shown to be sensitive to errors, owing to empirical coefficients present in the formulae.The ΔVp=ΔV0[1–α ln (1 +βp)] relationship is substantiat…

Advanced Chemical Physics StudiesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Solubility of octacosane and hexatriacontane in different n-alkane solvents

Hans Madsen、R. Boistelle1979-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The solubilities of octacosane in decane and dodecane and of hexatriacontane in hexane, octane, decane and dodecane in the temperature interval 11–38°C have been determined, and the standard enthalpies and entropies of solution, ΔHd and ΔSd, have been calculated from the solubility curves. For hexatriacontane ΔHd incr…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical Thermodynamics and Molecular Structure

Spectroscopic study of the field-induced spin reorientation in ErCrO3

Kazuharu Toyokawa、Susumu Kurita、K. Tsushima1979-01-01Physical review. B, Condensed matter

Using the optical Zeeman absorption spectrum of ${\mathrm{Er}}^{3+}$ and ${\mathrm{Cr}}^{3+}$ in ErCr${\mathrm{O}}_{3}$, the field-induced spin reorientations between ${\ensuremath{\Gamma}}_{1}$, ${\ensuremath{\Gamma}}_{2}$, and ${\ensuremath{\Gamma}}_{4}$ phases are investigated extensively. The data are analyzed usi…

Multiferroics and related materialsAdvanced Condensed Matter PhysicsSolid-state spectroscopy and crystallography

Charge Carrier Mobility Measurements in Nematic Liquid Crystals

Grzegorz Derfel、A. Lipiński1979-01-01Molecular crystals and liquid crystals

The nematic liquid crystal is considered as a weak electrolyte. The analysis of the time behaviour of the transient current flowing through the sample allows the estimation of the mean mobility of anions and cations. The electrohydrodynamic flows are avoided thanks to the application of low voltages. For p-octyloxyphe…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesNonlinear Dynamics and Pattern Formation